• Title/Summary/Keyword: Sorption Property

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Vapor Sorption Property of Charcoal-based Loess Composites (숯과 황토 복합소재의 흡착성능)

  • Lee, Won-Hee
    • Journal of the Korea Furniture Society
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    • v.17 no.3
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    • pp.87-94
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    • 2006
  • The purpose of this study was to evaluate the relationships between the mixing ratio and water vapor sorption property of charcoal-based loess composites for furniture & building materials with environmental friendly. Charcoal-based loess composite can be easily made by blending method with water. But the composites had much brittle fracture pattern with the increase of charcoal content. That is due to the lack of loess that takes linkage role of composites. In water vapor sorption properties, adsorption ability of charcoal was about six times higher than that of loess. Therefore, vapor sorption ability was maximum at the mixture ratio of charcoal 80% and loess 20%. It is considered that wood charcoal based inorganic composite materials can be used for various purposes as a building interior & exterior and furniture members.

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A Study on the Sorption and Physical Properties of the BTCA Finished Cotton Fabrics (BTCA로 방추가공한 면직물의 수착 성질 및 물리적 성질의 연구)

  • 최연주;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.22 no.4
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    • pp.535-542
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    • 1998
  • Cotton fabrics were treated with BTCA, which is used to improve the wrinkle recovery property of cotton fabrics. BTCA, with varying its concentrations, was treated on cotton fabrics by pad dry-cure technique. BTCA contents in treated cotton fabrics were determined by the weight gain and the FT-lR spectrometer. The effects on the sorption and physical properties of BTCA treated fabrics were investigated. IR spectra showed that ester-crosslinks were produced in BTCA treated cotton fabrics. And as increasing the concentration of BTCA, ester-crosslinks are increased in amorphous regions of fabrics. Moisture regain and water imbibition of treated fabrics were reduced. But, they were increased over a certain concentration. Dye sorptions also were reduced, but they were similar over 6% BTCA. When BTCA was treated on cotton fabrics, DP rating and wrinkle recovery angle were improved. On the other hand, strength retentions of treated fabrics were lower than untreated fabrics. Stiffness was increased.

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A Study on the Distribution and Property of Carbonaceous Materials in the Subsurface Sediments near the Imjin River (임진강변 퇴적층 내 탄소물질들의 분포 및 특성 연구)

  • Jeong, Sang-Jo
    • Journal of Soil and Groundwater Environment
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    • v.15 no.3
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    • pp.34-43
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    • 2010
  • The fate of hydrophobic organic contaminants (HOCs) in ground water is highly affected by the distribution and property of the carbonaceous materials (CMs) in subsurface sediments. CMs in soils consist of organic matters (e.g., cellulose, fulvic acid, humic acid, humin, etc.) and black carbon such as char, soot, etc. The distribution and property of CMs are governed by source materials and geological evolution (e.g., diagenesis, catagenesis, etc.) of them. In this study, the distribution and property of CMs in subsurface sediments near the Imjin river in the Republic of Korea and HOC sorption property to the subsurface sediments were investigated. The organic carbon contents of sand and clay/silt layers were about 0.35% and 1.37%, respectively. The carbon contents of condensed form of CMs were about 0.13% and 0.45%, respectively. The existence of black carbon was observed using scanning electron microscopes with energy dispersive spectroscopy. The specific surface areas (SSA) of CMs in heavy fraction(HFrCM) measured with N2 were $35-46m^2/g$. However, SSAs of those HFrCM mineral fraction was only $1.6-4.3m^2/g$. The results of thermogravimetric analysis show that the mass loss of HFrCM was significant at $50-200^{\circ}C$ and $350-600^{\circ}C$ due to the degradation of soft form and condensed form of CMs, respectively. The trichloroethylene (TCE) sorption capacities of sand and clay/silt layers were similar to each other, and these values were also similar to oxidzed layer of glacially deposited subsurface sediments of the Chanute Air Force Base (AFB) in Rantoul, Illinois. However, these were 7-8 times lower than TCE sorption capacity of reduced layer of the Chanute AFB sediments. For accurate prediction of the fate of hydrophobic organic contaminants in subsurface sediments, continuous studies on the development of characterization methods for CMs are required.

Study on Physical Properties of Domestic Species III: Sorption, Thermal, Electrical and Acoustic properties of Liriodendron tulipifera, Betula costata, Paulownia coreana (국산재의 응용물성연구III: 백합나무, 거제수나무, 오동나무의 수분흡착성 및 열적·전기적·음향적 성질)

  • Lee, Won-Hee;Park, Byung-Soo;Chong, Sung-Ho;Kang, Ho-Yang;Hwang, Kwon-Hwan;Byeon, Hee-Seop
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.6
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    • pp.1-12
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    • 2008
  • A series of the studies on the applied physical properties of domestic species have been conducted last three years. Liriodendron tulipifera, Betula costata, Paulownia coreana were examined on sorption property, thermal property, electric property, acoustic property. Because the same apparatus and experimental procedures were used for all species, their results can be easily comparable. The experiments for sorption property were conducted with 80 mesh wood powder and resulted in their EMC's and sorption isotherms. The thermal conductivity and diffusivity, and electric resistance and volumetric electric resistivity were measured with a thermal-wire device and a high electric resistance meter. The differences of the thermal and electric properties between quarter-and flat-sawn specimens were observed, which was partially attributed to their anatomical differences. An acoustic measurement system was used to evaluate dynamic MOE and internal friction. This paper provides the useful fundamental data for designing a wood structure, correcting a portable resistance-type moisture meter, and acoustic properties of wood.

Equilibrium Moisture Contents of Major Korean Coniferous Species (주요 국산 침엽수종의 평형함수율)

  • Lee, Won-Hee;Park, Byung-Soo;Byeon, Hee-Seop;Kang, Ho-Yang;Chong, Sung-Ho
    • Journal of the Korea Furniture Society
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    • v.19 no.1
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    • pp.75-82
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    • 2008
  • A series of the studies on the applied physical properties of main domestic species have been conducted last three years. Equilibrium moisture content(EMC) of Pinus koraiensis, Larix kaemferi, Pinus koraiensis were investigated. The experiments for sorption property were conducted with 20- and 80-mesh wood powder and resulted in their EMC's at various sorption conditions. Amount of moisture sorption and sorption speed of Larix kaemferi were shown the most large values and very fast among three Korean main coniferous wood.

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Changes of Getter properties by Crystallization of Amorphous Zr-V-Ti alloy Powders (비정질 Zr-V-Ti 합금분말의 결정화에 따른 게터 특성 변화)

  • Park, Je-Shin;Kim, Won-Baek;Baek, Jin-Sun
    • Journal of Powder Materials
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    • v.14 no.1 s.60
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    • pp.50-55
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    • 2007
  • The hydrogen sorption speeds of $Zr_{57}V_{36}Ti_7$ amorphous alloy and its crystallized alloys were evaluated at room temperature. $Zr_{57}V_{36}Ti_7$ amorphous alloy was prepared by ball milling. The hydrogen sorption rate of the partially crystallized alloy was higher than that of amorphous. The enhanced sorption rate of partially crystallized alloy was explained in terms of grain refinement that has been known to promote the diffusion into metallic bulk of the gases. The grain refinement could be obtained by crystallization of amorphous phase resulting in the observed increase in sorption property.

A Development of Landfill Liner by Utilizing Waste Lime (폐석회를 이용한 매립지 차수재 개발)

  • 김준섭;이승학;박준범
    • Proceedings of the Korean Geotechical Society Conference
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    • 1999.03a
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    • pp.521-528
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    • 1999
  • As the size of our industry and population inclose, the byproducts such as municipal solid wastes, industrial wastes are in the increasing phase. The treatment of such things is rising as a social problem. Today, the final disposal of these wastes depends mostly on the landfill, and the sanitary landfill is required and designed for preventing soil and groundwater contamination. Clays have been used for a liner material of a sanitary landfill, however, the high quality clay is hard to come by and quite expensive as a lining material in our country. Using the waste lime produced abundantly every year from chemical processes was studied here, made from the proper mixing of the bentonite and the waste lime meets the regulations from the USEPA. The soil property index tests (sieve analysis, specific gravity test Atterberg limit test) were performed, and at last to confirm the sorption characteristics of the bentonite and the waste lime the sorption isotherm equilibrium test and the sorption isotherm were performed with Toluene and Ethylbenzene which are the main components of the leachate from the landfill.

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The Effects of Amorphization on Hydrogen Absorption Properties of Zr57V36Fe7 Getter alloy (게터용 Zr57V36Fe7 합금의 수소 흡수특성에 미치는 비정질화의 영향)

  • Park Je-Shin;Suh Chang-Youl;Kim Won-Baek
    • Korean Journal of Materials Research
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    • v.15 no.12
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    • pp.802-808
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    • 2005
  • The hydrogen sorption speeds of $Zr_{57}V_{36}Fe_7$ amorphous alloy and its crystallized alloys were evaluated at room temperature $Zr_{57}V_{36}Fe_7$ amorphous alloy was prepared by ball milling. The amorphous alloy was crystallized through two stages. Initially, $\alpha-Zr$ solid solution was appeared from the amorphous phase. Two cubic Laves compounds were precipitated afterwards from the remained amorphous and from excessively saturated solid solution at higher temperature. The hydrogen sorption speed of the partially crystallized alloy was higher than that of amorphous. The enhanced sorption speed of partially crystallized alloy was explained in terms of surface oxygen stability which has been known to retard the activation of amorphous alloys. The retardation could be reduce by crystallization process resulting in the observed increase in sorption property.

Changes in Properties of Tropical Kapok Fibers by the Pretreatments (열대산 케이폭 섬유의 전처리에 따른 특성 변화)

  • Shin, Soo-Jeong;Jung, Woong-Ki;Sung, Yong Joo;Lee, Joon-Woo;Kim, Se-Bin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.1
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    • pp.52-58
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    • 2013
  • The effets of the pretreatments of tropical kapok fibers were evaluated in this study in terms of water sorption capacity and oil sorption capacity. The alkali treatments with NaOH resulted in the reduction of lignin, oil and hemicellulose, which were detected with FT-IR spectrum. The reduction of the lyphophilic components such as fat on kapok fiber by the ozone treatments were also measured with FT-IR spectrum. The oil sorption capacity of kapok fiber was decreased by the alkali treatments and the ozone treatments, while the water sorption capacity was increased. The liquid sorption capacity were greatly affected by the mechanical cutting of kapok fiber which exposed the big lumen of kapok fiber. The hydrophilic property of kapok fiber could be controlled by the pretreatments, which would increase the applicability of kapok fiber for preparation of various functional paper products.

Influence of Organic Matter and Temperature on the Sorption of Volatile Organic Compounds on Soil (토양 흡착에 대한 유기탄소와 온도의 영향)

  • 김희경
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1998.11a
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    • pp.57-59
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    • 1998
  • The headspace method has been acknowledged as a cost-effective and convenient method to analyze volatile organic compounds(VOCs) in soil. The headspace analysis is based on equilibrium partitioning of VOCs among water, air and soil in a closed system. However, the headspace method cannot be applied to soils where most of the VOCs remain sorbed even at high temperature. In this study, it was investigated how the sorption characteristics of VOCs varied with soil with different organic carbon contents and temperature. This study showed that all the VOCs were volatilized, not sorved, only in the soil with 5% organic carbon at 45$^{\circ}C$ or higher. Some fraction of VOCs remained in soil with 8% organic carbon at $65^{\circ}C$ of higher. Most of the VOCs remained sorbed in soil with 12% organic content even at 95$^{\circ}C$. This result suggested that the headspace method can be applied only to soils with little organic carbon content (less than 5%). In this case, 45$^{\circ}C$ seems to be high enough to volatilize all the VOCs from soil. Large particles still showed a significant sorption capacity for VOCs from soil. Large Particles still showed a significant sorption capacity for VOCs despite of their low level of organic carbon content. It was also shown that the organic carbon sorption coefficients (Koc) of VOCs varied with soils with different organic carbon content. This suggests that not only the organic matter content of soil but also the property of the organic matter in soil influence the sorption of VOCs to soil.

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