• Title/Summary/Keyword: Secondary particles

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Biodegradation of Secondary Phase Particles in Magnesium Alloys: A Critical Review

  • Kannan, M. Bobby
    • Corrosion Science and Technology
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    • v.15 no.2
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    • pp.54-57
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    • 2016
  • Magnesium alloys have been extensively studied in recent years for potential biodegradable implant applications. A great deal of work has been done on the evaluation of the corrosion behaviour of magnesium alloys under in vitro and in vivo conditions. However, magnesium alloys, in general, contain secondary phase particles distributed in the matrix and/or along the grain boundaries. Owing to their difference in chemistry in comparison with magnesium matrix, these particles may exhibit different corrosion behaviour. It is essential to understand the corrosion behaviour of secondary phase particles in magnesium alloys in physiological conditions for implant applications. This paper critically reviews the biodegradation behaviour of secondary phase particles in magnesium alloys.

Evaluation of the Secondary Particle Effect in Inhomogeneous Media for Proton Therapy Using Geant4 Based MC Simulation (Geant4 몬테칼로 시뮬레이션을 활용한 불균질 매질에서의 양성자의 이차입자 영향 분석)

  • Park, So-Hyun;Jung, Won-Gyun;Rah, Jeong-Eun;Park, Sung-Yong;Suh, Tae-Suk
    • Progress in Medical Physics
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    • v.21 no.4
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    • pp.311-322
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    • 2010
  • In proton therapy, the analysis of secondary particles is important due to delivered dose outside the target volume and thus increased potential risk for the development of secondary cancer. The purpose of this study is to analyze the influence of secondary particles from proton beams on fluence and energy deposition in the presence of inhomogeneous material by using Geant4 simulation toolkit. The inhomogeneity was modeled with the condition that the adipose tissue, bone and lung equivalent slab with thickness of 2 cm were inserted at 30% (Plateau region) and 80% (Bragg peak region) dose points of maximum dose in Bragg curve. The energy of proton was varied with 100, 130, 160 and 190 MeV for energy dependency. The results for secondary particles were presented for the fluence and deposited energy of secondary particles at inhomogeneous condition. Our study demonstrates that the fluence of secondary particles is neither influenced insertion of inhomogeneties nor the energy of initial proton, while there is a little effect by material density. The deposited energy of secondary particles has a difference in the position placed inhomogeneous materials. In the Plateau region, deposited energy of secondary particles mostly depends on the density of inserted materials. Deposited energy in the Bragg region, in otherwise, is influenced by both density of inserted material and initial energy of proton beams. Our results suggest a possibility of prediction about the distribution of secondary particles within complex heterogeneity.

Synthesis of Monodispersed Barium Titanate Nanopowders by Alkoxide-Hydroxide Sol-Precipitation Method

  • Yoon, Song-Hak;Kim, Min-Gyu;Shin, Nam-Soo;Kim, In-Sung;Baik, Sung-Gi
    • Journal of the Korean Ceramic Society
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    • v.43 no.11 s.294
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    • pp.710-714
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    • 2006
  • Barium titanate nanoparticles were synthesized under N$_2$ atmosphere by the hydrolysis and condensation of barium hydroxide octahydrate and titanium (IV) isopropoxide. The synthesized particles were aggregates of nanosized primary particles. The primary particles of about 20-50 nm in diameter became building blocks of larger secondary particles, which are in most cases spherical in shape. The size and morphological evolution of secondary particles are strongly related to the precursor concentration. The observations suggest that formation and control of secondary particles is an essential step in the alkoxidehydroxide sol-precipitation process to obtain monodispersed barium titanate nanopowders.

A Flow Field Analysis of Compound Jets Modified at a 10 Degree Upward Angle ($10^{\circ}$상향분사된 혼합분류의 유동장 해석)

  • 박상규;이용호
    • Journal of Advanced Marine Engineering and Technology
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    • v.24 no.5
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    • pp.103-110
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    • 2000
  • A two phase compound jet, which mixes pulverized solid particles with the air in the test section, is experimentally analyzed in this study. Two phase flow is jetted 10 degree upward in the primary jet, while the secondary jet utilizes the air only. The height difference between the primary and secondary central axises is 32.5mm. The velocity vector field, concentration field, and turbulent properties of solid particles are measured by using 3-Dimensional Particles Dynamics Analyzer. When the jet angle of the secondary jet goes into effect, the solid particle recirculation zone becomes larger. Also, solid particle concentration becomes more dense due to a velocity decrement of particles.

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ULTRA-FINE PARTICLES AND GASEOUS VOLATILE ORGANIC COMPOUND EXPOSURES FROM THE REACTION OF OZONE AND CAR-AIR FRESHENER DURING METROPOLIS TRAVEL

  • Lamorena, Rheo B.;Park, Su-Mi;Bae, Gwi-Nam;Lee, Woo-Jin
    • Environmental Engineering Research
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    • v.12 no.2
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    • pp.72-80
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    • 2007
  • Experiments were conducted to identify the emissions from the car air freshener and to identify the formation of ultra-fine particles and secondary gaseous compounds during the ozone-initiated oxidations with emitted VOCs. The identified primary constituents emitted from the car air freshener in this study were $\alpha$-pinene, $\beta$-pinene, $\rho$-cymene and limonene. Formation of ultra-fine particles (4.4-160 nm) was observed when ozone was injected into the chamber containing emitted monoterpenes from the air freshener. Particle number concentrations, particle mass concentrations, and surface concentrations were measured in time dependent experiments to describe the particle formation and growth within the chamber. The irritating secondary gaseous products formed during the ozone-initiated reactions include formaldehyde, acetaldehyde, acrolein, acetone, and propionaldehyde. Ozone concentration (50 and 100 ppb) and temperature (30 and $40^{\circ}C$) significantly affect the formation of particles and gaseous products during the ozone-initiated reactions. The results obtained in this study provided an insight on the potential exposure of particles and irritating secondary products formed during the ozone-initiated reaction to passengers in confined spaces.

A study on the Chemical Characteristics of secondary particles in Air (대기중 2차 생성입자의 화학적특성에 관한 연구)

  • 박태술;김동술
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.257-258
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    • 2001
  • 대기중 PM의 물리ㆍ화학적 특성은 발생 원의 종류에 따라 큰 차이가 있으며, 발생원에서 직접 배출된 1차 생성입자(Primary particles)와 가스상 물질이 물리ㆍ화학적 반응에 의하여 성장되거나 생성ㆍ변환되어 1차 생성입자와는 전혀 다른 2차 생성입자(Secondary particles)로 황산염, 질산염 및 유기물질 등이 있다. (중략)

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The Characteristics of YAG:Ce Phosphor Powder Prepared Using a NO3--Malonic Acid-NH4NO3-NH3·H2O System

  • Jeong, Jin-An;Park, Kyung-Hwan;Lee, Dong-Hoon;Kim, Hong-Gun;Kim, Yoo-Young
    • Bulletin of the Korean Chemical Society
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    • v.33 no.4
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    • pp.1141-1146
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    • 2012
  • Ce-doped $Y_3Al_5O_{12}$ (YAG:Ce) phosphor powder was prepared using a ${NO_3}^-$-malonic acid-$NH_4NO_3-NH_3{\cdot}H_2O$ system. The YAG:Ce precursor was ignited at $240^{\circ}C$ and the resulting powder contained YAG:Ce crystallites (42%) - active in the visible region at 460 nm - amorphous particles (53%) - inactive at visible wavelengths - and less than 3% oxide (3%) crystallite impurities. The impurities transformed to acitive YAG:Ce crystallites at above $800^{\circ}C$. At above $1000^{\circ}C$, the amorphous phase became YAG phase and isolated $Ce_2O$ crystallites emerged. The powder particles comprised < $4{\mu}m$ secondary aggregates of 20 nm primary particles. The thermal dusting of the secondary particles coincided with the aggregation of the secondary particles at above $900^{\circ}C$.

Synthesis and Characterization of $TiO_2$ Ultrafine Powder by Chemical Vapor Deposition (화학 증착법에 의한 $TiO_2$ 초미분의 제조 및 입자 특성에 관한 연구)

  • 염선민;이성호;김광호
    • Journal of the Korean Ceramic Society
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    • v.32 no.1
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    • pp.37-44
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    • 1995
  • TiO2 fine powders were synthesized using oxygenolysis and hydrolysis reaction of TiCl4 vapor in gas phase. The TiO2 powder synthesized showed morphological differences depending on reaction system as follows: TiCl4-O2 reaction system produced the monosized particles having polyhedral shape with well-defined crystal planes and the particles did not agglomerate into secondary particles. TiCl4-H2O reaction system, whereas, produced the spherical secondary particles which consisted of fine primary particles. Other powder characteristics such as particle size, impurity content and rutile content are also reported in this study.

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Development of DNA Chip Microarray by Using Secondary-step immobilization methods (2단계 고정화법을 이용한 DNA칩 마이크로어레이의 개발)

  • Yoon, Hee-Chan;Kim, Do-Kyun;Shin, Hoon-Kyu;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2002.11a
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    • pp.263-265
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    • 2002
  • We have used the secondary-step immobilization methods based on the chip pattern of hydrophobic self-assembly layers to assemble microfabricated particles onto the chip pattern. Immobilization of DNA, fabrication of the particles and the chip pattern, arrangement of the particles on the chip pattern, and recognition of each using DNA fluorescence measurement were carried out. Establishing the walls, the arrangement stability of the particles was improved. Each DNA is able to distinguish by using the lithography process on the particles. Advantages of this method are process simplicity, wide applicability and stability. It is thought that this method can be applicable as a new fabrication technology to develop a minute integration type biosensor microarray.

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Review of Viscosities and Phases of Biogenic Secondary Organic Aerosols (생물기원 이차유기에어로졸의 점성도와 상 규명에 관한 최근 연구 동향)

  • Song, Mijung
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.4
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    • pp.349-359
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    • 2016
  • Researchers have traditionally assumed that aerosol particles containing secondary organic aerosols (SOAs) are to be in liquid state with low viscosity even at low relative humidity. However, recent measurements showed that SOAs can have high viscosity under certain conditions. Herein, new different techniques for measurements of viscosities of SOA particles are introduced. Moreover, laboratory studies for the viscosities and the phases of biogenic SOAs produced by ${\alpha}$-pinene, isoprene, limonene, and ${\beta}$-caryophyllene of atmospheric relevance are reviewed. Future studies for determination of the phases of atmospheric aerosol particles are also suggested.