• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09b
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• pp.782-783
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• 2006

Titinium carbide $(TiC_x)$ was produced by self-propagating high temperature synthesis (SHS) method. The morphology and non-stoichiometric number of the SHS product were observed by scanning electron microscopy and neutron diffractometry, respectively. Tubular titanium carbide with hole inside was formed with different non-stoichiometric number (x), which value increased with combustion temperature.

• Journal of Powder Materials
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• v.2 no.2
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• pp.158-164
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• 1995

Synthesis of the NiTi shape memory alloy using the thermal explosion mode of the self-propagating high-temperature synthesis has been investigated. The significant fractions of intermetallics phases were found to form at the Ti/Ni powder interface during the heating to the ignition temperature and seemed to influence the relative fraction of phases in the final products. As the heating rate to the ignition temperature was increased, the combustion temperature and the fraction of NiTi in the final reaction products were increased. The synthesis reaction under 70 MPa compressive pressure yielded a reaction product with 98% theoretical density.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2003.10a
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• pp.95-96
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• 2003

Titanium carbide nano-tube and fibers were synthesized by self-propagating high temperature synthesis (SHS) method. The average diameters of the nano-tubes and nano-fibers are about 100 and 20 nm in diameter, respectively. the non-stoichiometric numbers of the titanium carbide determined by neutron diffractometry were 0.87 and 0.94.

• Journal of the Korean Ceramic Society
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• v.32 no.7
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• pp.817-824
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• 1995

TiB2 was simultaneously synthesized and densified with concurrent self-propagating high-temperature synthesis and direct contact-heating by electrcial power input and pressure. Density of TiB2 synthesized by self-propagating high-temperature synthesis and consolidated simultaneously by direct contact-heating and pressure was maximum 80% of the theoretical density (4.52g/㎤). Temperature profile was analyzed by solving heat balance equation with numerical method (FTCS method). The temperature of the sample was sufficiently raised to that temperature sufficient to be densified. It was ascertained that the density of the SHS synthesized TiB2 is exponentially proportinal to the input thermal energy per mass.

• Journal of Powder Materials
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• v.30 no.3
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• pp.233-241
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• 2023

In this study, we evaluated the effects of acid leaching on the properties of Cr powder synthesized using self-propagating high-temperature synthesis (SHS). Cr powder was synthesized from a mixture of Cr2O3 and magnesium (Mg) powders using the SHS Process, and the byproducts after the reaction were removed using acid leaching. The properties of the recovered Cr powder were analyzed via X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), particle size analysis (PSA), and oxygen content analysis. The results show that perfect selective leaching of Cr is challenging because of various factors such as incomplete reaction, reaction kinetics, the presence of impurities, and incompatibility between the acid and metal mixture. Therefore, this study provides essential information on the properties under acidic conditions during the production of high-quality Cr powder using a self-propagating high-temperature synthesis method.

• Journal of Powder Materials
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• v.10 no.1
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• pp.34-39
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• 2003

Porous TiNi bodies were produced by Self-propagating High-temperature Synthesis (SHS) method from a powder mixture of Ti and Ni. Porosity, pore size and structure, mechanical property, and transformation temperature of TiNi product were investigated. The average porosity and pore size of produced porous TiNi body are 63% and $216\mutextrm{m}$, respectively. XRD analysis showed that the major phase of produced TiNi body is B2 phase. Its average fracture strength and elastic modulus measured under dry condition were $22\pm2$ MPa and $0.18\pm0.01$GPa, respectively. It could be strained up to 7.3 %. The transformation temperatures determined by DSC showed the $M_s$ temperature of $67^{\circ}C$ and $A_f$ temperature of $99^{\circ}C$.

• Journal of Powder Materials
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• v.9 no.2
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• pp.96-102
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• 2002

In the present study, equiatomic porous TiNi shape-memory alloys have been successfully prepared by self-propagating high-temperature synthesis (SHS) using elemental titanium and nickel powders. The porous TiNi alloys thus obtained have an open porous structure with about 64 vol.% porosity, and the pore size is about 1.8 mm. The effect of preheating temperature on the microstructure have been investigated. It is found that the pore size increases with increasing preheating temperature. Moreover, the preheating temperature was shown to have a significant effect on the microstructrue of the SHS-synthesized porous TiNi shape memory alloys.

• Journal of the Korean Society for Precision Engineering
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• v.15 no.12
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• pp.120-127
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• 1998

The finite element method has been used to model and analyze the heat transfer phenomena during manufacturing process of $MoSi_2$ by SHS(Self-propagating High-temperature Synthesis). For this purpose nonlinear transient heat transfer analyses by using ANSYS have been performed to estimate the temperature distributions and the peak temperature in the test specimen. The effects of manufacturing process parameters such as pre-heating temperatures, the velocity of reaction zone have been investigated. The results of the analysis have been compared with the experimental results.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2000.11a
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• pp.11-12
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• 2000

Non-stoichiometric ceramics of $Ni_{x}ZnO_{1-x}Fe_{2}O_{4}$ were prepared by self-propagating high temperature synthesis reaction with various processing conditions and their stoichometric numbers were determined by neutron diffraction. The neutron diffraction patterns were measured at room temperature using monochromatic neutrons with a wave length of 0.18339 nm from a Ge(331) mocochromator at a 90 degree take off angle. The Rietveld refinement of each pattern converged to good agreement (x2=1.88-2.24). The neutron diffraction analysis revealed the final stoichiometries of the ferrites were $Ni_{0.38}Zn_{0.62}Fe_{2}O_{4}$ and $Ni_{0.33}Zn_{0.67}Fe_{2}O_{4]$, respectively. This supports that final stoichiometric number of the self-propagating high temperature synthesis product can be controlled by the processing parameters during the combustion reaction.

• Journal of the Korean Ceramic Society
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• v.35 no.7
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• pp.749-756
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• 1998

TiC-Ni and TiC-Ni-Mo cermet powders were produced by Self-propagating High temperature Synthesis (SHS) process. The cooling rate of synthesized powders were controlled by using the V-shaped copper jig and the carbide size decreased with increasing the cooling rate I. e decreasing the width of copper jig Round shape carbide particles were produced after SHS reaction in TiC-Ni as well as TiC-Ni-Mo powders. Local segregation of Mo rich phases was observed in SHS powder of TiC-Ni-Mo and the uneven dis-triobution of Mo promoted the faster growth rate of carbide particles during sintering compared to the same composition specimen with commercial TiC powder. Howogeneous microstructure of TiC-Ni-Mo cermet was obtained when the elemental Mo powder was mixed with the SHS powder of TiC-Ni.