• Title/Summary/Keyword: Thermodynamics

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Application and Verification of Thermodynamics by using Cylindrical Asphalt Mixture Specimen (아스팔트 혼합물 실린더 시편을 이용한 열역학적 이론의 적용 및 검증)

  • Yun, Tae Young;Yoo, Pyeong Jun
    • International Journal of Highway Engineering
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    • v.16 no.4
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    • pp.87-95
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    • 2014
  • PURPOSES: Evaluation of thermal conductivity and convection properties of asphalt mixture by using thermodynamics. METHODS: In this research, temperature prediction model based on thermodynamics is derived for asphalt mixture in transient state and it is verified with laboratory test results. RESULTS: The derived temperature prediction model shows good agreement with laboratory test results. CONCLUSIONS: It is concluded that the derived model based on thermodynamics and thermal properties in the literature are good enough to capture temperature variation in laboratory test. The approach based on thermodynamics can be applied to more complex temperature simulations.

A Comment on Presentation Order of Thermodynamic Laws for Undergraduate Mechanical-Engineering Education by Example Problems (예제를 통해 본 학부 기계공학 교육에서 열역학 법칙의 소개 순서에 대한 논평)

  • Park, Kyoung Kuhn
    • Journal of Engineering Education Research
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    • v.21 no.2
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    • pp.3-6
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    • 2018
  • A few thermodynamics texts are commonly found to have unrealistic example problems in which the process violates the second law of thermodynamics. This error would result from presentation order in the text which introduces first the first law for cycles, systems, and control volumes and then the second law later. In the presentation order, the example problems deal only with the first law without telling whether the process violates the second law. To correct this erroneous situation, it could be recommended to present the first law and the second law successively so that both laws could be applied simultaneously to the given example problems.

Reconstruction of Thermodynamics by the Concept of Available Energy (II) - Thermodynamics of Real World - (가용 에너지에 의한 열역학의 재구성 (II) - 실제세계 열역학 -)

  • Jung, Pyung-Suk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.12
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    • pp.1573-1581
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    • 2004
  • Thermodynamic principles are described with a new point of view. In present study, the interaction between two systems is focused instead of the behavior of a system in conventional thermodynamics. The state change of a system cannot occur by itself but it is the result of the interaction between systems. However, the interaction itself is also the result of another kind of interaction, the interaction between two interactions. To reconstruct thermodynamics with such a point of view, the reversible world is imagined, in which conservations and measurements are discussed. There exists a conserved quantity for each mode of reversible interaction. The conserved transferring quantity in the interaction between interactions is the effective work, which is supposed to be measurable and conserved in reversible world. Effective work is the primary concepts of energy. It is the key factor to explain measurements, energy conservation and energy dissipation. The concepts developed in reversible world are applied to the real world in which irreversible phenomena may occur. Irreversibility is the result of effective energy dissipation, in which effective work irreversibly changes into entropy. A quantitative relation between the disappearing effective work and the generated entropy is dissipation equation which is given by experiments. A special temperature scale to give a very simple type of the dissipation equation is the absolute temperature scale, which gives the conventional conservation of energy.

A Case Study on the Application of Flipped Learning Methodology to Thermodynamics in Mechanical Engineering (열역학 교과목에 대한 플립러닝 교수법 적용 사례)

  • Ryu, Kyunghyun
    • Journal of Engineering Education Research
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    • v.25 no.6
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    • pp.69-80
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    • 2022
  • In this study, the application of flipped learning methodology to thermodynamics in mechanical engineering was examined, and how university students view flipped learning and the effects of flipped learning were analyzed. To analyze the effects of flipped learning, pre-class survey, assessment on learning in pre-class, team activities during class, and post-class survey were conducted. The analysis was also conducted on 33 students who took the thermodynamics course in mechanical engineering, and the PARTNER flipped learning model was applied to the class. The results of this study are as follows; In the preliminary survey, the students expected that the flip-learning class with team activities and teaching between team members would be helpful in improving their learning. In addition, students recognized that cooperative learning through a team was helpful for learning. The case reflecting the result of pre-learning evaluation to the subject grades showed higher pre-learning evaluation results than the case not reflecting the result of the pre-learning evaluation to the subject grades, and it was found that the pre-learning evaluation was acting as a factor to promote learning in pre-class. In post-class survey, the satisfaction with the flipped learning class was high, indicating that the effectiveness of the flipped learning class applied to the thermodynamics class was excellent.

Transport Properties of Charged Mosaic Membrane Based on Non-equilibrium Thermodynamics

  • Song, Myung-Kwan;Yang, Wong-Kang
    • Korean Membrane Journal
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    • v.7 no.1
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    • pp.67-70
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    • 2005
  • It is well known as the role of ion exchange membrane with functional group in membrane matrix. Recently, we were reported that the charged mosaic membrane within parallel array of negative and positive charge groups. In this study we are reported the properties for the various transport coefficients of metal and heavy metal ions across charged mosaic membrane based on non-equilibrium thermodynamics is not based on equilibrium state.

The Theoretical Calculations of Kinetic and Thermodynamics Parameters and Anharmonic Correction for the Related Reactions of NO3

  • Yu, Hongjing;Liu, Yancheng;Xia, Wenwen;Wang, Li;Jiang, Meiyi;Hu, Wenye;Yao, Li
    • Journal of the Korean Chemical Society
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    • v.65 no.6
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    • pp.419-432
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    • 2021
  • According to the transition state (TS) theory, Gaussian software and Yao and Lin (YL) method, the thermodynamics and kinetic data respectively were calculated, and anharmonic effect was considered for related reactions of NO3. The methods of calculating and fitting kinetic and thermodynamics parameters were provided by least square method and related equations in this paper. Notably, the fitted E of Arrhenius equation was close to the calculated barrier of related reaction by QCISD(T) method. Therefore, the kinetic fitting result can well express the physical meaning of E in Arrhenius equation. Besides, the conversion process and the reaction mechanism of NO3 were researched. For NO3, it seemed that its instability results from its easy reaction with other substances rather than the decompose reaction of itself.

Availability of Energy and Reconstruction of Thermodynamics(I) Thermodydamics of the Reversible World (에너지의 가용성과 열역학의 재구성 (I) 가역세계 열역학)

  • 정평석;노승탁
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.5
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    • pp.1227-1236
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    • 1993
  • In conventional thermodynamics, energy is regarded as a physical quantity transferring from one system to another, but in present study, the real energy is regarded as a physical quantity coming out from one interaction and absorbing into another interaction between two systems. To reconstruct thermodynamics with such a point of view, available work is distinguished from half work in conventional work concepts, and a special space named reversible world is proposed in which every process is reversible and the only measurable quantity is available work and just the equality between the intensities of two systems can be verified. As results, thermodynamic laws are arranged into two principles in the reversible world-conservations of energy elements and conservation of available energy. It means the exsistences of state properties corresponding to transferring energy elements and the available work. The former are extensive properties and the later is named potential work which is a property of the composite system and a kind of mathematical distance. The conventional available energy (exergy) and internal energy can be explained as the special cases of potential work, and the conventional first law of thermodynamics can be derived from the principle of the conservation of available energy. With these new concepts, the description of thermodynamic processes is more comprehensive. The second law of thermodynamics is no longer needed in the reversible world.

Nonexistence and non-decoupling of the dissipative potential for geo-materials

  • Liu, Yuanxue;Zhang, Yu;Wu, Runze;Zhou, Jiawu;Zheng, Yingren
    • Geomechanics and Engineering
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    • v.9 no.4
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    • pp.531-545
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    • 2015
  • Two fundamental issues exist in the damage theory of geo-material based on the concept of thermodynamics: existence or nonexistence of the dissipation potential, and whether the dissipation potential could be decoupled into a damage potential and a plastic one or not. Thermodynamics theory of elastoplastic damage assumes the existence of dissipation potential, but the presence of dissipation potential is conditional. Based on the dissipation inequality in accord with the second law of thermodynamics, the sufficient and necessary conditions are given for the existence of the dissipation potential separately in total and incremental forms firstly, and proved strictly in theory. With taking advantage of the basic mechanical properties of geo-materials, the nonexistence of the dissipative potential is verified. The sufficient and necessary conditions are also given and proved for the decoupling of the dissipation potential of geo-materials in total and incremental forms. Similarly, the non-decoupling of the dissipation potential has also been proved, which indicates the dissipation potential of geo-materials in total or incremental forms could not be decoupled into a dissipative potential for plasticity and that for damage respectively. The research results for the fundamental issues in the thermodynamics theory of damage will help establish and improve the theoretic basis of elastoplastic damage constitutive model for geo-materials.