• Korean Journal of Food Science and Technology
• /
• v.52 no.3
• /
• pp.205-211
• /
• 2020

In this study, fruit phenolics were investigated with using LC/MS and HPLC analysis in order to compare the differences between domestic ('Campbell Early', 'Kyoho', 'Heukbosuk', and 'Hongju SDS') and imported ('Crimson SDS' and 'Thomson SDS') grapes. In the case of fruit characteristics, imported grape 'Crimson SDS' and 'Thompson SDS', had lighter skin weight (300-350 mg/berry) and hard flesh (5.2-5.6 kg·f) than domestic grape cultivar. The phenolic compound contents of 'Crimson SDS' skin was higher, but resveratrol (25-29 mg/kg), quercetin (350-380 mg/kg), and myricetin (31-32 mg/kg) contents were similar in to those of 'Hongju SDS'. The anthocyanin content was different from differed between grape cultivars. 'Hongju SDS' grape was showed higher in Delphinidin-3-glucose (D3G) levels, and 'Crimson SDS' was showed higher in Peonidin-3-glucoside (P3G) levels. The contents of phenolic compounds were investigated differently for each grape berry part. Catechin, epicatechin, procyanidin B1, and B2 were found in grape seeds.

• Journal of the Korean Chemical Society
• /
• v.38 no.12
• /
• pp.857-863
• /
• 1994

The absorption and fluorescence spectroscopic studies on the interaction between thionine (TH) and sodium dodecyl sulfate (SDS) have been carried out. The absorption and fluorescence spectral changes of TH with the changes of concentration of SDS are interpreted in terms of i) the aggregation of TH-SDS complex, ii) the stacking process of dye molecules by the association of the TH-SDS complex, iii) breakdown of the stacking due to the formation of dye-rich induced micelles, iv) redistribution of dye molecules in the surface of SDS micelles.

• Bulletin of the Korean Chemical Society
• /
• v.7 no.2
• /
• pp.113-116
• /
• 1986

Spectral behaviors of cationic dyes, methylene blue(MB) and acridine orange(AO), with varying concentrations of sodium dodecylsulfate(SDS) were studied. At low concentration of SDS(<1mM), these dyes formed insoluble dye-surfactant aggregates. When [SDS] is 4-5 mM, the aggregates were dissolved into mixed micelles of constant composition. At higher concentration of [SDS], the composition of mixed micelles were changed with [SDS], resulting only monomeric form of dyes in micelles. AO-SDS system showed greater aggregating and less dissolving properties, and weaker effect of salt than MB-SDS system did. These were attributed to the greater hydrophobic nature of the former dye. The monomer/dimer ratios of dyes in mixed micelles at given [SDS] were greatest at $20^{\circ}C$, reflecting the dependency of CMC of the surfactant on temperature.

• Proceedings of the Korea Information Processing Society Conference
• /
• 2008.05a
• /
• pp.320-323
• /
• 2008

많은 기업의 정보화 프로젝트가 계획된 예산과 기한 내에 완수하지 못하고, 폐지되거나 당초 예상된 성과를 달성하지 못하고 있다. 정보화 프로젝트의 성공 확률을 높이기 위해서는 프로젝트 실패의 원인이 될 수 있는 잠재된 위험을 식별하고, 식별된 위험요인을 체계적이며, 지속적으로 관리할 필요가 있다. 본 논문에서는 정보화 사업 중 시스템통합 사업에서 발생할 수 있는 위험요인을 체계적으로 분류하고 관리 할 수 있는 기반을 제안하고자 한다. 위험관리 프레임워크는 이해당사자들의 관점을 중심으로 위험요인을 체계적으로 분류하고, 위험요인을 점검할 수 있는 체크리스트를 제공함으로써 각 이해당사자들의 요구에 맞게 SI 프로젝트의 위험에 대응하여 정보화 프로젝트의 성공 확률을 높이는 데 이바지 할 수 있다.

• Journal of the Korean Chemical Society
• /
• v.55 no.3
• /
• pp.379-384
• /
• 2011

The critical micelle concentration (CMC) and the counter ion binding constant (B) for the mixed micellizations of DBS (sodium dodecylbenzenesulfonate), SDS (sodium dodecylsulfate), and Brij 30 (polyoxyethylene(4) lauryl ether) at $25^{\circ}C$ in pure water were determined by the use of electric conductivity and surface tension measuring methods. Various thermodynamic parameters ($X_i,\;{\gamma}i,\;C_i,\;a_i^M,\;{\beta}$, and ${\Delta}H_{mix}$) were calculated and compared with each other mixed surfactant system by means of the equations derived from the nonideal mixed micellar model. The results show that the SDS molecule interacts more strongly with Brij 30 molecule than DBS molecule and that the SDS/Brij 30 mixed surfactant system has the greatest negative deviation from the ideal mixed micellar model and the SDS/DBS mixed system has followed almost the ideal mixed micellar model.

• Journal of the Korean Geotechnical Society
• /
• v.27 no.9
• /
• pp.47-53
• /
• 2011

Marine dredged soils taken from navigation channels or construction sites of coastal area usually have a lot of salt in pores of clayey soils. This paper investigates effect of salt on mechanical characteristics of non-salt and salt-rich stabilized dredged soil. The stabilized dredged soil (SDS) consisted of dredged soil and cement. Several pairs of SDS with non-salt and salt-rich dredged soils, noted as N-SDS and S-SDS, respectively, were prepared to compare their strengths and compressibility characteristics. The microstructures, strength and compressibility characteristics of N-SDS and S-SDS specimens at 7 and 28 days of curing time were evaluated using scanning electronic microscope (SEM), unconfined compression test, and oedometer test. It was found that salt concentration of clayey soil affected not only the formation of soil structure but also the strength development of mixture. The compression index and swelling index of S-SDS were also greater than those of N-SDS, which indicated that the compressibility of mixture increased due to salt concentration. Salinity in clayey soil had a negative effect on the strength development and compressibility characteristics of stabilized dredged soils.

• Analytical Science and Technology
• /
• v.19 no.6
• /
• pp.529-534
• /
• 2006

The protein separation with molecular weight using SDS-PAGE(sodium dodecyl sulfate-polyacrylamide gel electrophoresis) is the one of the most conventional and simple techniques. In, this study, two dimensional SDS-PAGE using same separation principle consecutively was investigated and compared with one dimensional SDS-PAGE. The enhanced separation from duplex SDS-PAGE was observed and separated proteins in the gel were identified by MALDI TOF MS. Identified proteins from different gel spots were found to have different gi numbers. Therefore, duplex SDS-PAGE separation method will be used for economic separation method in the future because only tiny amount of inexpensive reagents are used to perform duplex SDS-PAGE.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.31 no.4B
• /
• pp.377-382
• /
• 2011

In this study, hydrogen peroxide is stabilized in modified Fenton reaction to improve the soil remediation. Phenanthrene, which is the typical compound in PAHs, was spiked into soil samples to copy the original contaminated site. Anionic surfactant, SDS (Sodium dodecyl sulfate) was used for hydrogen peroxide stabilizer. 4 mM of Fe(II), 5~50 mM of SDS and 102.897 mM of $H_2O_2$ was injected into soil samples which is contaminated by 125 mg/kg of phenanthrene to analyze decomposition rate of phenanthrene in modified Fenton reaction. In condition which SDS was injected 30 mM, decomposition rate of phenanthrene has best efficiency as 95% and in condition which SDS was injected over 30 mM, decomposition rate is lower than SDS 30 mM because SDS enacted as scavenger in the system. Results which assess the change of hydrogen peroxide concentration after injecting hydrogen peroxide stabilizer showed that hydrogen peroxide concentration was 14.6995 mM so that is stabilized at Fe(II) 2 mM condition in 48 hours. On the other hand, hydrogen peroxide is not stable in Fe(III) condition. SDS concentration was fixed and iron concentration was changed 2~8 mM to find out optimize proportion between iron concentration and SDS concentration in modified Fenton reaction. Consequentially, in condition of which Fe(II) 4 mM and SDS 30 mM, reaction has the highest removal rate as 95%.

• Journal of the Korean Chemical Society
• /
• v.42 no.6
• /
• pp.672-678
• /
• 1998

Chitin was extracted from crab shell of Portuns triberculatus and deacethylated to yield chitosan with various molecular weights. The absorption and the fluorescence spectra of Rhodamine 6G(Rh 6G)-sodium dodecyl sulfate(SDS) and Rh 6G-chitosan systems were obtained. From the spectra, we observed that the absorption and the fluorescence intensity of Rh 6G-SDS system decreased when S/D(the concentration of SDS to that of Rh 6G ratio) was below or at 32, while they increased when S/D was above 32. From the suspended solid(SS) removal rate and the transmittance of Rh 6G-SDS-chitosan system, we found that when S/D ratio was 32 its flocculating behaviour was much stronger than Rh 6G-SDS system. As the concentration and the molecular weight of chitosan increased, we also found that S/D range was extended from 32 to 100. With increasing the molecular weight of chitosan, the SS removal rate increased around pH 2~9 but decreased remarkably at pH>12.

• Macromolecular Research
• /
• v.16 no.6
• /
• pp.492-502
• /
• 2008

This study examined the adsorption of a synthetic cutting fluid and cutting fluid effluent on chitosan and SDS-modified chitosan, Chitosan and SDS-modified chitosan were prepared in form of beads and fibers. A series of batch experiments were carried out as a function of the initial concentration of cutting fluid, contact time and pH of the fluid. The contact angle study suggested that the SDS-modified chitosan was more hydrophobic than chitosan. The Zeta potential study showed that chitosan, SDS-modified chitosan and synthetic cutting fluid had a point of zero charge (PZC) at pH 7.8, 9 and 3.2, respectively. SDS-modified chitosan has a greater adsorption capacity than chitosan. The experimental results show that adsorption capacity of the cutting fluid on 1.0 g of SDS-modified chitosan at pH 3 and for a contact time of 120 min was approximately 2,500 g/kg. The adsorption capacity of chitosan and SDS-modified chitosan increased with decreasing pH. The Langmuir, Freundlich, and Brunauer Emmett and Teller (BET) adsorption models were used to explain the adsorption isotherm. The Langmuir isotherm fitted well with the experimental data of chitosan while the BET isotherm fitted well with the SDS-modified chitosan data. Pseudo first- and second-order kinetic models and intraparticle diffusion model were used to examine the kinetic data. The experimental data was fitted well to a pseudo second-order kinetic model. The significant uptake of cutting fluid on chitosan and SDS-modified chitosan were demonstrated by FT-IR spectroscopy, SEM and heat of combustion.