• Korean Journal of Soil Science and Fertilizer
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• v.49 no.1
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• pp.53-59
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• 2016

This study deals with the distribution of the clay minerals separated from clay fractions of ranch pastures in Korea and their chemical and mineralogical properties. Crystalline phases of the clay minerals were identified by powder X-ray diffraction (XRD) pattern and FT-IR spectra, and their relative chemical compositions were also analyzed by X-ray flourescence spectrometry (XRF). Primary minerals consisted mainly of quartz and mica and chlorite and kaolinite along with a trace of swelling micas were identified as secondary clay minerals. However, the relative content of these clay minerals was different with the locations, which led to significant effects on physical and chemical properties of soils like inorganic elemental composition. In particular, $SiO_2$ content was higher in Gochang ranch pasture than in other ranch pasture. Infrared (IR) spectra did not indicate any significant differences in organic functional groups among the locations. This study clearly showed that ranch pastures had different relative content of clay minerals and chemical properties depending on the location and consequently that those properties are worthy to be taken into account for soil amendment.

• Geomechanics and Engineering
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• v.5 no.6
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• pp.565-574
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• 2013

Extensive study was carried out on Clay expansive soil. This soil was silty clay and can be classified as CH. The degree of expansion was found to range from low to medium depending on the free swell and swell pressure tests. The research investigated the effect of using cement dust on swelling potential, Atterberg Limit, linear shrinkage, and mineralogical composition of expansive soil. The results showed that the swelling potential, plasticity index, linear shrinkage, and clay minerals decrease with increasing cement dust percentage. The cement dust accumulates in huge amounts as a side product in cement factories, and the disposal of this fine dust is very difficult and poses an environmental threat.

• Proceedings of the Korean Geotechical Society Conference
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• 1989.10a
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• pp.1.3-25
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• 1989

This paper describes procedures and the results of mineralogical, fabric and pore sixte analyses perforied on four shales to understand time-dependent deforiation behav iour of swell ins shales better. Mineralogical compositions of theme shales are eBtablished froi the results of X-ray diffraction snalysis and chemical analyses. The importance of the fabric in the understanding of swelling behaviour of shales is demonstrated using Scanning Electron Microscope (SRI). The change in pore sixte distribution during the process of swelling is investigated by measuring pore size distribution before and after free swell test. The results Of the Present study imply that the swelling of Shales studied is not attributed to minerals like pyritei anhydrite or swelling clay minerals. The anisotropic swelling behaviour of shales studied ray be explained by fabrics of theme shales and the difference in them. The swelling of theme shales is found to be accoipanied by increase in the volute of pores.

• Geomechanics and Engineering
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• v.18 no.3
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• pp.267-275
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• 2019

Tabriz is a large Iranian city and the capital of the East Azerbaijan province. The bed rock of this city is mainly consisted of marl layers. Marl layers have some outcrops in the northern and eastern parts of city that mainly belong to the Baghmisheh formation. Based on their colors, these marls are classified into three types: yellow, green, and gray marls. The city is developing toward its eastern side wherein various civil projects are under construction including tunnels, underground excavation, and high-rise building. In this regard, the swelling behavior assessment of these marls is of critical importance. Also, in lightweight structures with foundation pressure less than swelling pressure, several problems such as walls cracking and jamming of door and windows may occur. In the present study, physical properties and swelling behavior of Baghmisheh marls are investigated. According to the X-ray diffractometer (XRD) results, the marls are mainly composed of Illite, Kaolinite, Montmorillonite, and Chloride minerals. Type and content of clay minerals and initial void ratio have a decisive role in swelling behavior of these marls. The swelling potential of these marls was investigated using one-dimensional odometer apparatus under stress level up to 10 kPa. The results showed that yellow marls have high swelling potential and expansibility compared to the other marls. In addition, green and gray marls showed intermediate and low swelling potential and swelling pressure, respectively.

• Economic and Environmental Geology
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• v.12 no.1
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• pp.41-49
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• 1979

A literature review is made on the physical and chemical characteristics of clay minerals in acidic solutions from the mineralogical and hydrometallurgical viewpoints. Some of the important characteristics of clays are their ability to cation exchange, swelling, and incongruent dissolution in acidic solutions. Various clay minerals can take up metallic ions from solution via cation exchange mechanism. Generally, cation exchange capacity increases in the following order : kaolinite, halloysite, illite, vermiculite, and montmorillonite. In acidic solutions, the cation uptake such as copper by clay minerals is strongly inhibited by hydrogen and aluminum ions and thus is not economically significant factor for recovery of metals such as uranium and copper. In acidic solutions, the cation uptake is substial. Swelling is minimal at lower pH, possibly due to lattice collapse. Swelling may be controllable with montmorillonite type clays by exchanging interlayer sodium with lithium and/or hydroxylated aluminum species. The effect of add on clay minerals are : 1. Division of aggregates into smaller plates with increase in surface area and porosity. 2. Clay-acid reactions occur in the following order: (i) $H^+$ replacement of interlayer cations, (ii) removal of octahedral cations, such as Al, Fe, and Mg, and (iii) removal of tetrahedral Al ions. Acid attack initiates, around the edges of the clay particles and continued inward, leaving hydrated silica gel residue around the edges. 3. Reaction rates of (ii) and (iii) are pseudo-1st order and proportional to acid concentration. Rate doubles for every temperature increment of $10^{\circ}C$. Implications in in-situ leaching of copper or uranium with acid are : 1. Over the life span of the operation for a year or more, clays attacked by acid will leave silica gel. If such gel covers the surface of valuable mineral surfaces being leached, recovery could be substantially delayed. 2. For a copper deposit containing 0.5% each of clay minerals and recoverable copper, the added cost due to clay-acid reaction is about 1.5c/lb of copper (or 0.93 lbs of $H_2SO_4/1b$ of copper). This acid consumption by clay may be a factor for economic evaluation of in-situ leaching of an oxide copper deposit.

• Proceedings of the Korean Geotechical Society Conference
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• 2006.03a
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• pp.1-11
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• 2006

To be design the slope, the area distributed the shale or mica schist which was metamorphosed by shale must carefully consider the stability. The shale has the detrital materials of which the grain size are 1/256mm and fissility. As the reason the slope of shale is always unstable by bedding slip and fissility but also the joint and fault. Mica schist is also another unstable rock for slope by schistosity, cleavage, axial plane of a fold etc. In general shale and mica schist contain the swelling clay minerals such as smectite, vermiculite and montmorillonite. These minerals make the slope unstable. At OO tunnel construction area for the rail way of the Kyungbu high speed train, the slope of mica schist is very unstable by the distribution phenomena of the discontinuous plane such as joints which are 1-5cm spacing and thrust and strike-slip fault. By the drilling core of this area, most RQD have 0-20%.

• Nuclear Engineering and Technology
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• v.55 no.4
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• pp.1495-1506
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• 2023

For the safe disposal of high-level radioactive waste using Engineered Barrier Systems (EBS), bentonite buffer is used by its high swelling capability and low hydraulic conductivity. When the bentonite buffer is contacted to heated pore water containing ions by radioactive decay, chemical alterations of minerals such as illitization reaction occur. Illitization of bentonite indicates the alteration of expandable smectite into non-expandable illite, which threatens the stability and integrity of EBS. This study intends to provide a thorough review on the information underlying in the illitization of bentonite, by covering basic clay mineralogy, smectite expansion, mechanisms and observation of illitization, and illitization in EBS. Since understanding of smectite illitization is crucial for securing the safety and integrity of nuclear waste disposal systems using bentonite buffer, this thorough review study is expected to provide essential and concise information for the preventive EBS design.

• Geotechnical Engineering
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• v.12 no.2
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• pp.33-42
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• 1996

The weathering of mudrock in the Pohang area is mainly caused by slaking and swelling when the mudrock is absorbed with water. In this regard, this paper chows the results of chemical analysis and the identification of rock-forming minerals from XRD. It also compares the slaking and swelling characteristics of mudrocks sampled from 3 different sites. The chief rock -forming minerals are the quartz, and the several types of clay minerals. The slake durability indices are ranged from 71% to 96%, and these values are closely related to the liquid limit of the powdered nock specimen. In a similar manner to the slaking characteristics the greatest values of the swelling pressure and the swelling strain were measured from the mudrock specimen with the highest value of liquid limit. The greatest measured values of the swelling pressure and the swelling strain are 9.4 kg 1 cm2 and 33.5% respectively. The residual sheer strength of mudrock decreases as the number of wet -diy cycles increases, and the residual strength at 5 cycles are measured to c,=0.24kg/cm2 and p,=28$^{\circ}$. The lowest residual strength is measured at the fresh rock -rock contact surface in the moist condition of which values are cr: 0 and n,: 21.5$^{\circ}$.

• Proceedings of the Korean Geotechical Society Conference
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• 2008.03a
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• pp.848-857
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• 2008

In September 2007, the collapses of slopes and landslides are happened at Jeonlanamdo due to heavy rains accompanied with Typoon "Nari". The study area is the tunnel portal slope in new road construction site. This slope consists of pyroclastic rocks and has lots of faults. Particularly, the residual soils of the slope is deteriorated with yellowish mudstone layer as a results of chemical and physical weathering. This has a variety of swelling clay minerals and might be moved easily down at the gentle terrain. The inner factor of $\bigcirc\bigcirc$tunnel portal slope's collapse is the geological weak zone, the convergent topography, the inferiority of drainage and the heavy rain act on the failure as direct trigger.

• The Journal of Engineering Geology
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• v.19 no.3
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• pp.287-294
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• 2009

To be design the slope, the area distributed the mica schist which was metamorphosed by shale or mudstone must carefully consider the stability. Mica schist is another unstable rock for slope by schistosity, cleavage, axial plane of a fold etc. In general mica schist contains the swelling clay minerals such as smectite, vermiculite and montmorillonite. These minerals make the slope unstable. At OO tunnel construction area for the rail way of the Kyungbu high speed train, the slope of mica schist is very unstable by the distribution phenomena of the discontinuous plane such as joints which are 1-5 cm spacing and thrust and strike-slip fault. By the drilling core of this area, most RQD have 0-20%.