• 생약학회지
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• 제7권3호
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• pp.211-214
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• 1976

Basic substances were obtained from five Korean Aconitum, A. koreanum, A. chiisanense, A. ciliae, A. pseudoproliferum and unknown Aconitum species and compared TLC patterns of the substances. Soluble substances in ammonia alkali showed 8 spots on TLC, while insoluble substances in ammonia alkali 7 spots. These patterns are all similar in all species used in the investigation.

• 생약학회지
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• 제12권3호
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• pp.119-124
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• 1981

In our country, in order to cure diseases, a large number of crude drug preparations has been available. Nevertheless, the development of crude drug preparations have been inhibited, because the quality control is not completed so far. Therefore, we have eontinued on studing the quality control method by Zig-zag TLC. profile analysis. The water extract of 'Samyo-Tang' and componental crude drug (Glycyrrhizae Radix, Ephedrae Herba, Armenicae Semen) were developed on Silica gel $60F_{254}\;plate\;(E.\;Merck)$ useing elution solvent. The developed plate were examined useing Dual Wavelength Zig-zag Scanner (Shimadzu). According to the results of the experiment, it could be summarized as follow: 1) Original patterns of TLC profiles of 'Samyo-Tang' componental crude drug and mixing two crude drugs of 'Samyo-Tang' were observed. 2) Original patterns TLC profile of each extract after spraying with 2% ninhydrine were observed. 3) In the extract of addition and subtraction of Ephedrae Herba, peak area of Rf 0.48 and Rf 0.60 were varied quantitatively.

• 생약학회지
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• 제21권4호
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• pp.290-299
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• 1990

Taxonomic relationships between some inulin containing plants such as Platycodon and Codonopsis have been investigated comparing their contents of inulin crystals, resin, as well as TLC patterns of saponins and acetylenes. Although Platycodon and Codonopsis have been known to be close in anatomic characters, the present results showed that there were significant differences between not only in the genus but also in the species.

• 전자공학회논문지
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• 제51권12호
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• pp.72-82
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• 2014

최근 스마트폰, 태블릿 PC, SSD(Solid State Drive)의 보급률 증가로 메모리 반도체 산업시장의 규모는 지속적으로 증가하고 있다. 또한 최근 SSD시장에 TLC NAND-형 플래시 메모리 제품의 출시로 인해 TLC NAND-형 플래시 메모리의 수요가 점차 증가할 것으로 예상된다. SLC NAND 플래시 메모리는 많은 연구가 진행되었지만 TLC NAND 플래시 메모리는 연구가 진행되지 않고 있다. 또한 NAND-형 플래시 메모리는 고가의 외부장비에 의존하여 테스트를 하고 있다. 따라서 본 논문은 기존에 제안된 SLC NAND 플래시 메모리와 MLC NAND 플래시 메모리 테스트 알고리즘을 TLC NAND 플래시 메모리에 맞게 알고리즘과 패턴을 수정하여 적용하고 고가의 외부 테스트 장비 없이 자체 테스트 수행이 가능한 구조를 제안한다.

• 생약학회지
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• 제5권4호
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• pp.205-210
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• 1974

Four kinds of Bupleuri Radix, namely 'Dang shiho', 'Won shiho', 'Shik shiho' and 'Jook shiho', are currently used in the market of Korea. It is thought that 'Dang shiho' is the root of Bupleurum falcatum and B. scorzoneraefolium. It was also reported that 'Won shiho' and 'Shik shiho' are the root of B. falcatum. Since 'Jook shiho' which is widely used in the market and even exported, has not been clarified as to the origin of the plant and the chemical components, the author obtained some results by this study, the summaries of which are as following: 1. The results of microscopical examination of 'Jook shiho' and 'Kae shiho' were entirely identical and the TLC patterns were coincided as well. It was therefore definitely clarified that the origin of 'Jook shiho' is Bupleurum longe-radiatum. 2. The TLC patterns of 'Won shiho', 'Jook shiho' and 'Kae shiho' which are belonging to the same family and the same genus, appeared identical, and reveal the similarity of the chemical constituents and thereby strongly support the fact that 'Jook shiho' can be used for the same purpose as 'Won shiho'.

• 분석과학
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• 제30권2호
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• pp.102-111
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• 2017

Here we reported a methodology for identification of triacylglycerols (TAGs) and diacylglycerols (DAGs) in coix seed by preparative thin layer chromatography (prep-TLC) and non-aqueous reversed-phase liquid chromatography (NARP LC)-atmospheric pressure chemical ionization (APCI) tandem mass spectrometry (MS/MS). Lipid components were extracted from coix seed by reflux extraction using n-hexane for 3 hr. TAGs and DAGs in coix seed extract were effectively purified and isolated from matrix interferences by prep-TLC and then analyzed by LC-APCI-MS and MS/MS for identification. TAGs were effectively identified taking into consideration of their LC retention behavior, APCI-MS spectra patterns, and MS/MS spectra of $[DAG]^+$ ions. In MS/MS spectra of TAGs, diacylglycerol-like fragment $[DAG]^+$ ions were useful to identify TAGs with isobaric fragment ions. Based on an established method, 27 TAGs and 8 DAGs were identified in coix seed extract. Among them, 15 TAGs and 8 DAGs were for the first time observed in coix seed. Interestingly, some of TAGs isolated by prep-TLC were partly converted into DAGs through probably photolysis process during storing in room temperature. Thus, degradation phenomenon of TAGs should be considered in the quality evaluation and nutritional property of coix seed. LC-APCI-MS/MS combined with prep-TLC will be practical method for precise TAG and DAG analysis of other herbal plants.

• 한국식품과학회지
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• 제37권3호
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• pp.360-363
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• 2005

가시오가피에서 Polyacetylene 성분 중 falcarinol을 탐색하기 위해 TLC, HPLC/PDA, GC, GC/MS를 이용하여 falcarinol 표준품과 소분획물 사이의 비교 분석을 통하여 가시오가피에서 falcarinol을 동정하였다. 가시오가피 추출물을 silica gel column상에서 용매의 극성차이에 의해 6개의 분획물을 얻었고, 6개의 분획물과 falcarinol 표준품과의 TLC 상에서 전개시킨 결과 fraction 6 분획물에서 falcarinol과 동일 band의 물질을 분리하였다. Fraction 6의 분획물과 falcarinol 표준품을 HPLC/PDA로 분석한 결과 falcarinol 표준품의 peak와 동일 retention time의 peak를 fraction 6에서 분리하여 200-340nm 상에서 UV spectrum을 관찰한 결과 동일한 UV spectrum pattern을 보이는 것을 확인하였다. 이는 전형적인 polyacetylene 화합물의 UV spectrum pattern이었으며, 기존에 보고된 falcarinol의 UV spectrum과도 동일하였다. GC로 TMS 유도체화 전,후의 retention time을 확인한 결과 표준품과 fraction 6에서 동일한 결과를 보였다. TMS 유도체화 후에는 7.5분에서 8.5분으로 약 1분 정도 retention time이 증가하였고, detection 감도 또한 증가하였다. Falcarinol 표준품과 fiaction 6 분획물을 TMS 유도체화 후에 GC/MS로 mass fragment ion을 분석한 결과 표준품과 동일한 경향을 보였고 이는 기존의 보고와도 일치하였다(16). 본 실험결과들로 미루어 가시오가피에도 polyacetylene 성분인 falcarinol 존재하는 것으로 확인되었다.

• 생약학회지
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• 제19권3호
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• pp.201-207
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• 1988

Samples of red ginseng, which had been manufactured and packaged by the Korean Monopoly Corporation, were stored at ambient temperatures and humidities ($12{\sim}28^{\circ}$ and $55{\sim}68$ percent) for one to nine years to examine their overall quality stability. The proximate compositions, contents of 50% ethanol and water extracts of the samples and the TLC and HPLC patterns of ginsenosides in the samples remained almost unchanged in all cases. The lipids and fatty acids in the samples, which are otherwise susceptible to oxidation, were stable judged on the basis of the changes of the TLC and GLC patterns of the lipids and fatty acids. It was also found that polyunsaturated fatty acids such as linoleic(C18:2) and linolenic and(C18:3) present in the samples had been very stable during the long storage periods. It, therefore, seems that the autoxidations of the lipid and fatty acids of red ginseng were prevented by antioxidative compounds which will be progressively formed in red ginseng through non-enzymatic browning reactions during manufacturing process and long-term storage.

• 한국연초학회지
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• 제2권2호
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• pp.1-7
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• 1980

오리엔트산 및 한국산 향끽미종 잎담배의 휘발성이 적은 성분들을 간단한 장치와 간단한 조작을 통해 분리 농축하였다. 각 휘발성이 적은 농축물들은 가시 영역에서 흡광도를 측정하고 박층 크로마토그라피 (TLC)와 고성능 액체 크로마토그라피 (HPLC)에 의해서 상세한 조성분석을 하였다. 각 품종간의 정량적인 차이가 가시광선 흡수 스펙트라, TLC 패턴, HPLC프로파일 상에서 확인되었다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 추계학술대회
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• pp.1098-1103
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• 2004

In this study, the effect of channel flow in the concave surface on local heat transfer characteristics of array jets was investigated experimentally. A TLC method is employed to determine local heat transfer coefficients on the target plate and also flow visualization has been conducted to investigate the behavior of a row of impinging jets and array of impinging jets. Two different array patterns of impinging array jets devices are tested for Reynolds number(Re=10,000). In a row of impinging jets, secondary vortex is strongly maintained by main vortex at nozzle-to-plate distance of H/d=2. Therefore, the Nusselt number slowly decreased at the mid-way region between adjacent jets. In array jets, the local maximum Nusselt number region move further in the downstream direction due to the increase of channel flow velocity.