• Mass Spectrometry Letters
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• v.11 no.4
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• pp.90-94
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• 2020

Interest in aspects of industrialization relating to human health has increased. Accordingly, the use of labels such as 'natural foods' and 'organic ingredients' has become more widespread, and greater emphasis is being placed on improving quality of life. Water is an essential element for human life, and water quality has a significant impact on human health. However, technology that can precisely determine the substances present in water is still lacking. This study was conducted to establish a complete mass spectrometry process, from pretreatment to analysis, to measure and characterize natural organic matter (NOM) in Korean spring water samples. Salts and other matrices were removed from the samples using solid-phase extraction (SPE) with two different columns (PPL and C18). After establishing an accurate analysis method, the experimental results were evaluated based on Van Krevelen diagrams and analysis of molar O/C and H/C ratios. The method for characterizing NOM introduced herein should facilitate evaluation of water quality.

• Mass Spectrometry Letters
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• v.14 no.4
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• pp.147-152
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• 2023

The increasing demand for two-dimensional imaging analysis using optical or electronic microscopic techniques has led to an increase in the use of simple one-dimensional and two-dimensional mass spectrometry imaging. Among these imaging methods, secondary-ion mass spectrometry (SIMS) has the best spatial resolution using a primary ion beam with a relatively insignificant beam diameter. Until recently, SIMS, which uses high-energy primary ion beams, has not been used to analyze molecules. However, owing to the development of cluster ion beams, it has been actively used to analyze various organic molecules from the surface. Researchers and commercial SIMS companies are developing cluster ion beams to analyze biological samples, including amino acids, peptides, and proteins. In this study, a water droplet ion beam for surface analysis was realized. Water droplets ions were generated via electrospraying in a vacuum without desolvation. The generated ions were accelerated at an energy of 10 keV and collided with the target sample, and secondary ion mass spectra were obtained for the generated ions using ToF-SIMS. Thus, the proposed water droplet ion-beam device showed potential applicability as a primary ion beam in SIMS.

• Journal of Power System Engineering
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• v.9 no.4
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• pp.71-76
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• 2005

Marine structures are often in contact with inner or outer fluid as stern, ballast and oil tanks. The effect of interaction between fluid and structure has to be taken into consideration when we estimate the dynamic response of the structure appropriately. Fatigue damages can also be sometimes observed in these tanks which seem to be caused by resonance. Thin walled tank structures in ships which are in contact with water and located near engine or propeller where vibration characteristics are strongly affected by the added mass of containing water. Therefore it is essentially important to estimate the added mass effect to predict vibration characteristics of tank structures. But it is difficult to estimate exactly the magnitude of the added mass because this is a fluid-structure interaction problem and is affected by the free surface, vibration modes of structural panels and the depth of water. I have developed a numerical tool of vibration analysis of 3-dimensional tank structure using finite elements for plates and boundary elements for fluid region. In the present study, the effect of added mass of containing water, the effect of structural constraint between panels on the vibration characteristics are investigated numerically and discussed. Especially a natural frequencies by the fluid interaction between 2 panels and a breath mode of the water tank are focused on.

• Tunnel and Underground Space
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• v.8 no.2
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• pp.79-86
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• 1998

This study was performed to suggest to suggest suitable design conditions of water curtain system through analysis on pressure down in boreholes by hydraulic tests carried out I construction fields for underground oil storages. The influence by hydraulic conductivities of rock mass around boreholes on pressure down in boreholes was analysed. The relationship between array of boreholes and their pressure down was also analysed. Groundwater flow analysis on crude oil and LPG storages was carried out to evaluate results of field tests and to investigate distribution of hydraulic gradient in rock mass around cavern using finite difference method. As the results, hydraulic tests showed that pressure down in boreholes was inverse proportional to the hydraulic conductivity of surrounding rock mass. The rate of pressure down of boreholes was not influenced by water curtain system more than 20m over cavern and was proportional to installation interval of boreholes. The hydraulic gradient in rock mass around cavern was proportional to distance and interval of boreholes and its value was not satisfactory to oil tightness condition in case of no water curtain system.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2002.05a
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• pp.41-47
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• 2002

A model of simultaneous heat and mass transfer process in absorption of refrigerant vapor into a lithium bromide solution of water-cooled vertical plate absorber was developed. The model can predict temperature and concentration profiles as well as the absorption heat and mass fluxes, the total heat and mass transfer rates and the heat and mass transfer coefficients. Besides, the effect of operating condition on absorption mass flux has been investigated, with the result that the absorption mass flux is increased as the inlet cooling water temperature decreases, the system pressure increases and the inlet solution concentration increases. And among the effects of operating parameters on absorption mass flux, the effect of inlet solution concentration is dominant.

• Ocean Science Journal
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• v.41 no.4
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• pp.255-260
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• 2006

Long-term variability in the intermediate layer of the eastern Japan Basin has been investigated to understand the variability of water mass formation in the East Sea. The simultaneous decrease of temperature at shallower depths and oxygen increasing at deeper depths in the intermediate layer took place in the late 1960's sand the mid-1980's. Records of winter sea surface temperatures and air temperatures showed that there were cold winters that persisted for several years during those periods. Therefore, it was assumed that a large amount of newly-formed water was supplied to the intermediate layer during those cold winters. Close analysis suggests that the formation of the Upper Portion of Proper Water occurred in the late 1960's and the Central Water in the mid-1980's.

• Aerospace Engineering and Technology
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• v.12 no.1
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• pp.163-172
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• 2013

In this study, the cooling of rocket exhaust plume by sprayed water inside plume were investigated as varying of sprayed water mass, location, and method using computational fluid analysis. For Analyze rocket exhaust plume, a single species unreacted analysis model based on the chemically frozen analysis was used and the discrete particle model which was a kind of Euler-Lagrangian analysis model was used for simulate sprayed water inside plume. It was confirmed that the temperature of plume was reduced without cooling when water mass was two times of plume mass through analysis results.

• Journal of the Society of Naval Architects of Korea
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• v.40 no.4
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• pp.46-52
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• 2003

In ship structures, many parts are in contact with inner or outer fluid as stern, ballast and oil tanks. Fatigue damages can be sometimes observed in these tanks which seem to be caused by resonance. Tank structures in ships are in contact with water and the vibration characteristics are strongly affected by the added mass of containing water. Therefore it is important to predict vibration characteristics of tank structures. In order to estimate the vibration characteristics, the fluid-structure interaction problem has to be solved precisely. In the present paper, we have developed a numerical tool of vibration analysis of 3-dimensional tank structures using finite elements for plates and boundary elements for water region. To verify the present analysis, we have made an experiment for vibration characteristics of a tank with elastic opposite panels. And the added mass effect of containing water and the effect of structural constraint between panels are investigated numerically and discussed.

• Journal of Mechanical Science and Technology
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• v.17 no.1
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• pp.122-128
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• 2003

This paper presents a thermodynamic analysis of heat pump system using water as a heat source and heat sink. The primary object in this study is the optimization of exergetic efficiency. Two different systems, 2-stream and 1-stream system, are analyzed in detail. Mass flow ratio (the ratio of mass flow rate of water through evaporator to that through condenser) is identified as the most important parameter to be optimized. It is shown that there exists an optimum mass flow ratio to maximize exergetic efficiency. The variation of optimum exergetic efficiency of 2-stream system is quite small and the value lies between 0.2∼0.23 for the range of investigation in this study. However, far better performance can be obtained from 1-stream system. This means considerable irreversibilities are generated through condenser of the 2-stream system. The effects of adiabatic efficiency of compressor-motor unit on the overall system performance are also examined in the analysis.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2626-2631
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• 2007

Air-water two phase natural circulation flow in the T-HERMES (Thermo-Hydraulic Evaluation of Reactor cooling Mechanism by External Self-induced flow)-1D experiment has been evaluated to verify and evaluate the experimental results by using the RELAP5/MOD3 computer code. The RELAP5 results have shown that an increase in the coolant inlet area leads to an increase in the water circulation mass flow rate. However, the water outlet area does not effective on the water circulation mass flow rate. As the coolant outlet moves to a lower position, the water circulation mass flow rate decreases. The water level is not effective on the water circulation mass flow rate. As the height increases in the air injection part, the void fraction increases. However, the void fraction in the upper part of the air injector maintains a constant value. An increase in the air injection mass flow rate leads to an increase in the local void fraction, but it is not effective on the local pressure.