• Nuclear Engineering and Technology
• /
• v.53 no.6
• /
• pp.1942-1946
• /
• 2021

Gadolinium oxysulfide (GOS) is regarded as a novel scintillator for the realization of ultra-high spatial resolution in neutron imaging. Monte Carlo simulations of GOS scintillator show that the capability of its spatial resolution is towards the micron level. Through the time-of-flight method, the light output of a GOS scintillator was measured to be 217 photons per captured neutron, ~100 times lower than that of a ZnS/LiF:Ag scintillator. A detector prototype has been developed to evaluate the imaging solution with the GOS scintillator by neutron beam tests. The measured spatial resolution is ~36 ㎛ (28 line pairs/mm) at the modulation transfer function (MTF) of 10%, mainly limited by the low experimental collimation ratio of the beamline. The weak light output of the GOS scintillator requires an enormous increase in the neutron flux to reduce the exposure time for practical applications.

• BMB Reports
• /
• v.37 no.5
• /
• pp.533-537
• /
• 2004

Previously published kinetic data on the interactions of seventeen different enzymes with their physiological substrates are re-examined in order to understand the connection between ground state binding energy and transition state stabilization of the enzyme-catalyzed reactions. When the substrate ground state binding energies are normalized by the substrate molar volumes, binding of the substrate to the enzyme active site may be thought of as an energy concentration interaction; that is, binding of the substrate ground state brings in a certain concentration of energy. When kinetic data of the enzyme/substrate interactions are analyzed from this point of view, the following relationships are discovered: 1) smaller substrates possess more binding energy concentrations than do larger substrates with the effect dropping off exponentially, 2) larger enzymes (relative to substrate size) bind both the ground and transition states more tightly than smaller enzymes, and 3) high substrate ground state binding energy concentration is associated with greater reaction transition state stabilization. It is proposed that these observations are inconsistent with the conventional (Haldane) view of enzyme catalysis and are better reconciled with the shifting specificity model for enzyme catalysis.

• Journal of Magnetics
• /
• v.8 no.1
• /
• pp.1-6
• /
• 2003

The new class of $Gd_5(Si_xGe_{1-x})_4$ compounds undergoes a simultaneous magnetic/structural phase transition giving a high level of strain that can be induced either by change in temperature or by application of a magnetic field. Profound changes of structural, magnetic, and electronic changes occur in the $Gd_5(Si_xGe_{1-x})_4$ system lead to extreme behavior of the material such as the giant magnetocaloric effect, colossal magnetostriction, and giant magnetoresistance. These unique material characters can be utilized for various applications including magnetic solid refrigerants, sensors, and actuators.

• Journal of applied mathematics & informatics
• /
• v.39 no.5_6
• /
• pp.805-811
• /
• 2021

Currently, batteries use commonly as energy sources for mobile electric devices. Due to the high density of energy, the energy storage state of a battery is very important information. To know the battery's energy storage state, it is necessary to find out the open state voltage of the battery. The open state voltage calculates with a mathematical model, but the computation of the real time state is complicated and requires many calculations. Therefore, the state observer designs to estimate in real time the battery open-circuit voltage as disturbance including model error. Using the estimated open voltage and applying it to the state estimation algorithm, we can estimate the charge. In this study, we first estimate the open-circuit voltage and design an estimation algorithm for estimating the state of battery charge. This includes errors in the system model and has a robust characteristic to noise. It is possible to increase the precision of the charge state estimation.

• International Journal of Aeronautical and Space Sciences
• /
• v.16 no.3
• /
• pp.347-359
• /
• 2015

A method of describing the rovibrational energy transitions and coupled chemical reactions in the direct simulation Monte Carlo (DSMC) calculations is constructed for $H(^2S)+H_2(X^1{\Sigma}_g)$ and $He(^1S)+H_2(X^1{\Sigma}_g)$. First, the state-specific total cross sections for each rovibrational states are proposed to describe the state-resolved elastic collisions. The state-resolved method is constructed to describe the rotational-vibrational-translational (RVT) energy transitions and coupled chemical reactions by these state-specific total cross sections and the rovibrational state-to-state transition cross sections of bound-bound and bound-free transitions. The RVT energy transitions and coupled chemical reactions are calculated by the state-resolved method in various heat bath conditions without relying on a macroscopic properties and phenomenological models of the DSMC. In nonequilibrium heat bath calculations, the state-resolved method are validated with those of the master equation calculations and the existing shock-tube experimental data. In bound-free transitions, the parameters of the existing chemical reaction models of the DSMC are proposed through the calibrations in the thermochemical nonequilibrium conditions. When the bound-free transition component of the state-resolved method is replaced by the existing chemical reaction models, the same agreement can be obtained except total collision energy model.

• Bulletin of the Korean Chemical Society
• /
• v.28 no.12
• /
• pp.2343-2353
• /
• 2007

We report the application of time-dependent density functional theory (TDDFT) to the calculation of potential energy profile relevant to the excited state intramolecular proton transfer (ESIPT) processes in title molecules. The TDDFT single point energy calculations along the reaction path have been performed using the CIS optimized structure in the excited state. In addition to the Stokes shifts, the transition energies including absorption, fluorescence, and 0-0 transition are estimated from the TDDFT potential energy profiles along the proton transfer coordinate. The excited state TDDFT potential energy profile of SA and 3ASA resulted in very flat function of the OH distance in the range ROH = 1.0-1.6 A, in contrast to the relatively deep single minimum function in the ground state. Furthermore, we obtained very shallow double minima in the excited state potential energy profile of SA and 3ASA in contrast to the single minimum observed in the previous work. The change of potential energy profile along the reaction path induced by the substitution of electron donating groups (-NH2 and -OCH3) at different sites has been investigated. Substitution at para position with respect to the phenolic OH group showed strong suppression of excited state proton dislocation compared with unsubstitued SA, while substitution at ortho position hardly affected the shape of the ESIPT curve. The TDDFT results are discussed in comparison with those of CASPT2 method.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
• /
• 1998.10a
• /
• pp.45-50
• /
• 1998

• KIEAE Journal
• /
• v.16 no.6
• /
• pp.5-12
• /
• 2016

Purpose: Quasi-steady state simulations have played a pivoting role to expand the user group of simulation to design engineers and architects in Korea. Initially they are introduced in the market as a building energy performance rating tool. In domestic practice, however, quasi-steady state simulations seem to be regarded as a de facto simulation only available for energy retrofit. Selection of ECMs and economic feasibility analysis are being decided through these tools, which implies that running these tools has become a norm step of the Investment-grade Audit. Method: This study aims at identifying issues and problems with the current practice via test cases, analyzing the reasons and opportunities, and then eventually suggesting proper uses of quasi-steady state and dynamic simulations. Result: The functionality of quasi-steady state simulations is more optimized to the rating. If they are to used for energy retrofits, their off-the-shelf functions also need to be expanded for customization and detailed reports. Yet their roles may be limited only to the go/no go decision; because their algorithms are still weak at precisely estimating energy and load savings that are required for making investment decisions compared to detailed simulations.

• Proceedings of the Korean Powder Metallurgy Institute Conference
• /
• 2006.09b
• /
• pp.1229-1230
• /
• 2006

Adsorption isotherms of hydrogen by step-by-step method are widely used. However, the relations between the equations of state and the accumulated errors produced by step-by-step method and the mechanical errors of pressure or temperature controller were not analyzed. Considering the influence of various errors on the equations of state, we could find out the factors and compare the performance of the equations of state.

• Journal of Power Electronics
• /
• v.17 no.6
• /
• pp.1625-1636
• /
• 2017

A power electronic transformer (PET) based on the cascaded H-bridge (CHB) and the isolated bidirectional DC/DC converter (IBDC) is capable of accommodating a large scale battery energy storage system (BESS) in the medium-voltage grid, and is referred to as a power electronic transformer based battery energy storage system (PET-BESS). This paper investigates the PET-BESS and proposes a coordinative control strategy for it. In the proposed method, the CHB controls the power flow and the battery state-of-charge (SOC) balancing, while the IBDC maintains the dc-link voltages with feedforward implementation of the power reference and the switch status of the CHB. State-feedback and linear quadratic Riccati (LQR) methods have been adopted in the CHB to control the grid current, active power and reactive power. A hybrid PWM modulating method is utilized to achieve SOC balancing, where battery SOC sorting is involved. The feedforward path of the power reference and the CHB switch status substantially reduces the dc-link voltage fluctuations under dynamic power variations. The effectiveness of the proposed control has been verified both by simulation and experimental results. The performance of the PET-BESS under bidirectional power flow has been improved, and the battery SOC values have been adjusted to converge.