• Title/Summary/Keyword: Wet foams

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Stabilization of Wet Foams for Porous Ceramics Using Amphiphilic Particles

  • Pokhrel, Ashish;Park, Jung-Gyu;Nam, Jeong-Sic;Cheong, Deock-Soo;Kim, Ik-Jin
    • Journal of the Korean Ceramic Society
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    • v.48 no.5
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    • pp.463-466
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    • 2011
  • Wet foams formed through direct foaming were stabilized using various concentrations of amiphiphilic particles that could control pore size and porosity. These porous materials showed moderate strength upon compression with high porosity. Bubble size and wet foam stability were tailored by amphiphile concentration, particle concentration, contact angle, and pH of the suspension to obtain crack-free porous solid after sintering. Closed and open pores were obtained with sizes of 30~300 ${\mu}m$ and porosities of over 80%.

Processing of Porous Ceramics by Direct Foaming: A Review

  • Pokhrel, Ashish;Seo, Dong Nam;Lee, Seung Taek;Kim, Ik Jin
    • Journal of the Korean Ceramic Society
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    • v.50 no.2
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    • pp.93-102
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    • 2013
  • Macro porous ceramics possessing controlled microstructures and chemical compositions have increasingly proven useful in the industrial sphere. Their sintered structures have found application in both established and emerging, areas such as thermal insulation in buildings, filtration of liquids and molten materials, refractory insulation, bone scaffolds and tissue engineering. Stable ceramic foams can be formed by wet chemical methods using inorganic particles(e.g., $Al_2O_3$ or $SiO_2$). The wet foams are dried and sintered with improved porosity and mechanical properties. This review examines the different techniques used to prepare porous ceramics from ceramic foams, focusing on the explanation of this versatile method of direct foaming from the past to the present. Comparisons of the processes and the processing parameters are explained with the produced microstructures.

Controlling the Porosity of Particle Stabilized Al2O3 Based Ceramics

  • Pokhrel, Ashish;Park, Jung-Gyu;Jho, Gae-Hyong;Kim, Jin-Young;Kim, Ik-Jin
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.600-603
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    • 2011
  • The microstructure of particle stabilized wet foams can be tailored by using parameters including the amphiphile concentration, contact angle, and surface tension. The influence of these parameters on the porosity is satisfactorily described in terms of a combined influence of the contact angle and surface tension of the initial suspensions that are directly affected by the amphiphile concentration. The resulting macroporous structures exhibited a total porosity of 82%. The foam cells were predominantly closed due to the air bubbles of the original wet foams being completely covered.

Development of Multi-functional Mulch Papers and Evaluation of Their Performance(Part 3) -Defoaming Treatment during Trial Production of Mulch Papers and Their Influence on Wet End System- (다기능성 멀칭지의 개발 및 적용성 평가(제3보) -시제품 생상시 공정 백수의 거품제거 처리 및 그 영향에 관하여-)

  • 이학래;이진희
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.3
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    • pp.25-31
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    • 2000
  • It is required to use substantial amount of wet strength resin for producing multi-functional mulch papers since these paper products shold maintain its strength properties when they exposed to outdoor weather for several months. While producing mulch papers it is usual to observe significant amount of foam at white water silo. Thus it is imperative to use defoaming or antifoaming agents. In this study diverse defoaming and antifoaming agents have been tested for their effective-ness in eliminating foams that produced. It was shown that combined use of a silicone type defoamer and a fatty acid type anti-foaming agent was msot effective in eliminating foams. These chemicals were used in trial production of mulch papers and their influence on paper-making wet end system was examined including one pass retention cationic demand con-ductivity pH etc. It was found that the defoaming agents were very effective for removing foams in trial production. Tensile strengths of the mulch papers produced were significantly greater than commericial mulch papers produced in Japan.

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Fabrication of Macroporous Carbon Foam with Uniform Pore Size Using Poly(methyl methacrylate) Particles As The Template

  • Kim, Jin-Sil;Rhym, Young-Mok;Shim, Sang-Eun
    • Journal of Powder Materials
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    • v.18 no.2
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    • pp.129-134
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    • 2011
  • Herein, macroporous carbon materials were readily prepared by carbonization of cured body of resorcinol and formaldehyde using poly(methyl methacrylate) colloid microspheres which were employed as the template in the gelation of resorcinol with formaldehyde. The gel in the water was solvent exchanged with methanol and the wet gel was dried. After carbonization of the template-gel composite at $800^{\circ}C$, it was found that pores were left corresponding to the size of the template, yielding carbon materials with a fine porous structure with enlarged surface area and significant porosity. Properties of the carbon foams including the structure, morphology, thermal stability, and porosity were investigated. Finally, it was concluded that the method using polymer colloids as the template provided a facile route to prepare carbon foams.

Particle Stabilized Wet Foam to Prepare SiO2-SiC Porous Ceramics by Colloidal Processing

  • Bhaskar, Subhasree;Park, Jung Gyu;Han, In Sub;Lee, Mi Jai;Lim, Tae Young;Kim, Ik Jin
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.455-461
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    • 2015
  • Porous ceramics with tailored pore size and shape are promising materials for the realization of a number of functional and structural properties. A novel method has been reported for the investigation of the role of SiC in the formation of $SiO_2$ foams by colloidal wet processing. Within a suitable pH range of 9.9 ~ 10.5 $SiO_2$, particles were partially hydrophobized using hexylamine as an amphiphile. Different mole ratios of the SiC solution were added to the surface modified $SiO_2$ suspension. The contact angle was found to be around $73^{\circ}$, with an adsorption free energy $6.8{\times}10^{-12}J$. The Laplace pressure of about 1.25 ~ 1.6 mPa was found to correspond to a wet foam stability of about 80 ~ 85%. The mechanical and thermal properties were analyzed for the sintered ceramics, with the highest compressive load observed at the mole ratio of 1:1.75. Hertzian indentations are used to evaluate the damage behavior under constrained loading conditions of $SiO_2$-SiC porous ceramics.

A Study on Applicability of Citrus Sludge for the Manufacture of Corrugated Medium (골심지 제조를 위한 감귤 착즙 슬러지의 적용성 평가)

  • Lee, Tai-Ju;Kim, Hyoung-Jin;Lee, Chang-Yong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.5
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    • pp.47-53
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    • 2010
  • It is important to utilize the citrus sludge in terms of the reuse of waste materials in the manufacture of corrugated medium. Especially, the mandarin industry occupies the first place in Jeju province. In this paper, the application of citrus sludge mixed with KOCC recycled fibers into the manufacture of corrugated medium was studied. The citrus sludge was acidic in pH value. Also, the constituents of citrus sludge contain some short fibers, fines, and mucus which contain flavonoids, pectins and so on. In papermaking application, these components cause some troubles like foams, bad smell, fouling on the paper machine, and bad drainage and web breaks of wet web. The strength properties of handsheets prepared from KOCC and citrus sludge was decreased, compare to handsheets made of only KOCC. To compensate the problems on strength properties, some kinds of additives were tried to apply into papermaking wet-end system in laboratory scale. As a result, mixing conditions of alum, starch and anionic additives showed the best options in the recovery of strength properties and formations of corrugated medium.