• Title/Summary/Keyword: aluminum oxide

Search Result 897, Processing Time 0.036 seconds

Electrochemical Thinning for Anodic Aluminum Oxide and Anodic Titanium Oxide

  • Lee, In-Hae;Jo, Yun-Kyoung;Kim, Yong-Tae;Tak, Yong-Sug;Choi, Jin-Sub
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.5
    • /
    • pp.1465-1469
    • /
    • 2012
  • For given electrolytes, different behaviors of anodic aluminum oxide (AAO) and anodic titanium oxide (ATO) during electrochemical thinning are explained by ionic and electronic current modes. Branched structures are unavoidably created in AAO since the switch of ionic to electronic current is slow, whereas the barrier oxide in ATO is thinned without formation of the branched structures. In addition, pore opening can be possible in ATO if chemical etching is performed after the thinning process. The thinning was optimized for complete pore opening in ATO and potential-current behavior is interpreted in terms of ionic current-electronic current switching.

Corrosion behavior of oxide layer formed on surface of high silicon aluminum alloy by PEO process (고규소 알루미늄 합금의 표면에 PEO 공정에 의하여 형성된 산화물 층의 부식 거동)

  • Deok-Yong Park
    • Journal of the Korean institute of surface engineering
    • /
    • v.56 no.4
    • /
    • pp.250-258
    • /
    • 2023
  • Ceramic oxide layer was formed on the surface of high silicon aluminum alloy by using PEO (plasma electrolytic oxidation) process. The microstructure of the oxide layer was analyzed using scanning electron microscopy (SEM) and x-ray diffraction patterns (XRD). The high silicon aluminum alloy prior to PEO process consists of Al, Si and Al2Cu phases in XRD analysis, whereas Al2Cu phase selectively disappeared after PEO treatment. Considerable decrease of relative intensity in most of peaks in XRD results of the high silicon aluminum alloy treated by PEO process was observed. It may be attributed to the formation of amorphous phases after PEO treatment. The corrosion behavior of the high silicon aluminum alloy treated by PEO process was investigated using electrochemical impedance spectroscopy (EIS) and other electrochemical techniques (i.e., open circuit potential and polarization curve). Electroanalytical studies indicated that the high silicon aluminum alloy treated by PEO process shows greater corrosion resistance than that untreated by PEO process.

Effect of Solution Temperature for Al Alloy Anodizing on Cavitation Characteristics (캐비테이션 특성에 미치는 알루미늄 합금의 양극 산화 용액 온도의 영향)

  • Lee, Seung-Jun;Lee, Jung-Hyung;Kim, Seong-Jong
    • Corrosion Science and Technology
    • /
    • v.14 no.3
    • /
    • pp.140-146
    • /
    • 2015
  • The commercialization of aluminum had been delayed than other metals because of its high oxygen affinity. Anodizing is a process in which oxide film is formed on the surface of a valve metal in an electrolyte solution by anodic oxidation reaction. Aluminum has thin oxide film on surface but the oxide film is inhomogeneous having a thickness only in the range of several nanometers. Anodizing process increases the thickness of the oxide film significantly. In this study, porous type oxide film was produced on the surface of aluminum in sulfuric acid as a function of electrolyte temperature, and the optimum condition were determined for anodizing film to exhibit excellent cavitation resistance in seawater environment. The result revealed that the oxide film formed at $10^{\circ}C$ represented the highest cavitation resistance, while the oxide film formed at $15^{\circ}C$ showed the lowest resistance to cavitation in spite of its high hardness.

New Front Plate Structure of ac-PDP using Aluminum Fence-Type Electrode Coated with Anodic Aluminum Oxide

  • Lee, Mi-yeon;Yoon, Sang-Hoon;Kim, Yong-Seog
    • Journal of Information Display
    • /
    • v.8 no.4
    • /
    • pp.19-22
    • /
    • 2007
  • A new front plate structure of ac-PDP using fence-type aluminum electrode coated with anodic aluminum oxide was investigated. In this structure, ITO and glass dielectric layer were eliminated and expensive Ag BUS electrode was replaced with aluminum. Test panels were prepared using the new structure and their luminance and discharge characteristics were examined. These results indicate that the new structure provide a new way of cost reduction and enhancement of performance of ac-PDPs

New Front Plate Structure of ac-PDP using Aluminum Fence-type Electrode Coated with Anodic Aluminum Oxide

  • Lee, Mi-Yeon;Yoon, Sang-Hoon;Kim, Yong-Seog
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2007.08a
    • /
    • pp.127-130
    • /
    • 2007
  • A new front plate structure of ac-PDP was explored using fence-type aluminum electrode coated with anodic aluminum oxide.[1] In this structure, ITO and glass dielectric layer were eliminated and expensive Ag BUS electrode was replaced with aluminum. Test panels were prepared using the new structure and their luminance and discharge characteristics were examined. These results indicate that the new structure provide a new way of cost reduction and enhancement of performance of ac-PDPs

  • PDF

Study on Corrosion and Oxide Growth Behavior of Anodized Aluminum 5052 Alloy (알루미늄 5052 합금의 산화피막 성장 및 내식성 연구)

  • Ji, Hyejeong;Jeong, Chanyoung
    • Journal of the Korean institute of surface engineering
    • /
    • v.51 no.6
    • /
    • pp.372-380
    • /
    • 2018
  • Anodization techniques are widely used in the area of surface treatment of aluminum alloys because of its simplicity, low-cost and good corrosion resistance. In this study, we investigated the relationship between the properties (porosity and thickness) of anodic aluminum oxide (AAO) and its corrosion behavior. Aluminum 5052 alloy was anodized in 0.3 M oxalic acid at $0^{\circ}C$. The anodizing of aluminum 5052 was performed at 20 V, 40 V and 60 V for various durations. The corrosion behavior was studied in 3.5 wt % NaCl using potentiodynamic polarization method. Results showed that the pore diameter and thickness increased as voltage and anodization time increased. The relatively thick oxide film revealed a lower corrosion current density and a higher corrosion potential value.

A STUDY ON THE BOND STRENGTH OF HEAT-CURING ACRYIC RESIN BONDED TO A SURFACE OF CASTED ALLOY (주조 금속 표면과 열 중합 수지 표면간의 결합 강도에 관한 연구)

  • Lee, Yong-Seok;Chang, Ik-Tae
    • The Journal of Korean Academy of Prosthodontics
    • /
    • v.34 no.3
    • /
    • pp.620-631
    • /
    • 1996
  • Bonding of resin to cast alloy has traditionally been provided by mechanical retention. But, chemical bonding methods such as silicoating, tin plating, heat treatment, application of 4-META adhesives, have been developed to overcome the problems of the mechanical bonding methods. Silicoating has been used availaby in fixed prosthodontics, but is also reported to be used in removable prosthodontics. The aim of this study is to measure the tensile bond strength between resin and metal, and compare the effect of the type of metal and the grain size of the aluminum oxide on the bond strength, after metal surface roughening, coating of the opaque resin, and curing of heat-curing resin were performed. The test groups were divided into 4 groups according to the cast alloys and the aluminum oxide particles used. Group 1 : Type 4 gold alloy(DM66) blasted with $$50{\mu}m\;Al_{2}O_3$$ Group 2 : Type 4 gold alloy(DM66) blasted with $$250{\mu}m\;Al_{2}O_3$$, Group 3 : Co-Cr alloy(Nobilium) blasted with $$50{\mu}m\;Al_{2}O_3$$ Group 4 : Co-Cr alloy(Nobilium) blasted with $$250{\mu}m\;Al_{2}O_3$$ * 10 test specimens were made on each group. The specimens were thermocycled, and Instron Universal testing machine was used to measure the tensile bond strength of the finished specimens. The results were as follows : 1. Bond strengths showed that the group of gold alloy blasted with $250{\mu}m$ aluminum oxide particle had higher bond strength, and the group of gold alloy blasted with $50{\mu}m$ aluminum oxide particles had lower bond strength than any of the other groups. 2. Gold alloy had significantly higher bond strength when blasted with $250{\mu}m$ aluminum oxide particles than $50{\mu}m$, but. Co-Cr alloy showed no statistically significant difference between the two particle sizes. 3. When blasted with $50{mu}m$ aluminum oxide particles, Co-Cr alloy showed significantly higher bond strength than gold alloy. And, when blasted with $250{\mu}m$ aluminum oxide particles, gold alloy had significantly higher bond strength than Co-Cr alloy. 4. On the examination of the fractured sites, only the group of Co-Cr alloy blasted with $50{\mu}m$ aluminum oxide particles showed a part of residual opaque resin, but all the samples of the other groups fractured between the resin and the metal.

  • PDF

Effect of silica coating on bond strength between a gold alloy and metal bracket bonded with chemically cured resin

  • Ryu, Min-Ju;Gang, Sung-Nam;Lim, Sung-Hoon
    • The korean journal of orthodontics
    • /
    • v.44 no.3
    • /
    • pp.105-112
    • /
    • 2014
  • Objective: The purpose of this study was to evaluate the effects of three different surface conditioning methods on the shear bond strength (SBS) of metal brackets bonded directly to gold alloy with chemically cured resin. Methods: Two hundred ten type III gold alloy specimens were randomly divided into six groups according to the combination of three different surface conditioning methods (aluminum oxide sandblasting only, application of a metal primer after aluminum oxide sandblasting, silica coating and silanation) and thermocycling (with thermocycling, without thermocycling). After performing surface conditioning of specimens in accordance with each experimental condition, metal brackets were bonded to all specimens using a chemically cured resin. The SBS was measured at the moment of bracket debonding, and the resin remnants on the specimen surface were evaluated using the adhesive remnant index. Results: Application of metal primer after aluminum oxide sandblasting yielded a higher bond strength than that with aluminum oxide sandblasting alone (p < 0.001), and silica coating and silanation yielded a higher bond strength than that with metal primer after aluminum oxide sandblasting (p < 0.001). There was no significant change in SBS after thermocycling in all groups. Conclusions: With silica coating and silanation, clinically satisfactory bond strength can be attained when metal brackets are directly bonded to gold alloys using a chemically cured resin.

Effects of Various Deposition Rates of Al2O3 Gate Insulator on the Properties of Organic Thin Film Transistor (알루미늄 옥사이드 절연층의 증착율이 유기박막 트랜지스터의 특성에 미치는 영향)

  • Choi, Kyung-Min;Hyung, Gun-Woo;Kim, Young-Kwan;Choi, Eou-Sik;Kwon, Sang-Jik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.22 no.12
    • /
    • pp.1063-1066
    • /
    • 2009
  • In this study, we fabricated pentacene organic thin film trasistors(OTFTs) which used aluminum oxide as the gate insulator. Aluminum oxide for OTFTs was deposited on glass substrate with a different deposition rate by E-beam evaporation. In case of the deposition rate of $0.1\;{\AA}$, the fabricated aluminum oxide gate insulating OTFT showed a threshold voltage of -1.36 V, an on/off current ratio of $1.9{\times}10^3$ and field effect mobility $0.023\;cm^2/V_s$.

Metal nano-wire fabrication and properties (금속 나노와이어의 제조와 특성)

  • Hamrakulov, B.;Kim, In-Soo
    • Proceedings of the Korean Society for Technology of Plasticity Conference
    • /
    • 2009.05a
    • /
    • pp.432-434
    • /
    • 2009
  • Metal nano-wire arrays on Cu-coated seed layers were fabricated by aqueous solution method using sulfate bath at room temperature. The seed layers were coated on Anodic aluminum oxide (AAO) bottom substrates by electrochemical deposition technique, length and diameter of metal nano-wires were dominated by controlling the deposition parameters, such as deposition potential and time, electrolyte temperature. Anodic aluminum oxide (AAO) was used as a template to prepare highly ordered Ni, Fe, Co and Cu multilayer magnetic nano-wire arrays. This template was fabricated with two-step anodizing method, using dissimilar solutions for Al anodizing. The pore of anodic aluminum oxide templates were perfectly hexagonal arranged pore domains. The ordered Ni, Fe, Co and Cu systems nano-wire arrays were characterized by Field Emission Scanning Electron Microscopy (FE-SEM) and Vibrating Sample Magnetometer (VSM). The ordered Ni, Fe, Co and Cu systems nano-wires had different preferred orientation. In addition, these nano-wires showed different magnetization properties under the electrodepositing conditions.

  • PDF