• Proceedings of the Membrane Society of Korea Conference
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• 1998.04a
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• pp.1-6
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• 1998

To change permselectivity between anions through the anion exchange membrane in electrodialysis, the various modified anion exchange membranes were prepared: highly crosslinked anion exchange membranes, anion exchange membranes having benzyl trialkylammonium groups with different carbon number of alkyl chain as anion exchange groups and anion exchange membranes having pyridinium groups with a hydrophilic or hydrophobic substituent at a different position as anion exchange groups. It became clear from the evaluation of these membranes that the degree of the hydrophilicity of the anion exchange membranes greatly affects the permselectivity between two artions. To increase the hydrophiticity of the anion exchange membranes further, electrodialysis was carried out in the presence of ethylene glycols and the permeation of strongly hydrated anions increased and that of less-hydrated anions decreased. It became clear that the change in the permselectivity between two artions is due to the change in the affinity of anions to the membranes, not the change in mobility ratio of the anions in the membranes phase.

• Journal of Radiation Industry
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• v.6 no.1
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• pp.49-54
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• 2012

Various anion exchange membranes were prepared by radiation graft copolymerization of vinylbenzyl chloride onto fluorinated films and subsequent quaternization with various tertiary amines such as trimethylamine, N,N-dimethylbuthylamine, N,N-dimethylaniline, and N-methylpiperidine. The quaternizations of the anion exchange membranes were confirmed by measuring of the ion exchange capacities of the membranes. The mechanical properties and the water uptakes were also measured. The elongation at break was found to be largely dependent on the fluorinated film, the quateranry ammonium, and the degree of grafting. The results indicate that the poly (ethylene-alt-tetrafluoroethylene) with quaternized trimethylamine moiety exhibits higher flexible property compared to the other prepared anion exchange membranes.

• Journal of the Korean institute of surface engineering
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• v.55 no.6
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• pp.319-327
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• 2022

Ion exchange membranes have been developed from laboratory tools to industrial products with significant technical and trade impacts in the last 70 years. Today, ion exchange membranes are successfully applied for water and energy for different electro-membrane processes. Hydrogen could be produced by electrochemical water splitting using renewable energy, for example, solar, biomass, geothermal and wind energy. This review briefly summarizes the recent studies reporting the state-of-the-art anion-exchange membrane water electrolysis, especially focusing on the enhancement of the durability of anion-exchange membranes. Anion-exchange membrane water electrolysis could be used as inexpensive non-noble metal electrocatalysts that are capable of producing low cost of hydrogen. However, the main challenge of anion-exchange membrane water electrolysis is to increase the performance and durability. In this mini review, the limiting factors of the durability and the technology enhancing the durability will be discussed for anion exchange membrane water electrolysis.

• Membrane Journal
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• v.25 no.6
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• pp.515-523
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• 2015

While commercial polystyrene-based ion exchange membranes have simple manufacturing processes, they also possess poor durability due to their brittleness. Poly(ethylene glycol)methyl ether methacrylate with hydrophilic side chains of poly(ethylene glycol) was used as a co-monomer to make the membranes have improved flexibility. Hydrophilicity/hydrophobicity of the anion exchange membranes were able to be adjusted by varying the chain lengths of the poly(ethylene glycol). For the preparation of the anion exchange membranes, a porous PE substrate was immersed into monomer solutions and thermally polymerized. The prepared membranes were subsequently reacted with trimethylamine to produce anion exchange functional groups, Quaternary ammonium salts. The prepared pore-filled anion exchange membranes were evaluated in terms of ion exchange capacity, electric resistance, elongation at break and water uptake.

• Membrane and Water Treatment
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• v.7 no.1
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• pp.23-38
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• 2016

Batch adsorption of methyl orange (MO) from aqueous solution using three kinds of anion exchange membranes BI, BIII and DF-120B having different ion exchange capacities (IECs) and water uptakes ($W_R$) was investigated at room temperature. The FTIR spectra of anion exchange membranes was analysed before and after the adsorption of MO dye to investigate the intractions between dye molecules and anion exchange membranes. The effect of various parameters such as contact time, initial dye concentration and molarity of NaCl on the adsorption capacity was studied. The adsorption capacity found to be increased with contact time and initial dye concentration but decreased with ionic strength. The adsorption of MO on BI, BIII and DF-120B followed pseudo-first-order kinetics and the nonlinear forms of Freundlich and Langmuir were used to predict the isotherm parameters. This study demonstrates that anion exchange membranes could be used as useful adsorbents for removal of MO dye from wastewater.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.1
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• pp.28-37
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• 2022

In this study, we synthesized a poly(pheneylene oxide) (PPO)-based organic/inorganic composite membrane having silicotungstic acid (STA) for the development of an anion exchange membrane with excellent ionic conductivity and physicochemical stability. The organic/inorganic composite membranes were prepared by introducing different STA contents (0 wt%, 10 wt%, 30 wt%, and 50 wt%) into the quaternizaed(Q)-PPO matrix. The prepared anion exchange membranes were subjected to structural analysis by proton neclear magnetic resonance and Fourier transform infrared, and thermal behavior of membranes was confirmed by thermogravimetric analysis. Among the prepared composite membranes, the ion conductivity of Q-PPO/STA-50 (40.5 mS cm^-1) showed 1.46 times compared to that of the pristine membrane (27.6 mS cm^-1). Therefore, these results demonstrated that organic/inorganic composite membranes are promising candidates for application of anion exchange membranes.

• Membrane and Water Treatment
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• v.3 no.1
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• pp.63-76
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• 2012

Mother liquid discharged from a salt-manufacturing plant was electrodialyzed at 25 and $40^{\circ}C$ in a continuous process integrated with $SO_4{^{2-}}$ ion low-permeable anion-exchange membranes to remove $Na_2SO_4$ and recover NaCl in the mother liquid. Performance of electrodialysis was evaluated by measuring ion concentration in a concentrated solution, permselectivity coefficient of $SO_4{^{2-}}$ ions against $Cl^-$ ions, current efficiency, cell voltage, energy consumption to obtain one ton of NaCl and membrane pair characteristics. The permselectivity coefficient of $SO_4{^{2-}}$ ions against $Cl^-$ ions was low enough particularly at $40^{\circ}C$ and $SO_4{^{2-}}$ transport across anion-exchange membranes was prevented successfully. Applying the overall mass transport equation, $Cl^-$ ion and $SO_4{^{2-}}$ ion transport across anion-exchange membranes is evaluated. $SO_4{^{2-}}$ ion transport number is decreased due to the decrease of electro-migration of $SO_4{^{2-}}$ ions across the anion-exchange membranes. $SO_4{^{2-}}$ ion concentration in desalting cells becomes higher than that in concentration cells and $SO_4{^{2-}}$ ion diffusion is accelerated across the anion-exchange membranes from desalting cells toward concentrating cells.

• Membrane and Water Treatment
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• v.4 no.3
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• pp.203-214
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• 2013

Laboratory tests were performed to determine the efficiency of dye solution desalination by electrodialysis. The study involved anionic dye and mineral salt recovery by obtaining two streams from a salt and dye mixture - dye-rich solution and salt solution. A standard anion-exchange and cation-exchange membranes or monovalent selective anion-exchange membranes were used in the ED stack. It was found that the separation efficiency was strongly dependent on the dye molecular weight. The best results for standard ion-exchange membranes were achieved for the desalination of Direct Black solution. Furthermore, the obtained results implied that the application of monovalent selective anion-exchange membranes improved the recovery of dye and salt solutions - the dye concentration in the diluate remained constant irrespective of the molecular weight of anionic dyes, whereas the salt recovery remained very high (99.5%).

• Applied Chemistry for Engineering
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• v.21 no.6
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• pp.621-626
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• 2010

Anion exchange membranes can be used for reverse electrodialysis for electric energy generation, and capacitive deionization for water purification, as well as electrodialysis for desalination. In this study, anion exchange membranes of poly((vinylbenzyl) trimethylammonium chloride-2-hydroxyethyl methacrylate)/poly(vinyl alcohol) were prepared through the polymerization of (vinylbenzyl)trimethylammonium chloride and 2-hydroxyethyl methacrylate in aqueous poly(vinyl alcohol) solutions, esterification with glutaric acid, and cross-linking reaction with glutaraldehyde. We investigated electrochemical properties for the anion exchange membranes prepared according to experimental conditions. Ion exchange capacity and electrical resistance for the membranes were changed with a variation in the monomer ratio in polymerization. Water uptake and conductivity for the membranes decreased with an increase in the content of glutaric acid in esterification. The change in the time of crosslinking reaction with the formed film and glutaraldehyde affected electrochemical properties such as water uptake, conductivity, or transport number for the membranes. Chronopotentiometry and limiting current density for the anion exchange membranes prepared were measured.

• Membrane Journal
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• v.28 no.5
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• pp.326-331
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• 2018

Crosslinking of poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) anion exchange membranes, which can be used for capacitive deionization (CDI), was investigated. PPO Anion exchange polymer was prepared through bromination and amination reaction steps and crosslinked with bisphenol A diglycidylether (BADGE), m-phenylenediamine (m-PDA), and hexamethylenediamine (HMDA). The gelation time by crosslinking was short in the order of HMDA > m-PDA > BADGE. The anion exchange membranes crosslinked at room temperature over a certain amount of crosslinking agent did not dissolve in an aprotic solvent such as 1-methylpyrrolidone (NMP) and the chemical durability of their membranes to organic solvent increased. The ion exchange capacity and water uptake of anion exchange membranes crosslinked with different crosslinker (BADGE) contents were measured and compared. The CDI performance of the crosslinked PPO anion exchange membrane immersed in the HMDA solution was almost the same as that of the non - crosslinked membrane except for the initial stage of the adsorption step.