• 제목/요약/키워드: Silicones

검색결과 38건 처리시간 0.041초

Synthesis and Photopolymerization of Vinyl Ether and Epoxy-Functionalized Silicones

  • Pyun, Sang-Yong;Kim, Whan-Gi
    • Macromolecular Research
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    • 제11권3호
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    • pp.202-205
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    • 2003
  • The reactive precursors, vinyl ethers, and epoxy-silicones, were synthesized. The vinyl ether monomers were prepared from primary alcohol and ethyl vinyl ether with mercury (II) acetate. The epoxy-functionalized silicones have been achieved by the controlled, rhodium-catalyzed, chemoselective hydrosilation of vinyl ether with siloxanes or silane. It was shown that the hydrosilation proceeds exclusively at the vinyl ether group of alkenyl vinyl ether without participation at the alkenyl group. The photoinduced cationic polymerization of these monomers was studied and found to be all highly reactive.

실리콘 코팅을 이용한 poly(ethylene naphthalate) 고온용 방열 필름의 제조 (Preparation of Poly(ethylene naphthalate) Film Coated with Silicones for High Temperature Insulator)

  • 이수;나차수
    • 한국응용과학기술학회지
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    • 제24권2호
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    • pp.167-173
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    • 2007
  • The surface of poly(ethylene naphthalate) film applicable to high temerature insulator for convection microwave oven was modified with silicone coating solutions in the presence of silane crosslinking agent. The structure and properties of the PEN films were investigated by using Fourier transform IR spectroscopy, viscometry, microscopy, and tensile tests. The experimental results showed that the coating with silicone enhanced thermal stability up to $200^{\circ}C$, and slightly lowered the tensile strength and elongation of the PEN films. Judging from dimensional stability results the silicone coated PEN films can not be used for higher temperature insulator above $230^{\circ}C$. Serious dimensional contraction of films was obtained during heat treatment at $250^{\circ}C$ even for 1h. However, the surface of those films still have same chemical structure of silicones. Therefore, If we use PEN film prestretched at $230^{\circ}C$ as base one it will be possible to prepare a high temperature insulator up to $230^{\circ}C$. Conclusively, a silicone coated PEN film can be suitable for the application to convection microwave oven door insulator at high temperature up to $230^{\circ}C$.

Thermal Management Pre-Applied Underfill

  • 신준호
    • 한국마이크로전자및패키징학회:학술대회논문집
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    • 한국마이크로전자및패키징학회 2005년도 국제표면실장및인쇄회로기판생산기자재전 전자패키지 기술세미나
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    • pp.11-28
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    • 2005
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$ULTRASIL^{TM}$ ANIONIC SILICONES - Complexing Agents for Quaternary Compounds

  • B. Vondruska
    • 대한화장품학회:학술대회논문집
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    • 대한화장품학회 2003년도 IFSCC Conference Proceeding Book II
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    • pp.460-461
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    • 2003
  • Clear rinse-off ...gels can be prepared. allowing the introduction of novel product forms. Styling gels with improved viscosity, conditioning. clarity and product aesthetics are also possible with this concept. Beyond the creation of clear product.(omitted)

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Augmentation Mammaplasty Using Implants: A Review

  • Takayanagi, Susumu
    • Archives of Plastic Surgery
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    • 제39권5호
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    • pp.448-451
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    • 2012
  • One of the techniques for augmentation mammaplasty is the procedure using implants. Even though this technique has been used for many years, there are still several controversial issues to be discussed and overcome for patient safety. In this review article, capsular contracture, leak or rupture of the implants, possible systemic disease, relation with breast cancer, and recent problems with Poly Implant Prothese implants are described and discussed.

오일이 페녹시에탄올의 유.수상 분배계수에 미치는 영향 (The effect of Oil-aqueous phase Partition Coefficients of Phenoxyethanol according to Oils)

  • 조선웅;이영근;김미정
    • 한국산학기술학회:학술대회논문집
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    • 한국산학기술학회 2009년도 추계학술발표논문집
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    • pp.390-394
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    • 2009
  • 최근 화장품에 널리 사용되고 있는 페녹시에탄올에 대하여 오일의 종류가 유 수상 분배계수에 미치는 영향을 연구하였다. 분배계수의 측정은 오일을 탄화수소류, 고급지방산류, 고급알콜류, 에스테르류, 트리글리세라이드류 및 실리콘류로 구분하여 실험하였다. 실험결과 탄화수소류 및 실리콘류 오일은 유 수상 분배계수가 낮은 반면, 고급지방산류, 고급알콜류, 에스테르류 및 트리글리세라이드류 오일의 유 수상 분배계수는 높았다. 이는 탄화수소류 및 실리콘류 오일을 혼합한 경우 다른 오일을 사용한 경우에 비해 수상에 존재하는 페녹시에탄올의 농도가 높음을 나타낸다. 화장품에서의 방부력은 수상에 존재하는 방부제의 함량이 크게 좌우함으로 위의 실험 결과를 토대로 화장품에 혼합하는 오일을 조정함에 의해 페녹시에탄올의 함량이 적은 저자극의 화장품 처방을 구성할 수 있으리라 사료된다.

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세라믹 분말의 입자구조에 따른 나노 진동 흡수장치의 에너지 소산 효율 특성에 대한 연구 (Characteristics of Energy Dissipation in Vibration Absorbing Nano-Damper According to the Architecture of Silica Particle)

  • 문병영;김흥섭
    • 한국재료학회지
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    • 제13권3호
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    • pp.144-149
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    • 2003
  • This study shows an experimental investigation of a reversible nano colloidal damper, which is statically loaded. The porous matrix is composed from silica gel (labyrinth or central-cavity architecture), coated by organo-silicones substances, in order to achieve a hydrophobic surface. Water is considered as associated lyophobic liquid. Reversible colloidal damper static test rig and the measuring technique of the static hysteresis are described. Influence of the pore and particle diameters, particle architecture and length of the grafted molecule upon the reversible colloidal damper hysteresis is investigated, for distinctive types and mixtures of porous matrices. Variation of the reversible colloidal damper dissipated energy and efficiency with temperature, pressure, is illustrated. As a result, he proposed nano damper is effective one, which can be replaced the conventional damper.

Size Control of Silicone Particles Using Sonochemical Approaches

  • Jhung, Sung-Hwa;Yoo, Ki-Cheon;Hwang, Young-Kyu;Chang, Jong-San
    • Bulletin of the Korean Chemical Society
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    • 제28권12호
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    • pp.2401-2404
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    • 2007
  • Particle size of silicones can be controlled by changing the reaction conditions such as temperature and concentrations of water and tetramethoxysilane (TMOS). Alternatively, the use of ultrasound radiation is also an elegant technique to decrease the particle size. Small silicone particles can be obtained at low temperature from diluted reagent containing TMOS, especially under the powerful ultrasound radiation. The size control may be explained by the rate of particle growth rather than that of nucleation.