• Title/Summary/Keyword: Water vapor

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Preparation and Properties of Waterborne Polyurethane-Urea/Poly(vinyl alcohol) Blends for High Water Vapor Permeable Coating Materials

  • Yun, Jong-Kook;Yoo, Hye-Jin;Kim, Han-Do
    • Macromolecular Research
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    • v.15 no.1
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    • pp.22-30
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    • 2007
  • High water vapor permeable coating materials were prepared by blending aqueous poly(vinyl alcohol) (PVA) solution with waterborne polyurethane-urea (WBPU) dispersions synthesized by prepolymer mixing process. Stable WBPU/PVA dispersions were achieved at PVA content below 30 wt%. As the water soluble polymer PVA content increased, the number and density of total micro-pores (tunnel-like/isolated micro-pores) formed after the dissolution of PVA in water increased, and the water vapor permeability of coated Nylon fabric also increased significantly. Using WBPU/water soluble polymer PVA blends as a coating material and then dissolving PVA in water was confirmed to be an effective method to obtain prominent breathable fabrics.

An Experimental Study of Water Vapor Pressure that occurs at the Interface of a Fluid-Applied Membrane and Concrete (콘크리트와 도막 방수층 계면에 발생되는 수증기압에 관한 실험적 연구)

  • Ko, Jin-Soo;Kim, Mun-Hee;Lee, Sung-Bok;Shin, Yun-Ho
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.11a
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    • pp.147-150
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    • 2006
  • Of the total defects that have occurred recently in the Korean construction market, over 30% are caused by the construction of defective waterproofing, and the phenomenon of air pockets in the waterproofing layer, which is caused by the concrete vapor pressure, is known to be the primary cause of defective waterproofing. Accordingly, in this study the theory about the relationship between water pressure and temperature as well as the damp-proofing volume of concrete and, then, the change of vapor pressure volume was measured and analyzed by making a test sample after spraying a dampness remover and a waterproofing material to a prepared test body. As a result of measuring the water vapor pressure for the surface temperature of the waterproofing layer with the fluid-applied membrane temperature based on about $10^{\circ}C$, which is the average temperature of Seoul, it was found that first, the fluid-applied membrane elevated up to about $40^{\circ}C$, and the water vapor pressure generated from the fluid-applied membrane was about $0.3kgf/cm^2$ when the surface temperature of the waterproofing layer was raised up to about $80^{\circ}C$. Second, when the fluid-applied membrane temperature of the waterproofing layer was raised from $30^{\circ}C\;to\;35^{\circ}C,\;about\;0.1kgf/cm^2$ of water vapor pressure was generated, and when supplying a thermal source to raise the fluid-applied membrane temperature of the waterproofing layer from $35^{\circ}C\;to\;40^{\circ}C$, approximately $0.05kgf/cm^2$ of water vapor pressure was generated.

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Adsorption Characteristics of Water Vapor on Zeolite (Zeolite의 수증기 흡착특성)

  • Lee, Song-Woo;Na, Young-Soo;An, Chang-Doeuk;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.20 no.5
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    • pp.667-672
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    • 2011
  • The purpose of this work is to present the experiment results by a dynamic adsorption of water vapor on pelletized zeolites (ADZ300, ADZ400, and ADZ500) in fixed bed. The breakthrough curves of water vapor with several different concentrations and temperature in the range of 25~45 $^{\circ}C$ on zeolite bed were investigated. In the same conditions, the breakthrough time on ADZ400 and ADZ500 were little longer than ADZ300, and the equilibrium adsorption capacity on ADZ500 was highest. The higher the concentration of water vapor was, the faster the breakthrough time was, and the slope of breakthrough curves showed a tendency to increase. The faster the flow rate of water vapor was, the faster the breakthrough time was relatively, but variations between flow rate and breakthrough time did not have a proportional relationship. The breakthrough curve maintained constant gradient in spite of variation of flow rate in the same concentration. The temperature rise in zeolite bed by adsorption heat was occurred in the early stage of adsorption. After water molecule layers were formed on the surface of zeolite, the temperature was slowly cooled by water vapors continuously flowed in as constant temperature. The greater the concentration of water vapor and adsorption temperature were, the temperature difference in zeolite bed was increased.

Water-Vapor Transfer Characteristics of Carrageenan-Based Edible Film (카라기난 필름의 투습 특성)

  • Rhim, Jong-Whan;Hwang, Keum-Taek;Park, Hyun-Jin;Jung, Soon-Teck
    • Korean Journal of Food Science and Technology
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    • v.28 no.3
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    • pp.545-551
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    • 1996
  • Water-vapor transmission rate and water-vapor permeability of carrageenan-based edible film with three different thicknesses of 0.05, 0.08 and 0.11 mm were measured to investigate the potential applicability of the films to powder foods at five different temperatures (20, 25, 30. 35 and $4^{\circ}C$) and three different relative humidities (50. 70 and 90% RH). Water-vapor transmission rate of the carrageenan-based film was gound to be 2.3 times higher than that of polyethylene (PE) film and water-vapor permeability of the film was 45-230 times higher than that of PE film. Water-ydpor permeability of the film seemed to increase linearly with the film thicknees like other hydrophilic edible films. Water-vapor transmission rate were found to be dependent on the temperature. Activation energies of the water-vapor transmission rate of the film were found to be between 7.898 and 12.8702 kj/mol depending on the film thickness. The water-vapor transmission rate of the film showed the typical kinetic compensation effect between activation energies and preexponential factors. which was proved by the linear increase in the value of logarithms of preecponential factor.

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Water Vapor and Thermal Transmission Properties of Hybrid Yarns Fabrics for High Emotional Garments -Water Vapor and Heat Transport according to Experimental-Method- (고감성 의류용 복합사 직물의 수분증기 및 열이동 특성 -실험방법에 따른 수분증기 및 열이동-)

  • Kim, SeungJin;Kim, Hyunah
    • Journal of the Korean Society of Clothing and Textiles
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    • v.41 no.1
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    • pp.84-97
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    • 2017
  • Water vapor and thermal transmission properties of high emotional garments are important to evaluate wear comfort; in addition, the measuring methods of these properties are also critical for breathable and warm suit fabrics. In this study, the water vapor and thermal properties of composite yarn fabrics made of CoolMax, Tencel, and Bamboo fibers with filaments were measured and compared according to the measuring method. Water Vapor Transmittance (WVT) of the fabric woven by the sheath/core composite yarn in the warp direction was the highest due to the small staple fiber volume in the sheath/core yarn structure and high air voids in the sheath/core yarn fabrics. This property was also the highest in fabrics woven by bamboo staple yarns in the weft direction, and was the lowest on hi-multi filament fabrics. However, water vapor resistance ($R_{ef}$) of these fabrics by KSK ISO 11092 showed the opposite results to the water vapor transmittance method ($CaCl_2$ method); in addition, its correlation coefficient was low. The correlation coefficient between $R_{ef}$ and the drying rate was 0.719; therefore, the measurement mechanism of $R_{ef}$ is analogous to the drying property measurement. The thermal conductivity of the fabrics woven with compact staple yarn showed a high value; however, the hi-multi filament fabric showed low thermal conductivity. Therefore, fiber characteristics affect thermal properties more than yarn structure. The correlation between thermal property and moisture transport was also low. This study showed that: water vapor transmittance was active at the loose yarn structure, dry heat transport was vigorous at the compact yarn structure, and heat transport was affected more by fiber characteristics than yarn structure. In conclusion, sheath/core composite yarns were relevant to the high absorptive cool suit along with siro-fil and CoolMax/Bamboo staple yarns that were relevant to the heat diffusive cool suit.

Heat and Mass Transfer Characteristics of a Falling Film Ammonia Absorber with Respect to the Vapor Flow Direction (유하액막식 암모니아 흡수기에서 증기 유동방향에 따른 열 및 물질전달 특성)

  • 권경민;정시영;김병주;정은수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.1
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    • pp.16-25
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    • 2004
  • The flow and heat/mass transfer in the falling-film of a heat exchanger can be influenced by the motion of the surrounding refrigerant vapor. In this study, the effect of the vapor flow direction on the absorption heat transfer has been investigated for a falling-film helical coil which is frequently used as the absorber of ammonia/water absorption refrigerators. The experiments were carried out for different solution concentration. The heat and mass transfer performance was measured for both parallel and counter-current flow. The effect of vapor flow on the heat and mass transfer is found to be increased with decreasing solution concentration. In the experiments with low solution concentration, whose vapor specific volume is great, the counter-current flow of vapor resulted in uneven distribution of falling-film and reduced the heat transfer performance of the absorber. The direction of the vapor flow hardly affected the thermal performance as the solution concentration became stronger since the specific volume of the ammonia/water vapor was much smaller than that of the water vapor.

Molecular Diffusion of Water in Paper(III) -Theoretical analysis on vapor sorption properties of fiber surface - (종이내 수분확산 (제3보) -종이 표면의 수증기-흡습성에 관한 이론적 고찰-)

  • Yoon, Sung-Hoon;Jeon, Yang;Park, Jong-Moon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.1
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    • pp.61-71
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    • 1999
  • The study aimed at the theoretical analysis of vapor sorption properties of, pp.rmaking fibers. Water vapor affinity and sorption thermodynamic properties of fiber constituents were evaluated based on Henry's law and Hildebrand's solubility theory. Theoretical equilibrium moisture content(ThEMC) on fiber surface was estimated using functional group contribution. Crystallinity of cellulose in fiber significantly controlled the water vapor solubility. Comparisons of the measured equilibrium moisture content data and the estimated ThEMC data coincidently suggested the fact that crystallinity of cellulose in fibers was around 60% to 70%. Carbohydrates constituents including amorphous cellulose and hemicellulose in fibers showed higher vapor solubility than lignin molecules. High correlation existed between ThEMC and vapor solubility as well as between ThEMC and solubility parameter. In the thermodynamic analysis on water-vapor sorption process in fibers, the sorption enthalpy increased as RH increased, whereas sorption entropy and free energy decreased with increasing RH.

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Water vapor barrier properties of polymer-like amorphous carbon deposited polyethylene naphthalate film

  • Kim, Jeong-Yong;Park, Gyu-Dae;Song, Ye-Seul;Lee, Hui-Jin;Vu, Minh Canh;Kim, Seong-Ryong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.303.1-303.1
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    • 2016
  • Polymer-like amorphous carbon films were deposited on polyethylene naphthalate (PEN) substrate by plasma-enhanced chemical vapor deposition (PECVD) and their water vapor transmission rates (WVTR) were tested. propane was used as precursors. To make a polymer-like amorphous carbon film the deposition rate, surface roughness, light transmittance, and WVTR of the films were characterized as a function of the precursor feed ratio and plasma power. The water vapor transmission rates of bare PEN film and single layer PAC on PEN substrate were 6.95 g/m2/day and 0.3 g/m2/day, respectively. The superior property the water vapor permeability of thin layers of PAC was attributed to uniform coverage and good adhesion between PAC film and PEN substrate.

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Mass transfer in adiabatic rectifier of ammonia-water absorption system (암모니아-물 흡수식 시스템에서 단열정류기의 물질 전달)

  • 김병주
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.3
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    • pp.414-421
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    • 1999
  • Falling film rectification involves simultaneous heat and mass transfer between vapor and liquid interface. In the present work, the adiabatic rectification process of ammonia-water vapor on the vertical plate was investigated. The continuity, momentum, energy and diffusion equations for the solution film and vapor mixture were formulated in integral forms and solved numerically. The model could predict the film thickness, the pressure gradient, and the mass transfer rate. The effects of Reynolds number and ammonia concentration of solution and vapor mixture, rectifier length, and the enhancement of mass transfer in each phases were investigated. The stripping of water in vapor mixture occurred new the entrance of ammonia solution, which imposed the proper size of an adiabatic rectifier. Rectifier efficiency increased as film Reynolds number increased and as vapor mixture Reynolds number decreased. The improvement of rectifier efficiency was significant with the enhancement of mass transfer in falling film.

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Mass Transfer in an Adiabatic Rectifier of Ammonia-Water Absorption System

  • Kim, Byong-Joo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.8 no.2
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    • pp.69-79
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    • 2000
  • Falling film rectification involves simultaneous heat and mass transfer between vapor and solution film. In the present work, the adiabatic rectification process of ammonia-water vapor by the falling solution film on the vertical plate was investigated. The continuity momentum, energy and diffusion equations for the solution film and the vapor mixture were formulated in integral forms and solved numerically, The model could predict the film thickness, the pressure gradient, and the mass transfer rate. The effects of Reynolds number and ammonia concentration of solution and vapor mixture, rectifier length, and the enhancement of mass transfer coefficient in each phases were investigated. The stripping of water in vapor mixture occurred near the entrance of ammonia solution, which imposed the proper size of an adiabatic rectifier. Rectifier efficiency increased as film Reynolds number increased and as vapor mixture Reynolds number decreased. The improvement of rectifier efficiency was significant with the enhancement of mass transfer coefficient in falling film.

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