• 제목/요약/키워드: Sol-gel methode

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졸-겔법으로 $LaNiO_3$ 전극에 증착된 $(Na_{0.5}Bi_{0.5})TiO_3$ 박막의 배향성 (Orientation of $(Na_{1/2}Bi_{1/2})TiO_3$ thin films deposited on $LaNiO_3$ electrodes by sol-gel methode)

  • 박민석;유영배;문병기;손세모;정수태
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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    • pp.894-897
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    • 2004
  • Sodum bismuth titanate $(Na_{0.5}Bi_{0.5}TiO_3$ or NBT) thin films coated on the $LaNiO_3$ (LNO) electrode by sol-gel methode and rapid thermal annealing (RTA) technique. The NBT (NBT/LNO/Si) thin films examined by x-ray diffraction (XRD). The orientation of NBT was observed for films coated at $900^{\circ}C$, 5 min and $600^{\circ}C$, 60 min. Filed emission scanning electron microscopy (FE-SEM) showed uniform surface composed of grains. The grain size of NBT thin films increased with increasing annealing temperature.

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염기성 촉매제를 이용한 염료감응 태양전지의 효율에 관한 연구 (A Study on the Efficiency of Dye Sensitized Solar Cell Employing TiO2 Photoelectrode Synthesized Using Basic Catalyst)

  • 기현철;정행윤;구할본
    • 한국전기전자재료학회논문지
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    • 제26권10호
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    • pp.736-740
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    • 2013
  • In this study, the influence of electrochemical properties by mixing Tetrabutylammonium hydroxide (TBAOH) and ammonium hydroxide (NH4OH) electrode on the dssc. The titanias were prepared using a sol-gel method by mixing Tetrabutylammonium hydroxide and Ammonium hydroxide. The $TiO_2$ nanopowder prepared by sol-gel methode, and to improve the distributed properties of $TiO_2$ nanopowder, the TBAOH and NH4OH was added. The I-V values of cells show that the Tetrabutylammonium has 6.51% efficiency.

Low Temperature Synthesis and Characterization of Sol-gel TiO2 Layers

  • Jin, Sook-Young;Reddy, A.S.;Park, Jong-Hyurk;Park, Jeong-Young
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.353-353
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    • 2011
  • Titanium dioxide is a suitable material for industrial use at present and in the future because titanium dioxide has efficient photoactivity, good stability and low cost [1]. Among the three phases (anatase, rutile, brookite) of titanium dioxide, the anatase form is particularly photocatalytically active under ultraviolet (UV) light. In fabrication of photocatalytic devices based on catalytic nanodiodes [2], it is challenging to obtain a photocatalytically active TiO2 thin film that can be prepared at low temperature (< 200$^{\circ}C$). Here, we present the synthesis of a titanium dioxide film using TiO2 nanoparticles and sol-gel methods. Titanium tetra-isopropoxide was used as the precursor and alcohol as the solvent. Titanium dioxide thin films were made using spin coating. The change of atomic structure was monitored after heating the thin film at 200$^{\circ}C$ and at 350$^{\circ}C$. The prepared samples have been characterized by X-ray diffraction (XRD), scanning electron microcopy, X-ray photoelectron spectroscopy, transmission electron microscopy, ultraviolet-visible spectroscopy (UV-vis), and ellipsometry. XRD spectra show an anatase phase at low temperature, 200$^{\circ}C$. UV-vis confirms the anatase phase band gap energy (3.2 eV) when using the photocatalyst. TEM images reveal crystallization of the titanium dioxide at 200$^{\circ}C$. We will discuss the switching behavior of the Pt /sol-gel TiO2 /Pt layers that can be a new type of resistive random-access memory.

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바인더 함량에 따른 염료감응 태양전지의 효율에 관한 연구 (A Study on the Efficiency of Dye Sensitized Solar Cell Based on the Volume of Binder Addition)

  • 기현철;정행윤;구할본
    • 한국전기전자재료학회논문지
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    • 제26권12호
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    • pp.878-881
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    • 2013
  • In this study, we have fabricated the dye sensitized solar cell (DSSC) composed by a transparent conductive oxide (TCO), a nanocrystalline semiconductor film usually $TiO_2$, a sensitizer adsorbed on the surface of the semiconductor, an electrolyte containing a redox mediator and a counter electrode. The $TiO_2$ nanopowder was prepared by sol-gel methode. The HCl (hydrochloric acid) and TBAOH (Tetrabutyl amonium hydroxide) was added for improving the catalyst and distributed properties of $TiO_2$ nanopowder. Ammonium hydroixde was added in order to control the morphology and size of $TiO_2$ nano crystal. A $TiO_2$ paste for working electrode was prepared with the addition of HPC (hydroxypropyl cellulos) used as a binder of which volume was controled as 1.3, 1.5, 1.7, and 2.0%. The measured I-V curves of assembled DSSC showed that the cell with 1.7% HPC binder had the best efficiency of 6.79%.

Na고체전해질의 제조방법에 따른 CO2감응 특성연구 (A Study on Characteristics to Fabrication Methode of Na Solid Electrolyte)

  • 곽종식;최순돈;이덕동
    • 한국전기전자재료학회논문지
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    • 제20권9호
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    • pp.761-765
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    • 2007
  • NASICON sensors compare properties with manufacture method in order to improve $CO_2$ sensitivity and stability the sensing behaviors. Oxidation mixing method and Sol-gel method were compare analyze to characteristic in which each other sintered to $900^{\circ}C\;to\;1100^{\circ}C$ and NASICON $CO_2$ gas sensors were fabricate. Oxidation mixing method showed better sensing properties at sintered $1100^{\circ}C$ result to NASICON electrolyte analyze with manufacture methods.

Ramp Loading Scratch 방법을 이용한 상용 HDD Media와 ZnO박막소재의 Scratch 특성에 관한 연구 (Study on Scratch Characteristics of HDD Media and ZnO Thin Films by Ramp Loading Scratch Method)

  • 김대은;이정은;린리위
    • Tribology and Lubricants
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    • 제24권2호
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    • pp.77-81
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    • 2008
  • In this work, ramp loading scratch method was used to evaluate the scratch characteristics of HDD media and ZnO thin films. Commercially available HDD media and ZnO thin films grown on silicon(100) substrate by sol-gel method were used. As for the ZnO films, the effects of annealing temperature after the film deposition process were also investigated. A custom built scratch tester was used to scratch the specimen under a ramp loading condition. The scratch track formed by ramp loading was measured by optical microscope and Atomic Force Microscopy (AFM). The wear depth and width were used to assess the scratch characteristics of the HDD Media and ZnO thin films. The results showed that ZnO film annealed at $800^{\circ}C$ had the best scratch resistance property. Also, the HDD media showed overall better scratch resistance than the ZnO films.

리튬2차전지용 층상계 $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$의 표면개질에 따른 전지특성 변화 (Battery Performances of with Surface Treatment of Layered $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ Materials in Lithium Secondary Batteries)

  • 김현수;공명철;김기택;문성인;윤문수;김우성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.348-349
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    • 2006
  • $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ cathode material was synthesized by a mixed hydroxide methode. The surface of the $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ was coated with a carbon by using a sol-gel method to improve further its electrochemical properties. Electrochemical studies were performed by assembling 2032 coin cells with lithium metal as an anode. OSC (differential scanning calorimetry) data showed that exothermic reactions of charged to 4.3V vs. Li was suppressed in the carbon-coated materials. The carbon-coated $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ showed the improved rate capability and thermal stability.

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