• 제목/요약/키워드: binary binder

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EDLC용 CMC+PTFE 혼합바인더 전극의 전기적, 기계적 특성 (Electric and Mechanical Properties of CMC+PTFE Binary Binder Electrode for Electric Double Layer Capacitor)

  • 김익준;이선영;문성인
    • 한국전기전자재료학회논문지
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    • 제17권10호
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    • pp.1079-1084
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    • 2004
  • This work describes the effect of electrode binder on the characteristics of electric double layer capacitor. Among carboxymethylcellulose (CMC), Polyvinylpyrrolidone (PVP), Polyvinyl Alcohol (PVA), and Polyvinylidene Fluoride (PVDF), the unit cell using CMC showed good rate capability at current densities between 2.5 mA/$\textrm{cm}^2$~100 mA/$\textrm{cm}^2$. However, CMC as a binder is incongruent, because the electrode bound with CMC is rigid and easy to crack during a press and winding process for fabrication of capacitor. The unit cell capacitor using the electrode bound with binary binder composed of CMC and Polytetrafluoroethylene (PTFE), especially in composition CMC : PTFE =60 : 40 wt.%, has exhibited the better mechanical properties than those of the unit cell with CMC. On the other hand, the mechanical properties of CMC+PTFE electrode, coated on underlayer composed of CMC and carbon black, were much improved.

Freeze-thaw resistance and sorptivity of self-compacting mortar with ternary blends

  • Turk, Kazim;Kina, Ceren
    • Computers and Concrete
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    • 제21권2호
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    • pp.149-156
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    • 2018
  • This paper investigated the influence of binary and ternary blends of mineral admixtures in self-compacted mortar (SCM) on the fresh, mechanical and durability properties. For this purpose, 25 mortar mixtures were prepared having a total binder content of $640kg/cm^3$ and water/binder ratio between 0.41 and 0.50. All the mixtures consisted of Portland cement (PC), fly ash (FA) and silica fume (SF) as binary and ternary blends and air-entrained admixture wasn't used while control mixture contained only PC. The compressive and tensile strength tests were conducted for 28 and 91 days as well as slump-flow and V-funnel time tests whilst freeze-thaw (F-T) resistance and capillary water absorption tests were made for 91-day. Finally, in general, the use of SF with FA as ternary blends improved the tensile strength of mortars at 28- and 91-day while the use of SF15 with FA increased the compressive strength of the mortars compared to binary blends of FA. SCM mixtures with ternary blends had lower the sorptivity values than that of the mortars with binary blends of FA and the control mixture due to the beneficial properties of SF while the use of FA with SF as ternary blends induced the F-T resistance enhancement.

Synthesis of binary Cu-Se and In-Se nanoparticle inks using cherry blossom gum for CuInSe2 thin film solar cell applications

  • Pejjai, Babu;Reddy, Vasudeva Reddy Minnam;Seku, Kondaiah;Cho, Haeyun;Pallavolu, Mohan Reddy;Le, Trang Thi Thuy;Jeong, Dong-seob;Kotte, Tulasi Ramakrishna Reddy;Park, Chinho
    • Korean Journal of Chemical Engineering
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    • 제35권12호
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    • pp.2430-2441
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    • 2018
  • Selenium (Se)-rich binary Cu-Se and In-Se nanoparticles (NPs) were synthesized by a modified heat-up method at low temperature ($110^{\circ}C$) using the gum exudates from a cherry blossom tree. Coating of CISe absorber layer was carried out using Se-rich binary Cu-Se and In-Se NPs ink without the use of any external binder. Our results indicated that the gum used in the synthesis played beneficial roles such as reducing and capping agent. In addition, the gum also served as a natural binder in the coating of CISe absorber layer. The CISe absorber layer was integrated into the solar cell, which showed a power conversion efficiency (PCE) of 0.37%. The possible reasons for low PCE of the present solar cells and the steps needed for further improvement of PCE were discussed. Although the obtained PCE is low, the present strategy opens a new path for the fabrication of eco-friendly CISe NPs solar cell by a relatively chief non-vacuum method.

분말사출성형에서 초임계유체를 이용한 탈지공정 (Debinding Process Using Supercritical Fluids in Metal Powder Injection Molding)

  • 김용호;임종성;이윤우;박종구
    • 한국분말재료학회지
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    • 제10권1호
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    • pp.6-14
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    • 2003
  • The purpose of the present study is to investigate the method decreasing debinding time as well as lowering operation condition than pure supercritical $CO_2$ debinding by using cosolvent or binary mixture of propane + $CO_2$. First method is to add cosolvent, such as n-hexane, DCM, methanol, 1-butanol, in supercritical $CO_2$. In case of adding cosolvent, we were found the addition of non-polar cosolvent (n-hexane) improves dramatically the binder removal rate (more than 2 times) compared with pure supercritical $CO_2$ debinding, second method is to use mixture of supercritical propane + $CO_2$, as solvent. In case of using mixture of supercritical propane + $CO_2$, the rate of debinding speeded up with increasing of pressure and concentration of propane at 348.15 K. It was found that addition of cosolvent (e.g., n-hexane, DCM) and binary mixture propane + $CO_2$ for supercritical solvent remarkably improved binder removal rate for the paraffin wax-based binder system, in comparison with using pure supercritical $CO_2$.

고기능성 세라믹 주형 및 중자 제작을 위한 3원계 무기 바인더 시스템 개발 (Development of Ternary Inorganic Binder System for Manufacturing High-Functional Ceramic Molds and Core)

  • 박혜영;조근호;최현희;김봉구;김은희;양승철;정연길
    • 한국재료학회지
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    • 제32권12호
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    • pp.538-544
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    • 2022
  • In existing ceramic mold manufacturing processes, inorganic binder systems (Si-Na, two-component system) are applied to ensure the effective firing strength of the ceramic mold and core. These inorganic binder systems makes it possible to manufacture a ceramic mold and core with high dimensional stability and effective strength. However, as in general sand casting processes, when molten metal is injected at room temperature, there is a limit to the production of thin or complex castings due to reduced fluidity caused by the rapid cooling of the molten metal. In addition, because sodium silicate generated through the vitrification reaction of the inorganic binder is converted into a liquid phase at a temperature of 1,000 ℃. or higher, it is somewhat difficult to manufacture parts through high-temperature casting. Therefore, in this study, a high-strength ceramic mold and core test piece with effective strength at high temperature was produced by applying a Si-Na-Ti three-component inorganic binder. The starting particles were coated with binary and ternary inorganic binders and mixed with an organic binder to prepare a molded body, and then heat-treated at 1,000/1,350/1,500 ℃ to prepare a fired body. In the sample where the two-component inorganic binder was applied, the glass was liquefied at a temperature of 1,000 ℃ or higher, and the strength decreased. However, the firing strength of the ceramic mold sample containing the three-component inorganic binder was improved, and it was confirmed that it was possible to manufacture a ceramic mold and core via high temperature casting.

Low-Temperature Chemical Sintered TiO2 Photoanodes Based on a Binary Liquid Mixture for Flexible Dye-Sensitized Solar Cells

  • Md. Mahbubur, Rahman;Hyeong Cheol, Kang;Kicheon, Yoo;Jae-Joon, Lee
    • Journal of Electrochemical Science and Technology
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    • 제13권4호
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    • pp.453-461
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    • 2022
  • A chemically sintered and binder-free paste of TiO2 nanoparticles (NPs) was prepared using a binary-liquid mixture of 1-octanol and CCl4. The 1:1 (v/v) complex of CCl4 and 1-octanol easily interacted chemically with the TiO2 NPs and induced the formation of a highly viscous paste. The as-prepared binary-liquid paste (PBL)-based TiO2 film exhibited the complete removal of the binary-liquid and residuals with the subsequent low-temperature sintering (~150℃) and UV-O3 treatment. This facilitated the fabrication of TiO2 photoanodes for flexible dye-sensitized solar cells (f-DSSCs). For comparison purposes, pure 1-octanol-based TiO2 paste (PO) with moderate viscosity was prepared. The PBL-based TiO2 film exhibited strong adhesion and high mechanical stability with the conducting oxide coated glass and plastic substrates compared to the PO-based film. The corresponding low-temperature sintered PBL-based f-DSSC showed a power conversion efficiency (PCE) of 3.5%, while it was 2.0% for PO-based f-DSSC. The PBL-based low- and high-temperature (500℃) sintered glass-based rigid DSSCs exhibited the PCE of 6.0 and 6.3%, respectively, while this value was 7.1% for a 500℃ sintered rigid DSSC based on a commercial (or conventional) paste.

CMC+PTFE 혼합바인더 전극의 제조 및 전기화학적 특성 (Fabrication of CMC+PTFE Electrode and it's Electrochemical Performances)

  • 김익준;이선영;문성인
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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    • pp.1248-1253
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    • 2004
  • This work describes the effect of electrode binder on the characteristics of electric double layer capacitor Among carboxymethylcellulose (CMC), Polyvinylpyrrolidone (PVP), Polyvinyl Alcohol (PVA), and Polyvinylidene Fluoride (PVDF), the unit cell using CMC showed good rate capability between $2.5mA/cm^2{\sim}100mA/cm^2$ current density. However, CMC as a binder is incongruent, because the electrode bound with CMC is rigid and easy to crack during a press and winding process for fabrication of capacitor. The unit cell capacitor using the electrode bound with binary binder composed of CMC and Polytetrafluoroethylene (PTFE), especially in composition CMC : PTFE : 60 : 40 wt.%, has exhibited the better mechanical properties than those of the unit cell with CMC. On the other hand, it was also noted that the mechanical properties of CMC+PTFE electrode, coated on underlayer composed of CMC and carbon black, were much improved the binding force.

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신경망 이론을 이용한 100MPa급 초고강도 콘크리트의 최적 배합설계모델에 관한 연구 (A Study on the Optimum Mix Design Model of 100MPa Class Ultra High Strength Concrete using Neural Network)

  • 김영수;신상엽;정의창
    • 대한건축학회연합논문집
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    • 제20권6호
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    • pp.17-23
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    • 2018
  • The purpose of this study is to suggest 100MPa class ultra high strength concrete mix design model applying neural network theory, in order to minimize an effort wasted by trials and errors method until now. Mix design model was applied to each of the 70 data using binary binder, ternary binder and quaternary binder. Then being repeatedly applied to back-propagation algorithm in neural network model, optimized connection weight was gained. The completed mix design model was proved, by analyzing and comparing to value predicted from mix design model and value measured from actual compressive strength test. According to the results of this study, more accurate value could be gained through the mix design model, if error rate decreases with the test condition and environment. Also if content of water and binder, slump flow, and air content of concrete apply to mix design model, more accurate and resonable mix design could be gained.

Mechanical properties of SFRHSC with metakaolin and ground pumice: Experimental and predictive study

  • Saridemir, Mustafa;Severcan, Metin Hakan;Celikten, Serhat
    • Steel and Composite Structures
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    • 제23권5호
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    • pp.543-555
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    • 2017
  • The mechanical properties of steel fiber reinforced high strength concrete (SFRHSC) made with binary and ternary blends of metakaolin (MK) and ground pumice (GP) are investigated in this study. The investigated properties are ultrasonic pulse velocity ($U_{pv}$), compressive strength ($f_c$), flexural strength ($f_f$) and splitting tensile strength ($f_{st}$) of SFRHSC. A total of 16 steel fiber reinforced concrete mixtures were produced by a total binder content of $500kg/m^3$ for determining the effects of MK and GP on the mechanical properties. The design $f_c$ was acquired from 70 to 100 MPa by using a low water-binder ratio of 0.2. The test results exhibit that high strength concrete can be obtained by replacing the cement with MK and GP. Besides, correlations between these results are executed for comprehending the relationship between mechanical properties of SFRHSC and the strong correlations are observed between these properties. Moreover, two models in the gene expression programming (GEP) for predicting the $f_c$ of SFRHSC made with binary and ternary blends of MK and GP have been developed. The results obtained from these models are compared with the experimental results. These comparisons proved that the results of equations obtained from these models seem to agree with the experimental results.

A Set-theoretic Account of English Crossover Effects

  • Lee, Gunsoo
    • 한국영어학회지:영어학
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    • 제1권1호
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    • pp.101-117
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    • 2001
  • In English, whether or not wh-movement creates weak crossover effects depends upon the type of wh-phrases that cross over. A bare interrogative like who shows a typical weak crossover effect whereas which N type (e.g. which girl) and partitive type (e.g. which of these girls) wh-phrases would show mere weaker and weakest crossover effects, respectively. Previous approaches to English crossover phenomena that resort to a binary notion of specificity or D-linking cannot account for the three-way contrast the three different types of wh-phrases show. To overcome this problem, I argue in this paper that specificity should be a non-binary set-theoretic notion and propose the following subset principle and optimal binding relation: Between two lexical nominal expressions A and B, A is regarded as more specific than B iff the denotation of A comes from a more narrowly defined non-singleton set than B. Between two lexical nominal expressions A and B, if A locally binds B, then the non-singleton set from which the denotation of A comes should be a subset of the set from which the denotation of B comes (i.e. B cannot be more specific than A). The smaller the subset (i.e. the wider the specificity gap between binder and binder), the more optimal the local binding relation is. A locally binds B iff A is coindexed with B, and A c-commands B, and there is no such C that does not bind A but binds B. Finally, I show that partitivity functions to carve out a smaller subset and thus make partitive wh-phrases more specific than simple which N type wh-phrases.

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