• Tribology and Lubricants
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• v.39 no.6
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• pp.273-277
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• 2023

This paper presents a molecular dynamics simulation-based numerical investigation of the influence of surface energy on water lubrication. Models composed of a crystalline substrate, half cylindrical tip, and cluster of water molecules are prepared for a tribological-characteristic evaluation. To determine the effect of surface energy on lubrication, the surface energy between the substrate and water molecules as well as that between the tip and water molecules are controlled by changing the interatomic potential parameters. Simulations are conducted to investigate the indentation and sliding processes. Three different normal forces are applied to the system by controlling the indentation depth to examine the influence of normal force on the lubrication of the system. The simulation results reveal that the solid surface's surface energy and normal force significantly affect the behavior of the water molecules and lubrication characteristics. The lubrication characteristics of the water molecules deteriorate with the increasing magnitude of the normal force. At a low surface energy, the water molecules are readily squeezed out of the interface under a load, thus increasing the frictional force. Contrarily, a moderate surface energy prevents expulsion of the water molecules due to squeezing, resulting in a low frictional force. At a high surface energy, although squeezing of the water molecules is restricted, similar to the case of moderate surface energy, dragging occurs at the soil surface-water molecule interface, and the frictional force increases.

• Proceedings of the Korea Water Resources Association Conference
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• 2007.05a
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• pp.157-161
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• 2007

Nutrients were investigated for surface water, bottom sediment and ground water in a rural watershed from January 2006 to March 2007. The concentrations of TN and $NO_3-N$ in ground water were higher than those in surface water due to fertilization on cabbage upland neighboring a river during March to August, but lower than those in surface water during September to February. However, the concentrations TP and $PO_4-P$ in ground water were lower than those in surface water. The concentrations of TP and $PO_4-P$ in surface water was lower than those in bottom sediment. The TP concentration in the bottom greatly decreased during rainy season. due to flush sediment of bottom, and then gradually increased.

• Journal of Korea Water Resources Association
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• v.35 no.4 s.129
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• pp.367-374
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• 2002

Water supply plan by optimal conjunctive use of surface and ground water is studied to prepare expected water deficit in near future. The optimization model for conjunctive use of surface and ground water is developed using discrete differential dynamic programming technique to maximize net benefit by water supply. As a result of applying the model to Namdaechun river located in Yangyang, it is found that water supply reliability using optimal conjunctive use of surface and ground water is much higher than reliability using surface water alone.

• Korean Journal of Agricultural Science
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• v.47 no.4
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• pp.1057-1069
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• 2020

For most upland crops in Korea, underground water is used to ensure an adequate water supply. Thus, surface water storage tanks are needed to supply surface water from reservoirs or streams. This study discusses the design, manufacture and monitoring of a water storage tank capable of reliably supplying water to crops and preventing the inflow of floating debris. The study was conducted in an apple orchard in Yesan-gun, Chungcheongnam-do in Korea. Based on the water requirements of the crops and size of the orchard, a required flow volume of about 0.6 ㎥·h-1 was determined, along with a surface water storage tank capacity of 1.2 ㎥. Following a comparison with other materials, stainless steel (STS) was used to construct the water tank. The tank was designed to provide 14 hours of irrigation, enabling a small-capacity, cost-efficient tank design to be used. A surface water irrigation test was performed using the surface water storage tank. The average surface water irrigation flow rate was 0.00045 ㎥·m-2·h-1. The water quality test showed that the pH, suspended solids (SS), total nitrogen (TN), and total phosphorus (TP) values satisfied the reference values for agricultural water. The test results showed that the surface water storage tank evaluated in this study allows for crop irrigation when there is a lack of groundwater during droughts.

• Bulletin of the Korean Chemical Society
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• v.31 no.5
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• pp.1192-1198
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• 2010

Pharmaceuticals and personal care products (PPCPs) are emerging contaminants in the aquatic environment. Many pharmaceuticals are not completely removed during wastewater treatment, leading to their presence in wastewater treatment effluents, rivers, lakes, and ground water. Here, we developed analytical methods for monitoring ten pharmaceuticals from surface water by LC/ESI-MS/MS. For sample clean-up and extraction, MCX (mixed cation exchange) and HLB (hydrophilic-lipophilic balance) solid-phase extraction (SPE) cartridges were used. The limits of detection (LOD) in distilled water and the blank surface water were in the range of 0.006 - 0.65 and 1.66 - 45.05 pg/mL, respectively. The limits of quantitation (LOQ) for the distilled water and the blank surface water were in the range of 0.02 - 2.17 and 5.52 - 150.15 pg/mL, respectively. The absolute recoveries for fortified water samples were between 62.1% and 125.4%. Intra-day precision and accuracy for the blank surface water were 2.9% - 24.1% (R.S.D.) and -16.3% - 16.3% (bias), respectively. In surface wastewater near rivers, chlortetracycline and acetylsalicylic acid were detected frequently in the range of 0.017 - 5.404 and 0.029 - 0.269 ng/mL, respectively. Surface water near rivers had higher levels than surface water of domestic treatment plants.

• Journal of the Korean Society of Marine Environment & Safety
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• v.5 no.2
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• pp.57-65
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• 1999

The in situ observations and the seawater analyses were conducted at all seasons from July 1996 to April 1999 for the purpose of describing the characteristics of seasonal variations of water quality in Mokpo harbour, Korea. Vertical stratification started to be formed in water column in spring, developed in summer and disappeared in fall. In summer, vertical density distribution of water column was found to be in stable structure with lower temperature and higher salinity of bottom water, and the vertical mixing of water between surface and bottom layers was restricted. In winter, however, surface water was found to be similar to bottom water in temperature and salinity, and water column was in unstable structure and in well-mixed condition between surface and bottom waters. The saturation percentage of dissolved oxygen(DO) in bottom water of inner part of Mokpo harbour at all seasons was shown to be decreased to the third grade or under the third grade of Korean standards of seawater quality. In particular, dissolved oxygen was oversaturated in surface water and undersaturated in bottom water in summer, due to stratification and organic pollution. The difference of DO concentration between surface and bottom waters was found to be greater in spring and summer than in fall and winter, due to stratification and photosynthesis of phytoplankton. The concentrations of chemical oxygen demand(COD) over the entire waters of Mokpo harbour were found to fluctuate from below the third grade to the first grade of Korean standards through all seasons and COD concentrations of same seasons were shown to be different year after year. In particular, in view of COD, the annual average seawater quality of Mokpo harbour was evaluated to be in third grade of Korean standards, due to organic pollution. The average COD of surface water was greater than that of bottom water in spring and summer, due to the autochthonous COD caused by production of phytoplankton in surface waters, while the average COD of surface water was similar to that of bottom water in fall and winter, due to the vertical mixing of water between surface and bottom layers.

• Journal of Korean Society on Water Environment
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• v.26 no.1
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• pp.133-139
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• 2010

Global human activities associated with the use of fossil fuels have aggravated climate change, increasing air temperature. Consequently, climate change has the potential to alter surface water temperature with significant impacts on biogeochemical cycling and ecosystems in natural water body. In this study, we examined temporal trends on historical records of surface water temperature, and investigated the air temperature/water temperature relationship and the potential water temperature change from an air temperature scenario developed with regional climate model. Although the temporal trends of water temperature are highly variable site-by-site, surface water temperature was highly dependent on air temperature, and has increased significantly in some sub-watersheds over the last two decades. The results presented here demonstrate that water temperature changes are expected to be slightly higher in river system than reservoir systems and more significant during winter than summer for both river and reservoir system. Projected change of surface water temperature will likely increase $1.06^{\circ}C$ for rivers and $0.95^{\circ}C$ for reservoirs during the period 2008 to 2050. Given the potential climatic changes, every $1^{\circ}C$ increase in water temperature could cause dissolved oxygen levels to fall every 0.206 ppm.

• Proceedings of the Korea Water Resources Association Conference
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• 2009.05a
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• pp.1994-1998
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• 2009

Nutrients were investigated for surface water and ground water of paddy field and upland in a rural watershed from May 2008 to January 2009. The cocentrations of TN and $NO_3-N$ in ground water higher than those in surface water due to fertilization on cabbage upland neighboring a river during May to September, but lower than those in surface water during October to January. However, the concentrations TP and $PO_4-P$ in ground water were lower than those in surface water. TP and $PO_4-P$ concentrations in ground water of paddy field were generally lower than those of upland.

• Carbon letters
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• v.6 no.3
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• pp.166-172
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• 2005

The objective of this study was to investigate the possibility of application for water treatment using the zeocarbon. The zeocarbon was mixture of zeolite and activated carbon. In general, the application of commercial zeocarbon to water treatment is difficult because of weak strength in water and the high pH value of effluents after water treatment. Therefore, we have modified the surface of zeocarbon. For the surface modification, we used the acid treatment to make surface functional group. As a result of modification, was created functional group on zeocarbon surface and was formed mesopore in zeocarbon. The surface modified zeocarbon was applied to removal of nitrogen. In removal experiments of nitrogen, removal efficiency was very high. And, strength of zeocarbon after water treatment and pH of effluents were stabilized. This indicates that the surface modified zeocarbon was easy to recover and reuse. Consequently, our results were shown the possibility of application for water treatment using the surface modified zeocarbon.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.268-268
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• 2013

Water molecules on a Ru(0001) surface are anomalously acidic compared to bulk water. The observation was made by conducting reactive ion scattering, reflection absorption infrared spectroscopy, and temperature-programmed desorption measurements for the adsorption of ammonia onto a water layer formed on Ru(0001). The study shows that the water molecules in the first intact $H_2O$ bilayer spontaneously release a proton to NH3 adsorbates to produce $NH_4{^+}$. However, such proton transfer does not occur for $H_2O$, OH, and H in a mixed adsorption layer or for $H_2O$ in a thick ice film surface.