• Title/Summary/Keyword: Subsitution

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Antifungal activities of juglone and naphthazarine derivatives

  • Chae, Mi-Jin;Choi, Ik-Hwa;Han, Ja-Young;Jong, Ok-Jai;Ryu, Chung-Kyu
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.185.3-185.3
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    • 2003
  • Juglone and naphthazarine derivatives were newly systhesized for the evaluation of antifungal activities. These derivatives were prepared by methylation of juglone and 2, 3-dichloro-5, 8-dihydroxy-l, 4-naphthoquinone, and by regioselective nucleophilic subsitution with arylthiols. All compounds were tested in vitro for their growth inhibitory activities against pathogenic fungi by the standard method. The MIC values were determined by comparison to flucytosine as a standard agent. (omitted)

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SPN Block cipher SSB having same structure in encryption and decryption (암호와 복호가 동일한 SPN 블록 암호 SSB)

  • Cho, Gyeong-Yeon
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.15 no.4
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    • pp.860-868
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    • 2011
  • Feistel and SPN are the two main structures in a block cipher. Feistel is a symmetric structure which has the same structure in encryption and decryption, but SPN is not a symmetric structure. In this paper, we propose a SPN block cipher so called SSB which has a symmetric structure in encryption and decryption. The proposed SSB is composed of the even numbers of N rounds. Each round consists of a round key addition layer, a subsitution layer, a byte exchange layer and a diffusion layer. The subsitution layer of the odd round is inverse function of one of the even round. And the diffusion layer is a MDS involution matrix. The differential and linear attack probability of SSB is $2^{-306}$ which is same with AES. The proposed symmetric SPN block cipher SSB is believed to construct a safe and efficient cipher in Smart Card and RFID environments which is in limited hardware and software resources.

Antifungal activities of 2-arylthio-,2-arylthio-5-methoxy-,2,3-bisarylthio-juglones and 2,3-bisarylthio-5,8-dimethoxy-1 A-naphthoquinones

  • Shim, Ju-Yeon;You, Hea-Jung;Choi, Ko-Un;Choi, Ik-Hwa;Chae, Mi-Jin;Ryu, Chung-Kyu
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.350.3-351
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    • 2002
  • 2-Arylthio-, 2-arylthio-5-methoxy-, 2, 3-bisarylthio-juglones and 2, 3-bisarylthio-5, 8-dimethoxy-1, 4-naphthoquinones were newly systhesized for the evaluation of antifungal activities. These derivatives were prepared by methylation of juglone and 2, 3-dichloro-5, 8-dihydroxy-1, 4-naphthoquinone. and by resioselective nucleophilic subsitution with arylthiols. All compounds were tested in vitro for their growth inhibitory activities against pathogenic fungi by the standard method. The MIC values were determined by comparison to flucytosine as a fungicidal standard agent. In general. In general. most juglone derivatives shows in vitro antifungal activities. Among them. 2-arylthio-5-methoxy-juglones showed most potent antifungal activities against all pathogenic fungi.

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Effect of Ca Contents and Sr Substitutions on Microwave Characteristics of Mg-Ca-Sr-Ti-O System Ceramics (Ca 함량 및 Sr 치환량의 변화에 따른 Mg-Ca-Sr-Ti-O계 세라믹스의 마이크로파 특성)

  • Ryu, Heon-Wi;You, Whan-Sik;Jung, Ha-Chang;Kim, Bae-Yeon
    • Journal of the Korean Ceramic Society
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    • v.43 no.5 s.288
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    • pp.284-292
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    • 2006
  • $MgTiO_3{\cdot}CaTiO_3{\cdot}SrTiO_3$ system ceramics (MCST) were synthesized to study the effect of Ca addition amount and Sr substitution on temperature coefficient of resonance sequency. Temperature coefficient of resonance frequency was slightly increased by small amount ($i.e.{\sim}5%$) of Sr substitution. In case of 50% to 75% addition amount of $MgTiO_3$, decrease of quality factor was not observed with increasing dielectric constant.

Assessment of Clothing Ventilation through Openings (개구부를 통한 의복의 환기 양상 평가)

  • 추미선
    • The Research Journal of the Costume Culture
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    • v.8 no.5
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    • pp.660-667
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    • 2000
  • Clothing ventilation was investigated using a manikin wearing an impermeable overall under an isothermal condition, in which the ventilation occurred only through the openings. The ventilation volume was estimated by both microenvironment volume and ventilation rate, where, the microenvironment volume was measured by an air subsitution method and the ventilation rate by a trace gas method. Microenvironment volume of the experimental garment was about 21.0 liters. Even though it was certainly affected by the distance from the opening, the ventilation rate was more significantly influenced by the opening area and the shape of air layer in the clothing. The volume of air exchange in the clothing microenvironment was affected greatly by the microenvironment volume and the opening area, and it was different for each part of the body with bigger air exchange volume in the microenvironment of the leg as compared to that of the arm.

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Effect of Na Substitution for the Ca Site in the Bi$_2$Sr$_2$Ca$_{1-x}$Na$_x$Cu$_2$O$_{8+y}$ Superconductors (Bi$_2$Sr$_2$Ca$_{1-x}$Na$_x$Cu$_2$O$_{8+y}$ 산화물 고온초전도체의 Ca 위치에 Na 치환 효과)

  • 이민수;송승용;이종용;송기영;최봉수
    • Journal of the Korean Ceramic Society
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    • v.35 no.10
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    • pp.1007-1013
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    • 1998
  • The samples of Bi2Sr2Ca1-xNaxCu2O8+y with various carrier concentration were synthesized by substituting Na for Ca ion. The superconducting properties hall coefficients and X-ray powder diffraction were measur-ed the sampled. Single phase samples were obtained for 0$\leq$x<0.3 of Bi2Sr2Ca1-xNaxCu2O8+y In the single phase the critical temperature. {{{{ { T}_{c } }} and carrier concentration increase with the increase of Na concentration pass through a maximum and then decreases. In the range of x$\geq$0.7 to the Na doped samples however we observed the metal-semiconductor transition. The c-axis seemed to decrease and a and b-axes increase with increasing Na concentration in the single phase. Decreasing of c-axis while increasing x is due to the smaller size of {{{{ {Na}^{+1 } }} ions to the {{{{ { Ca}^{+2 } }} ions. In the range of x>0.3 however the trend becomes ambiguous due to the inclusion of the 10K phase and impurity phase.

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The Effect of Limestone Powder Admixture Chemical Properties on Workability and Compressive Strength of Composite Cement (석회석 미분말 혼합재의 화학특성이 혼합시멘트 유동성과 강도에 미치는 영향)

  • Suh, Dong Kyun;You, Byeong Know;Choi, Jae Won;Kim, Kyeong Suk;Woo, Ji Wan
    • Cement Symposium
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    • s.49
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    • pp.29-30
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    • 2022
  • Since the climate problem getting severe, carbon neutrality is rising global issue. The limestone powder addition that can substitute clinker in cement is look forward to get positive effect as filler. This study focus on the effect of limestone powder chemical characteristic on mortar workability and compressive strength. Consequently, regardless of type of limestone and subsitution amount, the compressive strength was lower then OPC. But the workability of limestone composite cement showed higher then OPC. Considering latter strength development, using unit water decreasing effect of limestone composite cement is planned further.

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The risk of MTHFR variants, folate and vitamin B$_{12}$ deficiencies and hyperhomocysteinaemia during pregnancy associated with short gestational age and reduced birth weight (임산부에서의 Methylenetetrahydrofolate reductase (MTHFR) 유전자 변이, 엽산 및 비타민 B$_{12}$ 결핍과 고호모시스틴 혈증이 재태기간과 출산아의 체중에 미치는 영향)

  • 박혜숙;김영주;하은희;이화영;장남수;홍윤철;김우경
    • Environmental Mutagens and Carcinogens
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    • v.23 no.1
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    • pp.1-6
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    • 2003
  • The purpose of this study was to evaluate whether the MTHFR variants, folate and vitamin $B_{12}$ deficiencies increase the risk of hyperhomocysteinaemia and adverse pregnancy outcome such as short gestational age or reduced birth weight. Healthy pregnant women (n=136; 24-28 gestational weeks; 20-40 years old), who visited Ewha Womans University Hospital for prenatal care, participated in this study. At the time of delivery, trained nurses recorded the pregnancy outcome from medical chart. We determined maternal MTHFR polymorphisms (C to T subsitution at nucleotide 677) and measured serum homocyteine, vitamin $B_{12}$, and folate concentrations. We compared serum homocysteine level by MTHFR genotype, serum folate and serum vitamin B12 levels using ANOVA. To evaluate the association between serum homocysteine level and pregnancy outcome, we compared the gestational age and birth weight by serum homocysteine levels using multiple regression analysis, adjusting for other potential predictors. Mean level of serum homocysteine was highest among pregnant women of the MTHFR variants with low levels of serum folate and vitamin $B_{12}$. Regarding association with birth outcome, we found the relationship between homocysteine levels and increased gestational age (p=0.03) and reduced birth outcome (p>0.05). Our data demonstrates that serum level of folate and vitamin $B_{12}$ among pregnant women affects significantly serum homocysteine levels, and the genetic polymorphism of MTHFR modulates the relationship between them. However, we did not have conclusive evidence of association between high homocysteine level and adverse pregnancy outcome such as preterm or low birth weight.

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Study of the Utility Value and Decide of the Mixture Ratio of Fly Ash for Livestock Waste Composting (가축분뇨처리 퇴비로서 석탄회의 이용가치 개발과 적정 혼합비율 결정에 관한 연구)

  • 고영두;김재황;김두환;유성오;고병두;이수칠;강경록
    • Journal of Animal Environmental Science
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    • v.5 no.1
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    • pp.53-62
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    • 1999
  • This study was carried out to investigate how to reuse the livestock waste and develop fly ash as a subsitution of sawdust which is used commonly to make compost. Fly ash and sawdust were mixed the ratio of 8 to 2, 7 to 3, 6, to 4, 5 to 5, 4 to 6. 3 to 7 and 2 to 8 after fermentation for 60 days the change of temperature, moisture, pH, organic matter, nitrogen content and C/N ratio were analyzed. The results are as follows; Temperature was reached to maximum (63.5$^{\circ}C$) more quickly in scraper type than in slurry type with adding large sawdust. When fly ash and sawdust were mixed same amount at scraper type and slurry type, moisture was 46.6~53.7% and maintained a good condition for fermentation. pH was showed the range of 7~10 as a mixture of fly ash. Organic matter contents were increased with increasing the added sawdust but did not show any tendency. Nitrogen content was also increased with increasing the amount of added sawdust but did not show any tendency. C/N ratio was increased to 20~60 with increasing the added sawdust, but when sawdust and fly ash were mixed 50:50, there was no significant during fermentation periods. In conclusion, supplementation of fly ash at the level of 50% of sawdust maintained a good condition for fermentation as a livestock waste composting.

The development and the magnetic properties of sheet hexaferrite magnets (Hexaferrite 쉬트자석의 개발과 자기적 성질에 관한 연구)

  • 김철성;박승일;오영제
    • Journal of the Korean Magnetics Society
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    • v.5 no.4
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    • pp.281-286
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    • 1995
  • In order to study the effect of additives $SiO_{2}$ on the magnetic properties of hexaferrite sheet magnet, we used X-ray diffractometer, Mossbauer spectrometer, and VSM magnetometer. We have prepared $Ba_{0.25}Sr_{0.75}Fe_{12}O_{19}$ green sheets by the Dr. Blade method. Most of samples have a magnetoplurnbite crystal structure of typical M-type hexaferrite. The lattice parameters are found not to be affected by the addition of $SiO_{2}$. ${\alpha}-Fe_{2}O_{3}$ phase develops above $SiO_{2}$ 2.0 wt.%. Isomer shifts indicate that the valence of Fe ions is trivalent. Curie temperatures decrease slightly with increasing $SiO_{2}$ concentrations. It means that the $Si^{4+}$ subsitution for 12k-site $Fe^{3+}$ has an effect on the superexchange interactions Fe-O-Fe, which change the distance and the angle between cations and anions. It was suggested that ${\alpha}-Fe_{2}O_{3}$ phase results from the excessive Fe produced by subsituting $Si^{4+}$ for $Fe^{3+}$. Based upon the results of $Ba_{0.25}Sr_{0.75}Fe_{12}O_{19}$ added with $SiO_{2}$, we concluded that $H_{c}$, $M_{s}$ and $M_{r}$ depend more strongly on the microstructure chracteristics than on the cation substitution.

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