• Title/Summary/Keyword: Total Gas

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Formation of particulate-phase and gas-phase polycyclic aromatic hydrocarbons in cigarette smoke

  • Shimazu, Haruki;Yata, Tsuyoshi;Ozaki, Naoto
    • Advances in environmental research
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    • v.6 no.3
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    • pp.189-202
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    • 2017
  • This study examines the concentrations of particulate-phase polycyclic aromatic hydrocarbons (PAHs) and gas-phase PAHs in sidestream cigarette smoke. Sixteen PAHs were determined for four brands of cigarettes. The volume of the experimental room is approximately $66m^3$. The air samples in the room were collected before and after smoking. The median total of particulate-phase and gas-phase PAH concentrations before smoking $3.13ng/m^3$and $48.0ng/m^3$, respectively. The median concentrations of them after smoking were $10.0ng/m^3$ and $79.6ng/m^3$. The median increases in the total of 16 PAH concentrations per cigarette during smoking were 271 ng for the particulate-phase PAHs and 1960 ng for the gas-phase PAHs. According to the relationship between particulate-phase and gas-phase PAHs after smoking, the two- to four-ring gas-phase PAHs and the higher molecular weight particulate-phase PAHs were probably formed from similar precursors. The relationship between the total suspended particulate (TSP) concentration and the increase in the total particulate-phase concentration of the 16 PAHs per cigarette during smoking were significantly positive. The increase in the total gas-phase concentration of the 16 PAHs tended to increase as the TSP concentration increased. This may indicates that decreasing the amount of TSP produced inhibit the production of PAHs during smoking.

Gas/Particle Level and Dry Deposition Flux of Atmospheric PCBs

  • Yeo, Hyun-Gu;Park, Ki-Chul
    • Journal of Environmental Health Sciences
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    • v.29 no.4
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    • pp.10-16
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    • 2003
  • Atmospheric samples were conducted from September 2001 to July 2002 with GPS-l PUF sampler in rural site to concentration distributions of gas/particle PCBs and to calculate dry deposition flux of PCBs. $\Sigma$PCBs concentrations of gas/particle PCBs were 59.29$\pm$48.83, 6.56$\pm$6.59 pg/㎥, respectively. Gas contribution (%) of total PCBs (gas + particle) was 90% which existed gas phase in the atmosphere. The particle contribution (%) of PCB congeners increased relatively more of the less volatile congeners with the highest chlorine number. The correlation coefficients (r) between total PCBs and temperature ($^{\circ}C$) showed negative correlation in - 0.62 (p<0.0l) for particle phase, positive correlation in 0.63 (p<0.01) for gas phase. In other word, particle phase PCBs is enriched in colder weather which could be due to greater in corporation of condensed gas phase at low temperature. The calculated dry deposition of total PCBs (gas + particle) was 0.008, 0.008 $\mu\textrm{g}$ $m^{-2}$ da $y^{-l}$ which showed maximum dry deposition flux in December, minimum data in July Bs in the atmosphere. The calculated dry deposition fluxes of total PCBs were influenced by particle phase PCBs even though PCBs in the atmosphere were present primarily in the gas phase.e.

Effects of Gas Composition on the Performance and Emissions of Compressed Natural Gas Engines

  • Min, Byung-Hyouk;Chung, Jin-Taek;Kim, Ho-Young;Park, Simsoo
    • Journal of Mechanical Science and Technology
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    • v.16 no.2
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    • pp.219-226
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    • 2002
  • Natural gas is considered to be a promising alternative fuel for passenger cars, truck transportation and stationary engines providing positive effects both on the environment and energy security. However, since the composition of natural gas fuel varies with location, climate and other factors, it is anticipated that such changes in fuel properties will affect emission characteristics and performance of CNG (Compressed Natural Gas) engines. The purpose of the present study is to investigate the effects of the difference in gas composition on the engine performance and emission characteristics. The results show that THC (Total Hydrocarbon) decreases with increasing Wl (Wobbe Index) and MCP (Maximum Combustion Potential). On the other hand, it is observed that NOx slightly increases as Wl and MCP increase. The TLHV (Total Lower Heating Value of Intake) is proposed in this study as a potential index for compatibility of gas fuels in a CNG engine. There is a variation in power up to 20% depending on the composition of gas when the A/F ratio and spark timing are flexed for a specific gas fuel.

A study on the calculation of greenhouse gas emission in industry complex of Shiwha-banwol using the method of IPCC (IPCC 방법을 이용한 시화·반월 산업단지의 온실가스 배출량 산정 연구)

  • An, Jae-Ho
    • KIEAE Journal
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    • v.11 no.2
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    • pp.67-74
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    • 2011
  • Recently environmental regulations like the Kyoto Protocol, adopted in 1997, required the reduction of the greenhouse gas of 5.2% up to 1990's emissions and 13th General Assembly in 2007, held in Bali of India, have agreed to duty reduction even in developing countries in 2013. Korean government needs research on climate change and greenhouse gas management, such as carbon emissions calculation system and the introduction of greenhouse gas reduction program. Using Top-Down approach with method of IPCC, greenhouse gas emissions from energy, transportation, agriculture, land use and forest, and waste was calculated. Total amount from Shiheung-City in 2007 was about 3,299.581 tons of greenhouse gas $CO_2$. By sectors, the total greenhouse gas emissions in the energy sector mostly accounted for 78 percent, 12 percent from transportation, 6 percent of waste, the landuse/forest sector, 4% of the greenhouse gas emissions. Approximately 5,401,618 tons of the greenhouse gas $CO_2$ was total amount from Ansan-City in 2007. The share of energy sector greenhouse gas emissions was the highest portion of 79 % and 14 percent of transportation, 4% from the waste sector, 3 % from landuse/forest sector.

Reviews on Natural Resources in the Arctic: Petroleum, Gas, Gas Hydrates and Minerals

  • Yoon, Jong-Ryeol;Kim, Yea-Dong
    • Ocean and Polar Research
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    • v.23 no.1
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    • pp.51-62
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    • 2001
  • The Arctic consists of numerous sedimentary basins containing voluminous natural resources and two of the world's major oil and gas producing areas. The western Siberia Basin in the Arctic region has the largest petroliferous province with an area of 800 ${\times}$ 1,200 km and produces more than 60% of total Russian oil production. The North Slope of Alaska produces about 20% of the U.S. output, i.e., 11% of the total U.S. consumption. Being small compared to those regions, the Canadian Northwest Territories and the Pechora Basin in Russia produce only fair amount of oil and natural gas. There are also many promising areas in the northern continental shelf of Russia. In addition to Russia, Svalbard and Greenland have been investigated for oil and gas. Gas hydrates are widespread in both permafrost regions and arctic continental shelf areas. The reserves of gas hydrates in the Arctic Ocean are about 20${\sim}$32% of total estimated amounts of gas hydrates in the world ocean. Mineral mining is well developed, especially in Russia. The major centers are located around the Kuznetsk Basin and Noril'sk. They are major suppliers of gold, tin, nickel, copper, platinum, cobalt, iron ore, coal as well as apatite. There are also some minings of lead-zinc in Alaska and Arctic Canada.

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Estimation of Exhaust Gas Recirculation using In-Cylinder Residual Gas Fraction in an SI Engine (잔류가스 추정 기법을 이용한 EGR율의 예측)

  • 김득상;김성철;황승환;조용석;엄인용
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.1
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    • pp.55-60
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    • 2004
  • Residual gas acts as a diluent which results in reducing the in-cylinder temperature as well as the flame speed, significantly affecting fuel economy, NOx emissions and combustion stability. Therefore it is important to determine the residual gas fraction as a function of the engine operating parameters accurately. However, the determination of the residual gas fraction is very sophisticated due to the unsteady state of induction and exhaust process. There has been little work toward the development of a generally applicable model for quantitative predictions of residual gas fraction. In this paper, a simple model for calculating the residual gas fraction in SI engines was suggested. The amount of fresh air was evaluated through AFR and fuel consumption. After this, from the intake temperature and pressure, the amount of total cylinder-charging gas was estimated. The residual gas fraction was derived by comparing the total charging and fresh air. This results coincide with measured EGR value very well.

Calculation of the Absorption Coefficient and Weighting Factor Expressing the Total Emissivity of Flame (화염의 총괄폭사 계수를 나타내는 급수계수 및 가중치의 계산)

  • 하만영;허병기
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.10 no.1
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    • pp.121-130
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    • 1986
  • Using the sbsorption coefficients and the weighting factors of the gray gas, the total emissivities of C $O_{2}$- $H_{2}$O and C $O_{2}$- $H_{2}$O- transient species-soot gas mixtures can be expressed by the following equation, [a numerical formula] Where, $a_{i}$ and $K_{i}$ represent the weighting factor and the absorption coeffient of i-gray gas respectively; L is the pathlength of the gas. This equation is widely used for the analyses of the radiation heat transfer in the combustors of internal combustion engines and in the furnace of external combustion engines. In this work, a simple calculation model of the weighting factor and the absorption coeffient of the above equation was developed. The weighting factors and the absorption coefficients of combustion products were calculated by applying the model to various kinds of fossil fuels such as coal and heavy oil. Then, the computed total emissivities for each fuel and pathlength were compared with measured and calculated values which have been already published in the literatures. The followings were the results obtained through the comparisons between the calculated emissivites and the published values; the developed model for the calculations of the weighting factor and the absorption coefficient of C $O_{2}$- $H_{2}$O and C $O_{2}$- $H_{2}$O- transient species-soot gas mixtures could be applied over the wide ranges of the temperature and the pathlength; the errors between the total emissivities calculted and the values published were maximum 10%, and average 1%, respectively.

Stabilization of Fuel F1ow in a Multi-Nozzle Combustion System Burning Natural Gas (천연가스 다노즐 열원설비의 연료 유동 안정화)

  • 박의철;차동진
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.12
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    • pp.1255-1265
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    • 2001
  • A numerical study has been conducted to characterize the transient flow in a utility gas turbine burning natural gas. The solution domain encompasses the supply gas pressure regulator to the combustor of the gas turbine that employs multi-nozzle fuel injectors. Some results produced for verification in the present study agree suite well with the experimental ones. It is found that the total gas flow may decrease noticeably during its combustion mode change, which would be the reason of momentary combustion upset, when a reference case of opening ratios of control valves in the system is applied. Several parameters are then varied in order to make the total gas flow stable over that period of time. Results of this study may be useful to understand the unsteady behavior of combustion system burning natural gas.

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HCD Ion Plating of Ti(C, N) Films for Cutting Tools (절삭공구용 Ti(C, N)피막의 HCD식 이온도금시 공정변수의 영향)

  • 강형호;고경현;안재환
    • Journal of the Korean institute of surface engineering
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    • v.27 no.3
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    • pp.143-148
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    • 1994
  • Effects of process variables of HCD ion plating on the film composition of Ti(C, N) were analyzed. The mole ratio of carbon to nitrogen and that of non-metal to titanium in the film primarily depend on the partial pressure ratio of ($C-2H_2$/ $N_2$) and total reactive gas pressure, respectively. The amount of nonmetallic com-ponents increases in nonlinear fashion as the total gas pressure due to the different reactivity of $C-2H_2$ and $N_2$ gases with Ti. The nonmetallic components was saturated dwith nitrogen when the nitrogen gas was more than 60% of total reactive gas. These two process variables could be related systematically using the concept of effective pressure in which the difference of reactivity of each gas was normalized.

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Consequence Analysis of Energy Facility(City Gas Pipeline) (에너지시설(도시가스배관)의 사고시 영향 평가)

  • Park Kyo-Shik;Lee Jin-Han;Jo Young-Do;Park Jin-Hee
    • Journal of the Korean Institute of Gas
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    • v.7 no.1 s.18
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    • pp.10-18
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    • 2003
  • Consequence model has been suggested to evaluate consequence of city gas accident considering actual situation. Through event tree analysis(ETA), probable accidents were summarized and listed. Then release rate was calculated both sonic and subsonic conditions. Among city gas accidents, fire damage is the dominant one and mainly discussed; fatality, burning injury, and damage to building were estimated using the consequence model suggested. With an appropriate conditions, calculating total cost by accident was suggested.

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