• 한국세라믹학회지
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• 제22권6호
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• pp.9-14
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• 1985

When the barium titanate is Synthesized in Solid-solid reaction the abnormal expansion occurs at about 110$0^{\circ}C$. The mixture was made of corresponding to the theoretical composition of barium titanate. The mixture was fired at various temperature from 90$0^{\circ}C$ to 130$0^{\circ}C$, After that the specimen was tested closely with XDR dilatometer and SEM. The results indicate that 1, The activation energy of barium titanate formation was 42 Kcal/mole. 2, Thermal expansion up to to 90$0^{\circ}C$ was mainly caused by $CO_2$ whereas it was mainly caused by the formation of the secondary phase above 100$0^{\circ}C$. 3. Thermal expansion was not influenced by the forming pressure up to 1000kg/$cm^2$ but it was largely influenced bythe forming pressure above 200kg/$cm^2$.

• 센서학회지
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• 제5권1호
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• pp.9-14
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• 1996

$WO_{3}$가 첨가된 $BaTiO_{3}$를 고상법으로 제작하여 상온에서 $160^{\circ}C$의 온도 범위와 300 kHz - 300 MHz의 주파수 범위에서 회로망분석기를 이용하여 2포트 S-파라메터 방법으로 고주파 저항, 리액턴스 및 임피던스를 측정하여 $130^{\circ}C$ 이하에서 주파수 및 온도센서로서의 가능성을 진단하였다.

• 한국세라믹학회지
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• 제40권1호
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• pp.5-10
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• 2003

Porous barium-strontium titanate ceramics were fabricated by adding corn- or potato-starch (are referred to as starch). The effect of sintering temperature on the microstructure and electrical properties of the porous ceramics was investigated. The room-temperature electrical resistivity of the barium-strontium titanate ceramics decreased with sintering temperature. The porosity and pore size were decreased and the grain size was increased with increasing the sintering temperature. The porosity and grain size of the barium-strontium titanate ceramics with corn-starch sintered at 1300 and 1450$^{\circ}C$ were 28.5, 22.6% and 3.2, 6.2 $\mu\textrm{m}$, respectively. The average pore sizes of the barium-strontium titanate ceramics with corn-starch sintered at 1300, 1400 and 1450$^{\circ}C$ were 0.5, 0.3 and 0.2 $\mu\textrm{m}$, respectively. The decrease in the room-temperature resistivity with increasing sintering temperature is attributed mainly due to the increase of grain size and the decrease of the electrical barrier height of grain boundaries as well as the partial decrease of porosity.

• 한국세라믹학회지
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• 제43권11호
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• pp.710-714
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• 2006

Barium titanate nanoparticles were synthesized under N$_2$ atmosphere by the hydrolysis and condensation of barium hydroxide octahydrate and titanium (IV) isopropoxide. The synthesized particles were aggregates of nanosized primary particles. The primary particles of about 20-50 nm in diameter became building blocks of larger secondary particles, which are in most cases spherical in shape. The size and morphological evolution of secondary particles are strongly related to the precursor concentration. The observations suggest that formation and control of secondary particles is an essential step in the alkoxidehydroxide sol-precipitation process to obtain monodispersed barium titanate nanopowders.

• 한국전기전자재료학회논문지
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• 제37권3호
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• pp.328-331
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• 2024

This research explores the development of [100]-textured barium titanate (BaTiO₃, BT) ceramics using sodium bismuth titanate (Na_0.5Bi_4.5Ti₄O₁₅, NBiT) templates, aimed at leveraging the inherent high dielectric property of BT. However, the attempted texturing was unsuccessful, primarily due to bismuth diffusion from the NBiT templates into the BT matrix below the sintering temperature, at 1,000℃. Systematical exploration about the cause of the failure is involved and alternative approaches are proposed in detail to overcome the challenge. These findings contribute to the understanding of techniques and conditions for textured ceramic fabrication and highlight the need for further research in this area.

• 한국세라믹학회지
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• 제23권4호
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• pp.41-46
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• 1986

When barium titanate was synthesized in solid-solid reaction the abnormal expansion occurred from 90$0^{\circ}C$ to 110$0^{\circ}C$. The equi molecular mixture of $BaCo_3$ and $TiO_2$ was sintered from 90$0^{\circ}C$ to 130$0^{\circ}C$ on the condition of air vacuum and $CO_2$ atomosphere. After that the specimens were tested closely with XDR Dilatometer and SEM The result indicated that: 1, Volume expansion to be synthesized barium titanate in solid-solid reaction was affected by atomosphere sintering. 2. The solid reaction ot fiorm barium titanate in vacuum atomosphere occurred faster than that in air atomosphere. In vacuum atomosphere the maxium volume expansion was about 30% at 90$0^{\circ}C$ for 2hrs, 3. The solid reaction to form barium titanate in 4CO_2$ atomosphere occurred slower than that in air atomosphere. In $CO_2$ atomosphere the maximum volume expansion was 13% at 100$0^{\circ}C$ for 2 hrs. 4. According to the result of x-ray the expanison was caused by the reaction to form $BaTiO_3$ and change $Ba_2TiO_4$ into 4BaTiO_3$.

• E2M - 전기 전자와 첨단 소재
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• 제10권3호
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• pp.255-261
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• 1997

In this study, pore-containing barium titanate ceramics were prepared with different porosities and pore sizes, in order to better understand how porosity and pore size affect electrical breakdown of barium titanate ceramics. A granulated barium titanate powder was mixed with three grades of commercial polymer microspheres up to 11wt%. The electrical breakdown test was performed at two different temperatures of 30.deg. C(below Tc) and 150.deg. C(above Tc) for samples immersed in a silicon oil bath using a 60kV de power supply. Electrical breakdown strength of pore containing barium titanate ceramics with porosity lower than 10% decreased as pore size and porosity increased. However, above the 10% porosity region, electrical breakdown strength decreased as the pore connectivity increased. From the experimental results, an optimum electrical breakdown model is proposed in an attempt to explain the effect of pores.

• 한국세라믹학회지
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• 제46권2호
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• pp.137-145
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• 2009

A remarkable improvement of the productivity in barium titanate by slurry spray pyrolysis process was realized by supplying solid source slurry into the rector. The produced barium titanate powders showed uniform powder properties, and reproducibility with higher tetragonality in the range of 80$\sim$200 nm, case by case. The secondary calcination experiments of the as-prepared powders by spray pyrolysis revealed that the powders as-prepared over 700$^{\circ}C$ showed perfectly different behavior with the lower temperature's ones and the solid state reaction’s case. The result was discussed in terms of the reaction mechanism based on the activation energy analysis.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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• pp.714-718
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• 2003

Usually for the commercial preparation of barium titanate films or ceramics the reaction atmosphere must be preferably in air. However, normally air is not used because it contains carbon dioxide, which can easily react with barium to form the undesired product barium carbonate, leading to unwanted second-phase formation in the (mal stages of the process. In the present work a series of perovskite barium titanate films was prepared by the sol-gel method, using a metal alkoxide solutions in the electrophoretic deposition (EPD). The influence of several process parameters, like sintering temperature of sol preparation before EPD and heat-treatment temperature and non-oxidized atmosphere, on the film properties is described.

• 대한화학회지
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• 제33권1호
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• pp.65-69
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• 1989

방사성 바륨 또는 방사성 란탄 추적자를 함유하고 있는 Ba(NO$_3)_2$ 와 TiO(NO$-3)_2$의 무기혼합용액을 옥살산의 에탄올 용액으로 적정하므로써 바륨티탄닐의 옥살산 염을 합성하였고, 이를 1000$^{\circ}$C에서 하소시켜 BaTiO$_3$를 만들었다. 옥살산염의 분석결과는 BaTiO(C$_2O_4)_2{\cdot}4H_2O$이며, 무기혼합용액중 Ba/Ti의 몰비가 0.950∼1.05 범위 내에서 화학양론적 결합으로 합성됨을 방사성 바륨 추적자의 도움으로 쉽게 확인하였고, Perovskite형의 구조임을 XRD로 확인하였다. 그리고 란탄 첨가제가 침전에 화학적으로 균일하게 혼입됨은 방사성 란탄의 추적자 실험으로 발견하였다. 이와 같은 실험적 사실로부터 침전물의 구성 성분의 결합이 분자준위에서 일어나고 또 티탄산바륨이 단일상의 결정임을 설명하였다.