• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2004.05a
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• pp.221-224
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• 2004

The clad samples of five plies of sheets comprising ferritic stainless steel (STS) and aluminum (Al) were prepared by roll-cladding at $350^{\circ}C$. The evolution of strain states and textures during roll-cladding of STS430/AA3003/AA3003/AA3 003/STS430 and STS430/AA3003/STS430/AA3003/STS430 was investigated by measurements of crystallographic textures and by simulations with the finite element method (FEM). Because the deformation mainly occurs in the Al layer during roll-cladding, the present investigation was focused on the Al layers located. The stacking sequence of sheet materials in the clad samples played an important role in the evolution of strain states during roll-cladding.

• Journal of Powder Materials
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• v.16 no.3
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• pp.185-190
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• 2009

Fe-Cr steels are the most promising candidate for interconnect in solid oxide fuel cells. In this study, an effective, dense and well adherent (LaSr)(CrCo)$O_3$ [LSCC] coating layer was produced onto 430 stainless steel (STS-430) by atmospheric plasma spraying and the oxidation behavior as well as electrical properties of the LSCC coated STS-430 were investigated. A significant oxidation of pristine STS-430 occurred at $800^{\circ}C$ in air environment, leading to the formation of $Cr_2O_3$ and $FeCr_2O_4$ scale layer up to ${\sim}7{\mu}m$ after 1200h, and consequently increased an area specific resistance of $330\;m{\Omega}{\cdot}cm^2$. Although the plasma sprayed LSCC coating contained the characteristic pore network, the coated samples presented apparent advantages in reducing oxidation growth of STS-430, resulting a decrease in oxide scale thickness of ${\sim}1{\mu}m$ at $800^{\circ}C$ after 1200h. The area specific resistance of the LSCC coated STS-430 was much reduced to ${\sim}7\;m{\Omega}{\cdot}cm^2$ after exposure at $800^{\circ}C$ for 1200h, compared to that of the pristine STS-403.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.436-437
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• 2008

Flexible CIGS thin film solar cell was fabricated using STS430 plate as a flexible substrate in this work. A diffusion barrier layer of $SiO_2$ thin film was deposited on STS430 substrate by PECVD followed by deposition of double layered Mo back contact. After depositing CIGS absorber layer by co-evaporation, CdS buffer layer by chemical bath deposition, ZnO window layer by RF sputtering and Al electrode by thermal evaporation, the solar cell fabrication processes were completed and its performance was evaluated. Corresponding solar cell showed an conversion efficiency of 8.35 % with $V_{OC}$ of 0.52 V, $J_{SC}$ of 26.06 mA/$cm^2$ and FF of 0.61.

• Corrosion Science and Technology
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• v.6 no.1
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• pp.1-6
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• 2007

Ferritic stainless steels for the SOFC interconnect applications are required to possess not only a good oxidation resistance, but also a high electrical conductivity of the oxide scale that forms during exposure at the SOFC operating environment. In order to understand the effects of alloying elements on the oxidation behavior of ferritic stainless steels and on the electrical properties of oxide scales, two kinds of commercial ferritic stainless steels, STS 430 and STS 444, were investigated by performing isothermal oxidations at $800^{\circ}C$ in a wet air containing 3% $H_{2}O$. The results showed that STS 444 was superior to STS 430 in both of the oxidation resistance and the area specific resistance. Although STS 444 contained a less amount of Mn for the $(Mn,Cr)_{3}O_{4}$ spinel formation than STS 430, the minor alloying elements of Al and Mo in STS 444, which were accumulated in the base metal region adjacent the scale, were suggested to reduce the scale growth rate and to enhance the scale adherence to the base metal.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2004.10a
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• pp.29-33
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• 2004

This paper presents ESPI system for the measurement of thermal expansion coefficient of STS430 up to 1,000$^{\circ}C$. Existing methods, strain gauge and moire have the limitation of contact to object and do not supply the coefficient up to 800$^{\circ}C$. There needs to measure the data up to 800$^{\circ}C$, because heat resistant materials have high melting temperature up to 1,000$^{\circ}C$. In previous studies related to thermal strain analysis, the quantitative results are not reported by ESPI at high temperature, yet. In-plane ESPI and vacuum chamber for the reduction of air turbulence and oxidation are designed for the measurement of the coefficient up to 1,000$^{\circ}C$and speckle correlation fringe pattern images are processed by commercial image filtering tool-smoothing, thinning and enhancement- to obtain quantitative results, which is compared with references data. The comparison shows two data are agreed within 4.1％ blow 600$^{\circ}C$ however, there is some difference up to 600$^{\circ}C$. Also, the incremental ratio of the coefficient is changed up to 800$^{\circ}C$. The reason is the phase transformation of STS430 probably begins at 800$^{\circ}C$.

• Journal of the Korean Society for Precision Engineering
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• v.21 no.11
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• pp.69-74
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• 2004

This paper presents ESPI system for the measurement of thermal expansion coefficient of STS430 up to 1,00$0^{\circ}C$ . Existing methods, strain gauge and moire have the limitation of contact to object and do not supply the coefficient up to 80$0^{\circ}C$ . There needs to measure the data up to 80$0^{\circ}C$, because heat resistant materials have high melting temperature up to 1,000'E In previous studies related to thermal strain analysis, the quantitative results have not reported by ESPI at high temperature, yet. In-plane ESPI and vacuum chamber for the reduction of air turbulence and oxidation are designed for the measurement of the coefficient up to 1,00$0^{\circ}C$ and speckle correlation fringe pattern images are processed by commercial image filtering tool-smoothing, thinning and enhancement- to obtain quantitative results, which is compared with references data. The comparison shows two data are agreed within 4.1% blow $600^{\circ}C$ however, there is some difference up to $600^{\circ}C$. Also, the incremental ratio of the coefficient is changed up to 80$0^{\circ}C$ . The reason is the phase transformation of STS430 probably begins at 80$0^{\circ}C$

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2006.05a
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• pp.413-416
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• 2006

Two clad composites of five ply sheets comprising STS430/AA3003/AA3003/AA3003/STS430 and STS430/AA3003/STS430/AA3003/STS430 were produced by roll cladding at $350^{\circ}C$. In order to clarify the deformation behavior and strain states in the composites during roll cladding, the variation of individual sheet thickness and the evolution of through thickness textures and microstructures of the composites were investigated. The thickness reduction of each sheet depended on the location of the sheet and on the strength of each sheet in the composites. In order to elucidate the evolution of textures and microstructures in AA3003 sheets, the strain states in AA3003 sheets during roll cladding were calculated by FEM. The formation of shear textures and fine grains in AA3003 sheet was discussed in terms of the strain states in each sheet layer. Finally, the strain states extracted from the FEM were verified by texture simulations

• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.12 s.255
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• pp.1211-1217
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• 2006

This study is focused on oxidation prevention of STS430, which is generally used as solid oxide fuel cell(SOFC) interconnect at intermediate operating temperatures with oxidation-proof coatings. Inconel, $La_{0.6}Sr_{0.4}CoO_3(LSCo)$ and $La_{0.6}Sr_{0.4}CoO_3(LSCr)$ were chosen as coating materials. Using a radio frequency magnetron sputtering method, each target material was deposited as thin film on STS430 and was analyzed to find out favorable conditions. In this study, LSCr-coated STS430 can reduce electrical resistance to 1/3 level, compared with uncoated STS430. Also, long-term durability test at $700^{\circ}C$ for 1000 hours tells that LSCr thin layer performs an important role to prohibit serious degradations. Superior oxidation-resistant characteristic of LSCr-coated STS430 is attributed to the inhibition of spinel structure formation such as $MnCr_2O_4$.

• Proceedings of the Materials Research Society of Korea Conference
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• 2007.11a
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• pp.111.2-111.2
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• 2007

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2003.10a
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• pp.136-137
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• 2003

Recrystallization textures of ferritic stainless steel sheets of STS 430, the crystallographic texture was modified by means of cross rolling and subsequent annealing. The conventional normal rolling led to the formation of ｛334｝＜483＞ in the final recrystallization texture. Cross rolling in the present work was performed by a 45$^{\circ}$rotation of RD around ND. After recrystallization annealing the cross-rolled samples displayed stronger｛111｝//ND orientations. The cross rolled sample displayed a higher resistance against ridging.