• Title/Summary/Keyword: barium sulfate

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The Effect of Barium Sulfate on the Structural Transformations in Tricalcium Silicate (3CaO.$SiO_2$의 구조전이에 미치는 $BaSO_4$의 영향)

  • 서일영;최상흘
    • Journal of the Korean Ceramic Society
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    • v.11 no.2
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    • pp.17-21
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    • 1974
  • Miscibility of barium sulfate in tricalcium silicate was investigated by firing 3CaCO3·SiO2 mixture containing barium sulfate at 1530℃. Added amount of barium sulfate to the mixture was zero to 5 mole % with intervals of 1 mole %. Lattice parametres were also calculated. Results were as follow; 1) Dissolution of barium sulfate in tricalcium silicate does not alter the symmetry in room temperature, but influences it's polymorphic transition forms, temperatures and thermal effects; modification triclinic Ⅱ is stabilized in room temperature. 2) Barium sulfate dissolves about up to 2 mole % in tricalcium silicate and more than this amount, tricalcium silicate formation is inhibited. 3) Unit cell volume of tricalcium silicate is slightly decreased with dissolution of barium sulfate, mainly because of contraction in c axis.

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Influence on PET Exam Caused by Density Differences of Barium-sulfate Contrast Media (Barium 조영제의 농도 차이가 PET 검사에 미치는 영향)

  • Choi, Woo-Joon;Shin, Sang-Ki;Nam, Ki-Pyo;Park, Soon-Ki
    • The Korean Journal of Nuclear Medicine Technology
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    • v.12 no.1
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    • pp.27-32
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    • 2008
  • Purpose: The evaluation of SUV (Standardized Uptake Values) for quantitative analysis in PET exam is the most significant. In PET exam, we make attenuation correction images by using $^{68}Ge$, $^{137}Cs$ or CT data. At this time, a distorted attenuation map affects quantitative analysis. After the exam using barium-sulfate and high density of barium contrast make attenuation map distorted. And then it brings bed influences on SUV. The aim of this study is to verify the relationship between high density barium-sulfate and SUV in PET exam. Materials and Methods By using $^{18}F$-FDG, we made barium-sulfate powder, density of 0, 1.5, 3, 5, 10 and 15% respectively and acquired PET and PET/CT images per each density. And we examined SUV variations from PET and PET/CT images according to differences of barium's density. Moreover, we finally calculated SUV causing variations in HU (Hounsfield Units) values to justify whether the differences of barium density bring any changes in PET/CT exam. Results: From PET images acquired from transmission scan with $^{68}Ge$, we got SUV figures from 6.46 to 6.8 in barium density between 0 to 15 percent. On the other hand, In PET images acquired from Tx scan that using CT, SUV was 6.77 to 23.73, derived from the same barium density. And CT HU values range from 29 to 2004. Conclusion: PET images from Tx data using $^{68}Ge$ weren't affected by barium density and had no differences in SUV. But in the PET/CT images using CT Tx data, there's considerable variations in HU and SUV values according to a difference of barium density in HU values. To perform a precise examination, barium sulfate should be removed from a human body before performing a PET exam.

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Optimal Synthesis Conditions of Barium Sulfate (황산바륨의 최적합성조건)

  • 신화우;최광식
    • YAKHAK HOEJI
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    • v.46 no.5
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    • pp.364-368
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    • 2002
  • Optimal synthetic conditions of barium sulfate were investigated from the viewpoint of yield and bulkiness according to a randomized complete block design proposed by Box and Wilson. Barium chloride and Sodium sulfate were utilized as reactants in order to prepare barium sulfate in this study. The optimum Synthesis conditions of barium sulfate obtained from this study are as follows; Reactant temperature; 60~75$^{\circ}C$ (viewpoint of yield) and 60~71$^{\circ}C$ (viewpoint of bulkiness). Concentration of two reactants; 12.7~14.4% (viewpoint of yield) and 5~10.5% (viewpoint of bulkiness). Mole ratio of two reactants, [BaCl$_2$]/[Na$_2$SO$_4$]; 1.62~1.96 (viewpoint of yield) and 2.0 (viewpoint of bulkiness). Reacting time; 13~15 minutes (viewpoint of yield) and 12~14 minutes (viewpoint of bulkiness). Drying temperature of product; 86~10$0^{\circ}C$ (viewpoint of yield) and 6$0^{\circ}C$ (viewpoint of bulkiness).

A Study on Barium Mixed Radiation Shield using 3D Printer (3D 프린터를 이용한 바륨혼합형 차폐체에 대한 연구)

  • Gang, Heon-Hyo;Kim, Dong-Hyun
    • Journal of the Korean Society of Radiology
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    • v.14 no.5
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    • pp.627-634
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    • 2020
  • Instead of lead, we intend to develop shielding materials for morphological implementation by mixing barium sulfate, an eco-friendly substance, and PLA filament, a 3D printer material. The environmental substance, barium sulfate powder and PLA filament, a 3D printer material, were used, and the shielding was made with a 3D printer after being fused into an extruder to mix the powder powder of barium sulfate with PLA. To check the mixing ratio of barium sulfate powder and PLA filament, the mixing input was analyzed, and the absorption dose by thickness according to barium sulfate content was obtained to check the shielding function of the mixed shielding. In the evaluation of the mixture of sulfate barium powder particles and PLA filaments, it was mixed in the most appropriate proportion when the content was 30% in the apparent and electron microscopic observation photographs. In the absorption dose results by thickness according to barium sulfate content, the difference between the content of 0% and the content of each % was greatest at 0.5 cm in thickness and the lowest dose value at 3 cm in thickness when the barium content was 30%. In addition, as the barium content began to increase at 30%, the absorbed dose value increased again. Instead of conventional lead, barium sulfate, an eco-friendly substance, could be mixed with PLA, a filament material, to create morphological shielding. Based on this study, it is expected that the mixing ratio of barium to the mixture is the most appropriate 30%, and will be used as the basis for the implementation of morphological shielding using 3D printers in the diagnosis and treatment section.

Development and Performance Comparison of Silicon Mixed Shielding Material (실리콘 혼합 차폐체의 개발과 성능비교)

  • Hoi-Woun Jeong;Jung-Whan Min
    • Journal of radiological science and technology
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    • v.46 no.3
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    • pp.187-195
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    • 2023
  • A shield was made by mixing materials such as bismuth(Bi) and barium(Ba) with silicon to evaluate its shielding ability. Bismuth was made into a shield by mixing a bismuth oxide(Bi2O3) colloidal solution and a silicon base and applied to a fibrous fabric, and barium was made by mixing lead oxide(PbO) and barium sulfate(BaSO4) with a silicon curing agent and solidifying it to make a shield. The test was conducted according to the lead equivalent test method for X-ray protective products of the Korean Industrial Standard. The experiment was conducted by increasing the shielding body one by one from the test condition of 60 kVp, 200 mA, 0.1sec and 100 kVp, 200 mA, 0.1 sec. At 60 kVp, 2 lead oxide-barium sulfate shields, 2 bismuth oxide 1.5 mm shields, and 5 bismuth oxide 0.3 mm shields showed shielding ability equal to or higher than that of lead 0.5 mm. At 100 kVp, 2 lead oxide-barium sulfate shields and 2 bismuth oxide 1.5 mm shields showed shielding ability equal to or higher than that of lead 0.5 mm. It was confirmed that when using 2 pieces of lead oxide-barium sulfate and 1.5 mm of bismuth oxide, respectively, it has shielding ability equivalent to that of lead. Bismuth oxide and lead oxide-barium sulfate are lightweight and have excellent shielding ability, thus they have excellent properties to be used as an apron for radiation protection or other shielding materials.

Effects of Electroacupuncture on Motility of the Castro-intestinal Tract of Dogs (전침자극이 개의 위장관운동에 미치는 영향)

  • Sung Jai-Ki;Nam Tchi-Chou
    • Journal of Veterinary Clinics
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    • v.5 no.1
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    • pp.9-21
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    • 1988
  • Gastro-intestinal mortility and transit time of barium sulfate after electroacupuncture were investigated in normal dogs and administration of xylatine in dogs. Electroacupuncture was performed with a current of 1.5 volt and 20 Hz at the acupoints of Tsu San Li(right(+) left(-) in dogs for 30 minutes. The results were as follows: 1. After electroacupuncture stimnlation in normal dogs, rates of stomach contractions was not changed, but amplitudes of stomach motility was markadly increased. The electroacupuncture stimulation tasted about 60 minutes after the end of electroacupuncture. 2. The stomach contractions was markedly increased, while the amplitudes of stomach motility was sligltly decreased by the administration of xylazine in dogs. 3. The rates of stomach contractions and amplitudes of motility were markedly increased after administration of xylazine in the electroacupuncture stimulated dogs. 4. Gastric emptying time o barium sulfate after electroacupuncture stimulation in dogs was highly significantly decreased compared with that of normal dogs(p < 0.01). 5. Small bowel transit time of barium sulfate after electroacupuncture stimulation in dogs was highly significantly decreased compared with that of normal dogs (p < 0.01). 6. Gastroduodenal transit time of barium sulfate after administration of xylazine following electroacupuncture stimulation dogs was blighty significantly decreased compared to that of dogs dosed with xylazine (p< 0.01). 7. Small bowel transit time of barium sulfate after administration of xylazine following electroacupuncture stimulation dogs markedly decreased compared to that of dogs dosed with xylazine (p < 0.05).

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Removal of heavy metal by coprecipitation with barium sulfate (황산바륨의 공침현상을 이용한 중금속 이온의 제거)

  • Lim, Heon-Sung;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.19 no.4
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    • pp.280-284
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    • 2006
  • The objective of this study is to investigate the removal of heavy metal by using the coprecipitation of barium sulfate. Several parameters governing the efficiency of the coprecipitation method were evaluated by the pH of sample solution, amount of coprecipitant, and addition of sulfide for the removal of As(V), Cd(II), Cr(III), Cr(VI), Cu(II), Hg(II) and Pb(II) metal ions ($10{\mu}g/ml$ each). The coprecipitation was about 80% - 95% only for lead at low pH but under 10% for other ions. The amount of removal was about 95% - 100% for Cd, Hg, Pb, Cu in the all pH range by the addition of sulfide with barium sulfate but As(V) and Cr(III, VI) ions were not affected by the same conditions.

Effect of $CaSO_4$ and $BaSO_4$ on the Formation of Portland Cement Clinker (Portland Cement Clinker 생성반응에 미치는 $CaSO_4$$BaSO_4$의 영향)

  • 서일영;최상흘
    • Journal of the Korean Ceramic Society
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    • v.11 no.1
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    • pp.29-35
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    • 1974
  • Effect of calcium sulfate and barium sulfate on the formation of portland cement clinker was studied by means of chemical analysis. DTA and X-ray diffraction analysis. In the presence of liquid phase, effect of the additives on the formation of tricalcium silicate was examined according to the reaction, 2CaO.$SiO_3$+CaO$\longrightarrow$3CaO.$SiO_3$, which is the principal reaction in portland cement clinkerization, and optimum conditions in firing clinker concerning amount of additive, firing time and temperature were determined, and its kinetics was referred to. The experimental results are summerized as follow: (1) Appropriate burning temperature range of cement clinker is more limited as the content of calcium sulfate in clinker is increased. Amount of calcium sulfate, firing time and temperature in proper condition of clinkerization is related to each others. Being added suitable quantity of calcium sulfate, firing temperature of clinker can be lowered about $100^{\circ}C$. (2) When 3-5 mole% of calcium sulfate is added, firing time of 15-30 minutes at about $1380^{\circ}C$ is reasonable, and if the content is over7 mole %, firing for 1 hr. or more at $1350^{\circ}C$ is anticipated to be optimum condition. (3) In the reaction of tricalcium silicate formation, the role of barium sulfate as a mineralizer is similar to that of calcium sulfate, but the optimum firing temperature of cement clinker containing barium sulfate tends to be 20-$30^{\circ}C$ higher than that of clinker containing calcium sulfate. (4) When barium sulfate is used as mineralizer, 2-3 mole % of it to tricalcium silicate is recommended and if it is added more than this amount, free CaO is increased rapidly in clinker and alite formation is inhibited.

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Massive barium sulfate aspiration during upper gastrointestinal contrast material study in an elderly patient with dysphagia

  • Yun, Hae Ryong;Kim, Chang-gon;Park, Jihye;Park, Yong eun;lee, Yong-il;Yoo, Byung-Woo;Chung, Kyung Soo;Kim, Young Sam;Song, Joo Han
    • Journal of Yeungnam Medical Science
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    • v.33 no.2
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    • pp.162-165
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    • 2016
  • Barium sulfate is an inert material used as a radiographic contrast medium during upper gastrointestinal contrast studies for evaluation of patients with dysphagia. Oral barium aspiration is an uncommon but well-reported complication of this procedure. While barium aspiration of small amounts may not cause any symptoms, massive barium aspiration can be life-threatening, particularly in elderly patients with multiple comorbidities. In this case report, we describe an elderly patient with multiple comorbidities who presented with thyrotoxicosis and dysphagia, and then died after massive barium aspiration. Despite administration of intensive medical care with ventilator support and therapeutic bronchoalveolar lavage to remove the aspirated barium, the patient died of multiple organ failure 9 days after barium aspiration. Clinicians should pay attention to elderly patients with predisposing factors for aspiration in whom upper gastrointestinal barium contrast studies are indicated, and should consider other diagnostic tools for evaluation of dysphagia in this population.

A Study on the Surface-Modification of Barium Sulfate/TiO$_2$/Dimethicone Composite Powder and its Application in Color Cosmetics (바륨설페이트/티타늄디옥사이드/디메치콘의 복합화 및 메이크업에서의 응용)

  • Kyung-Ho, Choi;Seung-Yong, Ko;Hak-Hee, Kang;Ok-Sub, Lee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.2
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    • pp.197-200
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    • 2004
  • Sensor and optical properties have become critical features in powder foundation. The flaky barium sulfate powder shows good smooth texture, adhesion and natural looking characteristics. However, it has limitations abilities in UV shielding, hiding and blooming effect. Thus we adopt TiO$_2$ that has excellent hiding power and blooming effect as well as UV shielding ability, but TiO$_2$ has still intrinsic problems in dispersion and texture. To overcome this disadvantages, the barium sulfate/TiO$_2$/dimethicone composite powder was prepared. The flaky barium sulfate powder was coated with TiO$_2$ in nanoscale and followed by coated with dimethicone. When this surface-modified powder was applied for make-up cosmetics, especially in powder foundation, the powder gave powder foundation more good characteristics than the original flaky barium sulfate, Ti02 powder, dimethicone in abovementioned optical and sensory properties. To characterize the distinctive features of this surface-modified powder, we measured its characteristics with UV in vitro tester, hiding powder test method, goniophotometer, consumer panel test and so on.