• Title/Summary/Keyword: Solution Mixing Method

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Dispersibility, Electrical Property of Nano-Composite by Solution Mixing Method (용액혼합법에 따른 나노복합재료 분산성 및 전기적 특성)

  • Yang, Hoon;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04c
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    • pp.73-74
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    • 2008
  • In this paper, we have investigated dispersibility, volume resistivity of nano-composite by solution mixing method. Dispersibility measured by FE-SEM(Field Emission Scanning Electron Microscope. And volume resistivity measured by ASTM D991. To expect interaction used dual filler system. But, dual filler system had influence on polymer complex. So, polymer chain mobility doesn't resist.

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The Relation between Vortex Index and Mixing Index in Micromixer;Insoluble Solution;Insoluble Solution (마이크로 믹서에서 와도 지수와 혼합 지수의 관계;비용해성 물질)

  • Maeng, Joo-Sung;Kim, Bum-Joong;Cho, Il-dae
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.1841-1844
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    • 2004
  • 'Mixing Index($D_I$)'s generally used to measure the degree of mixing. A new method to calculate $D_I$ was proposed, when insoluble solution flows in micromixer. 'Vortex Index (${\Omega}_I$)'which indicate the degree of chaotic advection, is defined and formulated. A lots of arbitrary shaped microchannels were tested to calculate the $D_I$ and ${\Omega}_I$. And then a simple algebraic equation, $D_I=A{\Omega}_I+B$, was obtained. This equation may be used instead of partial differential equation, concentration equation.

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Prediction of partial molar volumes of solutes in supercritical CO2 using the Peng-Robinson equation of state with various mixing rules and Kirkwood-Buff solution theory (3차 상태방정식과 여러 혼합법칙 및 Kirkwood-Buff용액이론을 이용한 초임계유체내에서의 용질의 무한희석 부분몰부피의 계산)

  • Jeon, Young-Pyo;Park, Jong-Seon;Kwon, Yong-Jung
    • Journal of Industrial Technology
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    • v.19
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    • pp.253-260
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    • 1999
  • Two thermodynamic models were used to predict the partial molar volumes of solutes in supercritical carbon dioxide at infinite dilution: (1) the Peng-Robinson equation of state with various mixing rules including those based on $EOS/G^E$ (2) the Kirkwood Buff fluctuation integral with the hard sphere expansion (HSE) method. The Kirkwood-Buff fluctuation integral method, in which an equation of state for pure component and molecular parameters are required, produced better results especially near the critical point than the Peng-Robinson equation of state with the several mixing rules based an $EOS/G^E$. When the $EOS/G^E$ mixing rules were used, poorer results were obtained compared with the classical mixing rule and Kirkwood-Buff model.

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A Mixing Time Measurement by a Conductivity Method in a Continuous Flow Stirred Tank (電氣傳導度 測定에 依한 連續流 攪拌槽의 混合時間 測定)

  • Kang, Woong-Ki
    • Journal of the Korean Chemical Society
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    • v.6 no.2
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    • pp.130-132
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    • 1962
  • A new method of evaluating the mixing time in the continuous flow stirred tank is herein proposed. Experimental results to test the concept are also presented.The mixing time is defined as the time interval between the injection of a slug of an electrolyte solution into the tank and the moment at which an essentially straight line begins on a plot of the conductivity of effluent versus time.The proposed method of measuring the mixing time is valid even for the low mixing time (5 seconds) and the results obtained agree well with previous work, where the mixing time measurements were carried out by the injection of a dye into the feed stream.

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Prediction of Degree of Mixing for Insoluble Solution with Vortex Index in a Passive Micromixer (마이크로 믹서에서 와도 지수에 의한 비용해성 물질의 혼합 예측)

  • Cho Il-dae;Kim Bum-joong;Maeng Joo-sung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.2 s.233
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    • pp.232-238
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    • 2005
  • The 'Mixing Index($D_I$)' is used as a conventional guidance measuring the degree of mixing for multiphase flows. For the case when insoluble solutions flow in a passive micromixer, a new method to calculate $D_I$ is proposed. The 'Vortex Index(${\Omega}_I$)' is suggested and formulated. We infer that ${\Omega}_I$ relates to the degree of chaotic advection. Various arbitrary shaped microchannels were tested to calculate the $D_I\;and\;{\Omega}_I$, and then a simple algebraic equation, $D_I=Aexp(B{\Omega}_I)$, is obtained. This equation may be used instead of the conventional partial differential equation, concentration equation, to estimate the degree of mixing.

The Properties of OPC-Slag Cement Mixed with Nano-Silica Solution by Mixing Water Weight Replacement Method (나노실리카 졸을 배합수 중량치환 방법으로 혼합한 OPC-slag cement의 특성)

  • Seo, Ki-Young;Kim, Taewan;Kim, Seong-Do
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.1
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    • pp.24-34
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    • 2020
  • This research is a study on the characteristics of OPC-slag cement using nano-silica solution (NSS) with water-weight substitution method. The new replacement method is a fundamental step to study the behavior of cement with higher NSS replacement rates than previous studies. NSS was replaced by 10%, 20%, 30%, 40%, and 50% of the mixing water weight. As a result, the mechanical and microstructural characteristics were improved. This can be summarized in two ways. First, when the NSS is replaced with mixing water, the homogeneous dispersion action of the nano-silica particles is improved. This promotes initial hydration. Second, substitution of NSS with higher density than mixing water reduces w / b. This forms a dense hydration reaction material. The new substitution method did not show any degradation of mechanical and microstructural properties as compared with the results using the powdered nano-silica particles revealed in the previous study. Therefore, it is considered that the method of weight substitution of NSS used in this study can be applied to the formulation of OPC-slag cement.

$^7Li$ NMR studies of LiMn$_2$O$_4$ prepared by eutectic self-mixing method without any mixing

  • Lee, Youngil;Kyooseung Han;Hyunkoo Kang;Jaebum Choo
    • Proceedings of the Korean Magnetic Resonance Society Conference
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    • 2002.08a
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    • pp.85-85
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    • 2002
  • Lithiated transition metal oxides such as LiMn2O4, Lil-xMnO$_2$, LiNiO$_2$, LiCoO$_2$, and their solid solution phases are used as cathode materials for lithium rechargeable batteries. We prepared the cathode materials using a novel eutectic self-mixing method without any artificial mixing procedures. This method provides an extraordinarily simple way to make the cathode materials, and it is possible to prepare at very low temperature such as 25$0^{\circ}C$. Furthermore, the cathode materials produced have discharge capacities that are much better than cathode materials prepared by previously reported synthetic methods. The spontaneous and homogeneous mixing is verified by $^{7}$ Li magic-angle-spinning (MAS) NMR spectroscopy.

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Mechanical Properties of Carbon Nanofiber Reinforced Hybrid Composites (탄소나노섬유가 강화된 하이브리드 복합재료의 기계적 물성)

  • Kong Jin-Woo;Chung Sang-Su;Kim Tae-Wook
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.31-34
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    • 2004
  • Carbon nanofiber exhibits superior and often unique characteristics of mechanical, electrical chemical and thermal properties. In this study, For improvement of the mechanical properties of composites, carbon nanofiber reinforced hybrid composites was investigated. For the effect of dispersion, The dispersion methods of solution blending and mechanical mixing were used. The mixing of solution blending method was used using ultrasonic. Dispersion of carbon nanofiber was observed by scanning electron microscope (SEM). Mechanical properties were measured by universal testing Machine (UTM).

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The Free Energy of Mixing for a Binary Lattice Solution Consisting of Two Identical Interpenetrating Sublattices (두개의 동등한 상호침투 부격자로 구성된 이성분 격자 용액의 혼합자유에너지)

  • Jung, Hae-Young
    • Journal of the Korean Chemical Society
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    • v.66 no.4
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    • pp.278-283
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    • 2022
  • Using the Kirkwood's method, the free energy of a binary lattice solution consisting of two identical interpenetrating sublattices, such as a simple cubic lattice or a body-centered cubic lattice, was calculated up to the tenth order of the reciprocal of absolute temperature. Using this, liquid-liquid coexistence curves and critical solution temperatures for the binary lattice solutions were calculated to quantitatively investigate the effect of non-random mixing of molecules. And it was shown that the coexistence curve of the simple cubic lattice solution was in good agreement with the Monte-Carlo computer simulation result.

Chemical Solution Mixing and Hydrogen Reduction Method for Fabrication of Nanostructured Fe-Co Alloy Powders (화학용액 혼합과 수소환원법을 이용한 나노구조 Fe-Co 합금분말의 제조)

  • 박광현;박현우;이백희;장시영;이정근;김영도
    • Journal of Powder Materials
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    • v.11 no.2
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    • pp.137-142
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    • 2004
  • In this study, chemical solution mixing and hydrogen reduction method was used to fabricate nanostructured $Fe_xCo_{1-x}$ alloy powders. Fe-Co chloride mixture, FeCl$_2$ and COCI$_2$ with 99.9% purity, were reduced in hydrogen atmosphere. Nanostructured Fe-Co alloy powders with a grain size of 50 nm were successfully fabricated. Magnetic properties of fabricated $Fe_xCo_{1-x}$(x=0, 10, 30, 50, 70, 100) alloy powders with the same grain size were measured because size factor can affect magnetic properties. Coercivity of Fe-Co alloy powders were increased with increasing Co contents. Maximum value of coercivity in various Co contented Fe-Co alloy powders with similar grain size was 125 Oe at Fe$_{100}$. Saturation magnetization value at Fe$_{70}$Co$_{30}$ composition showed maximum value of 219 emu/g and saturation magnetization value decreased with increasing Co contents and minimum value of 155 emu/g was observed at Co$_{100}$.