• Title/Summary/Keyword: Soot Particulate

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Overview of the Effect of Catalyst Formulation and Exhaust Gas Compositions on Soot Oxidation In DPF

  • Choi Byung Chul;FOSTER D.E.
    • Journal of Mechanical Science and Technology
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    • v.20 no.1
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    • pp.1-12
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    • 2006
  • This work reviews the effects of catalyst formulation and exhaust gas composition on soot oxidation in CDPF (Catalytic Diesel Particulate Filter). DOC's (Diesel Oxidation Catalysts) have been loaded with Pt catalyst (Pt/$Al_{2}O_3$) for reduction of HC and CO. Recent CDPF's are coated with the Pt catalyst as well as additives like Mo, V, Ce, Co, Fe, La, Au, or Zr for the promotion of soot oxidation. Alkali (K, Na, Cs, Li) doping of metal catalyst tends to increase the activity of the catalysts in soot combustion. Effects of coexistence components are very important in the catalytic reaction of the soot. The soot oxidation rate of a few catalysts are improved by water vapor and NOx in the ambient. There are only a few reports available on the mechanism of the PM (particulate matter) oxidation on the catalysts. The mechanism of PM oxidation in the catalytic systems that meet new emission regulations of diesel engines has yet to be investigated. Future research will focus on catalysts that can not only oxidize PM at low temperature, but also reduce NOx, continuously self-cleaning diesel particulate filters, and selective catalysts for NOx reduction.

Prediction of Particulate Matter Being Accumulated in a Diesel Particulate Filter (디젤 매연 필터에서 퇴적되는 입자상 물질의 퇴적량 예측)

  • Yu, Jun;Chun, Je-Rok;Hong, Hyun-Jun
    • Transactions of the Korean Society of Automotive Engineers
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    • v.17 no.3
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    • pp.29-34
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    • 2009
  • Diesel particulate filter (DPF) has been developed to optimize engine out emission, especially particulate matter (PM). One of the main important factors for developing the DPF is estimation of soot mass being accumulated inside the DPF. Evaluation of pressure drop over the DPF is a simple way to estimate the accumulated soot mass but its accuracy is known to be limited to certain vehicle operating conditions. The method to compensate drawback is adoption of integrating time history of the engine out PM and burning soot. Present study demonstrates current status of the soot estimation methods including the results from the engine test benches and vehicles.

Study on Soot Primary Particle Size Measurement in Ethylene Diffusion Flame by Time-Resolved Laser-Induced Incandescence (시분해 레이저 유도 백열법을 이용한 에틸렌 확산 화염에서의 매연 일차입자크기 측정에 관한 연구)

  • Kim Gyu-Bo;Cho Seung-Wan;Lee Jong-Ho;Jeong Dong-Soo;Chang Young-June;Jeon Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.10 s.253
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    • pp.973-981
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    • 2006
  • Recently there is an increasing interest in particulate matter emission because of new emission regulations, health awareness and environmental problems. It requires to improve particulate measurement techniques as well as to reduce soot emissions from combustion systems. As mentioned above, it is demanded that reduction techniques together with measurement techniques of exhausted particulate matters in combustion systems such as vehicles. However, measurement techniques of particulate matters should be prior to reduction techniques of that because it is able to know an increase and a decrease of exhausted particulate matters when measured particulate matters. Therefore, in this study, we report the measurement of soot primary-particle size using time-resolved laser induced incandescence (TIRE-LII) technique in laminar ethylene diffusion flame. As an optical method, laser induced incandescence is one of well known methods to get information for spatial and temporal soot volume fraction and soot primary particle size. Furthermore, TIRE-LII is able to measure soot primary particle size that is decided to solve the decay ate of signal S $(t_1)$ and S $(t_2)$ at two detection time. In laminar ethylene diffusion flame, visual flame height is 40 mm from burner tip and measurement points are height of 15, 20, 27.5, 30 mm above burner tip along radial direction. As increasing the height of the flame from burne. tip, primary particle size was increased to HAB(Height Above Burner tip)=20mm, and then decreased from HAB=27.5 mm to 30 mm. This results show the growth and oxidation processes for soot particles formed by combustion.

DETAILED EXAMINATION OF INVERSE-ANALYSIS PARAMETERS FOR PARTICLE TRAPPING IN SINGLE CHANNEL DIESEL PARTICULATE FILTER

  • Jung, S.C.;Park, J.S.;Yoon, W.S.
    • International Journal of Automotive Technology
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    • v.8 no.2
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    • pp.165-177
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    • 2007
  • Predictions of diesel particulate filtration are typically made by modeling of a particle collection, and providing particle trapping levels in terms of a pressure drop. In the present study, a series of single channel diesel particulate filter (DPF) experiments are conducted, the pressure traces are inversely analyzed and essential filtration parameters are deducted for model closure. A DPF filtration model is formulated with a non-linear description of soot cake regression. Dependence of soot cake porosity, packing density, permeability, and soot density in filter walls on convective-diffusive particle transportation is examined. Sensitivity analysis was conducted on model parameters, relevant to the mode of transition. Soot cake porosity and soot packing density show low degrees of dispersion with respect to the Peclet number and have asymptotes at 0.97 and $70\;kg/m^3$, respectively, at high Peclet number. Soot density in the filter wall, which is inversely proportional to filter wall Peclet number, controls the filtration mode transition but exerts no influence on termination pressure drop. The percolation constant greatly alters the extent of pressure drop, but is insensitive to volumetric flow rate or temperature of exhaust gas at fixed operation mode.

Experimental Study on Estimation of Oxidation Rate of PM inside of Diesel Particulate Filter (DPF내 포집된 입자상 물질의 산화율 산출을 위한 실험적 연구)

  • Shim, Beomjoo;Park, Kyoungsuk;Jo, Kyuhee;Lee, Hyeongjun;Min, Byeongdu
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.2
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    • pp.98-103
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    • 2013
  • Conventional method to estimate mass of particulate matter accumulated in diesel particulate filter is to use pressure difference between upstream and downstream of the filter. Then measured pressure difference should be compared that of clean condition which is no particulate matter accumulated in DPF. During regeneration soot oxidation is also estimated by same method. This methodology, however, has demerit on accuracy because of pressure difference deviation of clean DPFs and pressure difference caused by non-carbon based PM which is different from that of caused by carbon based PM. This study suggests new methodology to estimate accumulated soot oxidation rate through exhaust gas characteristics during regeneration. Results, more high accuracy of soot oxidation was obtained by analysis of relationship between fuel mass and concentration of carbon dioxide and oxygen.

Rigorous Modeling of Single Channel DPF Filtration and Sensitivity Analysis of Important Model Parameters (단일 채널 DPF의 PM 포집 모델링 및 모델 파라미터의 민감도 해석)

  • Jung, Seung-Chai;Park, Jong-Sun;Yoon, Woong-Sup
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.6
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    • pp.127-136
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    • 2006
  • Prediction of diesel particulate filtration is typically made by virtue of modeling of particulate matter(PM) collection. The model is closed with filtration parameters reflecting all small scale phenomena associated with PM trapping, and these parameters are to be traced back by inversely analyzing large-scale empirical data-the pressure drop histories. Included are soot cake permeability, soot cake density, soot density in the porous filter wall, and percolation constant. In the present study, a series of single channel DPF experiment is conducted, pressure histories are inversely analyzed, and the essential filtration parameters are deducted by DPF filtration model formulated with non-linear description of soot cake regression. Sensitivity analyses of model parameters are also made. Results showed that filtration transients are significantly altered by the extent of percolation constant, and the soot density in the porous filter wall is controlling the filtration qualities in deep-bed filtration regime. In addition, effect of soot particle size on filtration quality is distinct in a period of soot cake regime.

Comparative Studies on Soot Oxidation by Nitrogen Dioxide and Ozone

  • Purushothama, C.;Chen, Xin-Hong;Li, Ming-Wei;Chae, Jae-Ou;Sim, Ju-Hyen
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.117-121
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    • 2006
  • Non-thermal plasma technology has many applications in various areas. One of the applications is regenerating diesel particulate filter (DPF). DPF is a widely applied device to control the particulate emission of diesel engines. But it needs periodic removal of clogged soot for the smooth running of engine. Conventional high-temperature removal processes easily leads to the breakage of DPF. Herein, low-temperature plasma formed in a dielectric barrier discharge (DBD) reactor was used to form active oxidants such as ozone and nitrogen dioxide. Experimentally, the effects of discharge power and frequency on the performance of DBD reactor were studied. Two oxidants, $O_3$ and $NO_2$, were synthesized and used for incinerating soot in the used DPF. Performances of the two oxidants on the reduction of soot were compared, and it was found that $NO_2$ is more effective than $O_3$ for getting rid of soot

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An Experimental Study on Effects of Soot Loading and Mass Flow Rate on Pressure Drop and Heat Transfer in Catalyzed Diesel Particulate Filter (촉매 코팅 DPF의 soot loading과 유량 변화에 따른 압력강하 및 열전달에 관한 실험적 연구)

  • Cho, Yong-Seok;Noh, Young-Chang;Park, Young-Joon;Kim, Duk-Sang
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.3
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    • pp.72-78
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    • 2007
  • A diesel particulate filter causes progressive increase in back pressure of an exhaust system due to the loading of soot particles. To maintain the pressure drop caused by DPF under proper level, a regeneration process is mandatory when excessive loading of soot is detected in the filter. It is a major reason why the relation between the amount of soot and the pressure drop in a DPF becomes crucial. On the other hand, pressure drop varies with not only the soot loading but also conditions of exhaust gas such as mass flow rate. Therefore, the relation among them becomes complicated. Furthermore, the characteristics of heat transfer in a DPF is another crucial parameter in order for the filter to avoid thermal crack during regeneration period. This study presents characteristics of pressure drop under various conditions of soot loading and mass flow rate in catalyzed diesel particulate filter. This study also shows characteristics of heat transfer in DPF when high temperature gas flows into the filter. Experiments reveal that the soot loading and mass flow rate affect characteristics pressure drop independently. Experiments also indicate that the amount of coating material has little influence on pressure drop with changes in soot loading and mass flow rate. However, increased catalyst coating may lead to the improved heat transfer which is efficiency to reduce thermal stress of the filter.

Combined Application of Burner and Oxidation Catalyst for Diesel Particulate Filter Regeneration (DPF 재생을 위한 버너-산화촉매 복합 적용)

  • Shim, Sung-Hoon;Jeong, Sang-Hyun
    • Journal of the Korean Society of Combustion
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    • v.15 no.3
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    • pp.25-31
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    • 2010
  • Combined technique of burner and DOC has been used for regeneration of Diesel Particulate Filter. Experiments has been performed to increase the temperature of engine exhaust gas to burn the collected soot in DPF at all conditions of operation of 3 liter diesel engine. Ignition temperature of soot can be successfully obtained by heats of burner flame and residual fuel oxidation at diesel oxidation catalyst even in the condition of oxygen deficiency. It is found that the load of air compressor and heat loss can be reduced to the level of practical application. It is also found that CO and THC emissions are not increase by additional combustion of regeneration burner.

Comparison of removal efficiency of diesel particulate filter with different measurement methods in a high-speed marine diesel engine (선박용 고속 디젤엔진에 적용한 디젤미립자 필터의 측정방법에 따른 입자상물질 저감효율 비교 연구)

  • Lee, Ik-Sung;Ko, Dong-Kyun;Moon, Gun-Feel;Nam, Youn-Woo;Kim, Shin-Han;Oh, Young-Taig
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.4
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    • pp.362-367
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    • 2017
  • This study was conducted to compare the particulate removal efficiency of the developed diesel particulate filter using various measurement methods in a high-speed marine diesel engine. A four-stroke mechanical marine diesel engine is used for the test, which has a maximum output of 403 kW and is coupled to an AC dynamometer to control engine speed and load. The test was conducted based on four steady-state engine operating conditions of E3 engine test cycle for the measurement of PM and soot removal efficiency using partial dilution method considered as gravimetric method and filter smoke number method as light absorption method, respectively. As a result of the removal efficiency measurement according to the application of diesel particulate filter, particulate matter was reduced from 76% to 91% and the soot was reduced by more than 90% while meeting the permissible engine back pressure. From these results, the applicability of diesel particulate filter adopted in high-speed marine diesel engines could be confirmed. In addition, based on the result that the particulate removal efficiency varies with different measurement methods, the necessity of unification of these methods could be identified.