• Title/Summary/Keyword: Vapor phase

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Characteristics of Friction and Wear of Metals Under Vapor Phase Lubrication (Vapor Phase Lubrication을 통한 금속의 마찰 및 마멸 특성)

  • 김대은;양지철;성인하
    • Tribology and Lubricants
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    • v.18 no.2
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    • pp.109-116
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    • 2002
  • phase lubrication can be used as an alterative lubrication method to overcome the demerits of liquid and solid lubrications. In this work, the tribological characteristics of metals are investigated under vapor phase lubrication. It was found that the friction coefficient and wear volume can be controlled efficiently by the amount of vapor phase lubricant delivered to the sliding interface. The friction coefficient could be reduced to about 0.1 under vapor lubrication. Also, depending on the amount of vapor lubrication delivered to the system, the width of the wear track could be varied between 50 to 250 Um. It is shown that vapor phase lubrication mechanism is very effective to control the friction and wear phenomena without the use of excessive oil.

Distribution of the Concentration of Fuel Vapor in DI Gasoline Sprays Under Evaporation Condition (증발 조건에서 직분식 가솔린 분무의 증기 농도의 분포)

  • Hwang, S.C.;Choi, D.S.;Cha, K.J.;Kim, D.J.
    • Journal of ILASS-Korea
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    • v.4 no.4
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    • pp.1-8
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    • 1999
  • The concentration and spatial distribution of vapor phases in DI (Direct Injection) gasoline spray were measured quantitatively by exciplex fluorescence method. Fluorobenzene and DEMA (diethylmethylamine) in a solution of hexane were used as the exciplex-forming dopants. The fluorescence intensity of vapor phase were obtained by ICCD camera with the appropriate filter The relationship between fluorescence intensity and vapor concentration was induced fer the purpose of a quantitative analysis. The 2-D vapor/liquid images of fuel spray were captured under the evaporation condition, and the spatial distribution of vapor concentration was obtained. The spatial distribution of liquid phase had hollow-cone shape. And the vapor phase was widely distributed in the whole spray. The behavior of vapor phase was significantly affected by second flow such as entrainment, vortex, while that of liquid phase was scarcely affected.

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Characteristics of Mercury Concentration in Vapor Phase from Compact Fluorescent Lamp (소형형광등(Compact Fluorescent Lamp)의 파쇄에 따른 기상에서의 수은농도 특성)

  • Rhee, Seung-Whee
    • Korean Chemical Engineering Research
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    • v.52 no.5
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    • pp.652-656
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    • 2014
  • Mercury amount in vapor phase from 3 types of CFL(compact fluorescent lamp) are estimated by measuring mercury concentration in vapor phase. The mercury concentration in vapor phase from CFL is sharply decreased during initial time and then the change in the mercury concentration is slightly decreased up to 24 hours. The mercury concentration in vapor phase is almost constant after 42 hours, which can be called by stabilized concentration. It can be estimated that the stabilized concentration is caused by the evaporation of mercury in the residues of broken CFL and can be affected by temperature and pressure in crushing apparatus. The mercury concentration for CFL manufactures are in the order of A < B < C as the same results of the initial mercury concentration and the stabilized concentration in vapor phase. As increased air flow rate, the partial pressure of mercury is decreased and the amount of mercury is reduced. Initially, the mercury concentration in vapor phase emitted from CFLs is higher than the regulatory level of $0.1mg/m^3$ in the specific facilities regardless of air flow rate. Hence, it is absolutely necessary that mercury in vapor phase should be controlled at the point of crushing campact fluorescent lamp.

Comparison of Liquid- and Vapor-Phase Spray Characteristics of E85 Fuel using Schlieren Visualization Technique (쉴리렌 가시화 기법을 이용한 E85 연료의 액상 및 기상 분무 비교)

  • Park, Suhan;Chang, Mengzhao
    • Journal of Institute of Convergence Technology
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    • v.8 no.1
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    • pp.9-13
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    • 2018
  • The purpose of this study is to investigate the liquid- and vapor-phase spray characteristics, such as spray tip penetration and spray angle using gasoline direct injection (GDI) injector with multi-hole. The vapor-phase spray was captured by the Schlieren visualization system, which consists of high-speed camera, LED lamp, concave mirrors, and knife-edge. The liquid-phase spray was visualized by Mie-scattering techniques. Both spray images of vapor- and liquid-phase were visualized under 373 K of ambient temperature, 1 bar of ambient pressure, and 100/200 bar of injection pressure. The energizing duration was fixed at 1.5 ms. From the analysis of experimental results, it revealed that the increased injection pressure induced an early vaporization due to the improvement of droplet atomization. The spray tip penetration and spray angle in vapor-phase were higher than those in liquid-phase. The difference in the spray tip penetration between vapor- and liquid-spray gradually increased with the time elapsed after the injection. Even with the spray angle characteristics, it was found that the difference between the spray angle of liquid and vapor spray gradually grew after they entered steady-state conditions.

Effect of HF and Plasma Treated Glass Surface on Vapor Phase-Polymerized Poly(3,4-ethylenedioxythiophene) Thin Film : Part I

  • Lee, Joonwoo;Kim, Sungsoo
    • Journal of Integrative Natural Science
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    • v.6 no.4
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    • pp.211-214
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    • 2013
  • In this study, in order to investigate how consecutive treatments of glass surface with HF acid and water vapor/Ar plasma affect the quality of 3-aminopropyltriethoxysilane self-assembled monolayer (APS-SAM), poly(3,4-ethylenedioxythiophene) (PEDOT) thin films were vapor phase-polymerized immediately after spin coating of FeCl3 and poly-urethane diol-mixed oxidant solution on the monolayer surfaces prepared at various treatment conditions. For the film characterization, various poweful tools were used, e.g., FE-SEM, an optical microscope, four point probe, and a contact angle analyzer. The characterization revealed that HF treatment is not desirable for the synthesis of a high quality PEDOT thin film via vapor phase polymerization method. Rather, sole treatment with plasma noticeably improved the quality of APS-SAM on glass surface. As a result, a highly dense and smooth PEDOT thin film was grown on uniform oxidant film-coated APS monolayer surface.

Expert System Approach for Vapor-Phase Infrared Spectra of Aromatic Compounds

  • Pyo Dongjin;Hwang Hoon;Lee Junyeoun
    • Bulletin of the Korean Chemical Society
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    • v.13 no.2
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    • pp.148-155
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    • 1992
  • Computerized interpretation of vapor phase infrared spectra using a novel expert system approach for spectra/structure correlation for vapor phase spectra is introduced. Rapid identification of aromatic functional groups of components in gaseous mixture can be achieved using this expert system.

Selective Vapor-Phase Deposition of Conductive Poly(3,4-ethylenedioxythiophene) Thin Films on Patterned FeCl3 Formed by Microcontact Printing

  • Lee, Bo H.;Cho, Yeon H.;Shin, Hyun-Jung;Kim, Jin-Yeol;Lee, Jae-gab;Lee, Hai-won ;Sung, Myung M.
    • Bulletin of the Korean Chemical Society
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    • v.27 no.10
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    • pp.1633-1637
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    • 2006
  • We demonstrate a selective vapor-phase deposition of conductive poly(3,4-ethylenedioxythiophene) (PEDOT) thin films on patterned $FeCl_3$. The PEDOT thin films were grown on various substrates by using the vapor-phase polymerization of ethylenedioxythiophene (EDOT) with $FeCl_3$ catalytic layers at 325 K. The selective deposition of the PEDOT thin films using vapor-phase polymerization was accomplished with patterned $FeCl_3$ layers as templates. Microcontact printing was done to prepare patterned $FeCl_3$ on polyethyleneterephthalate (PET) substrates. The selective vapor-phase deposition is based on the fact that the PEDOT thin films are selectively deposited only on the regions exposing $FeCl_3$ of the PET substrates, because the EDOT monomer can be polymerized only in the presence of oxidants, such as $FeCl_3$, Fe($CIO_4$), and iron(II) salts of organic acids/inorganic acids containing organic radicals.

Effect of HF and Plasma Treated Glass Surface on Vapor Phase-Polymerized Poly(3,4-ethylenedioxythiophene) Thin Film : Part II

  • Lee, Joonwoo;Kim, Sungsoo
    • Journal of Integrative Natural Science
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    • v.6 no.4
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    • pp.215-219
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    • 2013
  • In this study, in order to investigate how consecutive treatments of glass surface with HF acid and water vapor/Ar plasma affect the quality of 3-aminopropyltriethoxysilane self-assembled monolayer (APS-SAM), poly(3,4-ethylenedioxythiophene) (PEDOT) thin films were vapor phase-polymerized immediately after spin coating of FeCl3 and poly-urethane diol-mixed oxidant solution on the monolayer surfaces prepared at various treatment conditions. For the film characterization, various poweful tools were used, e.g., FE-SEM, an optical microscope, four point probe, and a contact angle analyzer. The characterization revealed that a well prepared APS-SAM on a glass surface treated with water vapor/Ar plasma is very useful for uniform coating of FeCl3 and DUDO mixed oxidant solution, regardless of HF treatment. On the other hand, a bare glass surface without APS-SAM but treated with HF and water vapor/Ar plasma generally led to a very poor oxidant film. As a result, PEDOT films vapor phase-polymerized on APS-SAM surfaces are far superior to those on bare glass surfaces in the quality and electrical characteristics aspects.

Atmospheric Concentrations of PAHs in the Vapor and Particulate Phases in Chongju

  • Park, Seung-Shik;Kim, Young-J.;Kang, Chang-H.;Cho, Sung-Yong;Kim, Tae-Young;Kim, Seung-Jai
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.E2
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    • pp.57-68
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    • 2006
  • Four intensive seasonal sampling campaigns between October 1998 and October 1999 were undertaken at an urban site of Chongju, in which polyurethane foam (PUF) sampler was used to collect particulate- and vapor-phase polycyclic aromatic hydrocarbons (PAHs). The contribution to total (particulate+vapor) PAH concentration by the vapor phase component exceeded the particulate phase contribution by factor of ${\sim}2.6$. Summed concentrations of phenanthrene (30.9%), pyrene (16.6%), naphthalene (11.3%) and fluoranthene (11.0%) account for significant amounts of the vapor-phase, while chrysene (12.5%), benzo[b]fluoranthene (11.6%), indeno[123-cd]pyrene (9.9%), benzo[ghi]perylene (9.5%), benzo[k]fluoranthene (9.4%), pyrene (8.9%), and benzo[a]pyrene (8.3%) are found to be the most common PAH compounds in the particulate phase. The results from application of principal component analysis to particulate-phase PAH data demonstrate that a combination of PAH and $PM_{2.5}$ inorganic data is a more powerful tracer of emission sources than PAH species data alone. Particulate-phase PAH species were found to be associated predominantly with emissions from diesel engine vehicles and incineration.

The Effects of Tumble and Swirl Flow on the Behavior of Liquid/Vapor Phases in a DI Gasoline Engine (직분식 엔진에서 실린더 내 연료의 액.기상 거동에 미치는 텀블과 스월의 영향)

  • 강정중;최동석;김덕줄
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.2
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    • pp.23-30
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    • 2002
  • This present study experimentally investigates the behavior of liquid and vapor phase of fuel mixtures with changing the in-cylinder air motion in an optically accessible engine. The conventional MPI/DOHC engine was modified to gasoline direct injection engine with swirl motion. The images of liquid and vapor phases were captured in the motoring operation condition using exciplex fluorescence method. Two dimensional spray fluorescence images of liquid and vapor phases were acquired to analyze spray behaviors and fuel distribution inside of cylinder respectively, In early injection timings $(BTDC\;270^{\circ},\;180^{\circ})$, tumble flow transported most of vapor phase to the lower region and the both sides of cylinder, so vapor phase didn't become uniform distribution up to the half of the compression stroke. In the case of swirl flow, the fuel mixture was confined near the swirl origin in upper region of cylinder. In late injection timings $(BTDC\;90^{\circ})$, tumble flow transported vapor phase to the intake valve and swirl flow to the exhaust valve.