• Title/Summary/Keyword: bipolar electrodes

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Paper-Based Bipolar Electrochemistry

  • Renault, Christophe;Scida, Karen;Knust, Kyle N.;Fosdick, Stephen E.;Crooks, Richard M.
    • Journal of Electrochemical Science and Technology
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    • v.4 no.4
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    • pp.146-152
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    • 2013
  • We demonstrate that carbon electrodes screen-printed directly on cellulose paper can be employed to perform bipolar electrochemistry. In addition, an array of 18 screen-printed bipolar electrodes (BPEs) can be simultaneously controlled using a single pair of driving electrodes. The electrochemical state of the BPEs is read-out using electrogenerated chemiluminescence. These results are important because they demonstrate the feasibility of coupling bipolar electrochemistry to microfluidic paperbased analytical devices (${\mu}PADs$) to perform highly multiplexed, low-cost measurements.

The Behavior of Pellet Packed-bed Electrodes Reactor -Graphite Pellet Electrode- (펠레트 충전층 전극 반응기의 특성 -흑연 펠레트 전극-)

  • Kim, Hark-Joon
    • Applied Chemistry for Engineering
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    • v.3 no.4
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    • pp.657-662
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    • 1992
  • For describing the bipolar packed-bed electrode cell filled with graphite pellete electrode, the application of the model of equivalent circuit was studied. The ratio between the Faradaic current through bipolar electrodes and the applied current was dependent on the resistance coefficient, specific conductivity of electrolyte, and electrolyte circulation rate. The ratio of the Faradaic current through bipolar electrodes to the applied current increased with the applied current(or cell voltage), but decreased with the increase of electrolytic conductivity and circulation rate of the electrolyte.

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Research on Remediation of Trichloroethylene using Zero Valent Iron Bipolar Packed Bed Electrodes (영가철 충진 복극전해조를 이용한 TCE 정화기법에 관한 연구)

  • Park, Yu-Ri;Shin, Ja-Won;Park, Joo-Yang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.1B
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    • pp.85-91
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    • 2012
  • Permeable Reactive Barriers (PRBs) using zero valent iron (ZVI, $Fe^0$) is a promising technology for in-situ remediation of trichloroethylene (TCE) forming dense non aqueous phase liquid (DNAPL). The objective of this study is to develop an enhanced treatment method of trichloroethylene-contaminated groundwater using ZVI packed bed with direct current (D.C.). A column experiment was performed to investigate degradation efficiency of TCE that was performed in three different combination of control (only sand), ZVI column (ZVI:sand, packing ratio 1:2(v/v)) and bipolar column (ZVI:sand=1:2(v/v) with electric current) in the test columns. As the results of this study, the degradation efficiency of TCE was improved with simultaneous application of both bipolar column compared to that used ZVI column. Because ZVI particles are isolated and individual particles act like small electrodes. In this experiment, it was indicated a basic material for application of bipolar packed bed as electro-PRBs that was effective degradation of TCE.

Removal of COD and T-N caused by ETA from Nuclear Power Plant Wastewater using 3D Packed Bed Bipolar Electrode System (3D 복극충진전기분해를 이용한 원전 ETA에 의해 유발된 폐수 내 COD 및 T-N 제거)

  • Kim, Han-Ki;Jeong, Joo-Young;Shin, Ja-Won;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.3
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    • pp.409-421
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    • 2012
  • Ethanolamine (ETA) is mainly used to prevent corrosion of pipe in secondary cooling system of nuclear power plant. Condensed ETA in wastewater could increase COD and T-N when it was emitted to natural water system. Compared to conventional treatments, electrochemical oxidation process using packed bed bipolar electrodes was adopted to treat COD and T-N. According to arrangement of feeder electrode, single packed bed bipolar electrode reactor and multi-paired packed bed bipolar reactor were developed and conventional zero-valent iron (ZVI) was selected as conducting bipolar electrode. Bipolar electrodes were coordinated three-dimensionally in the reactor. The experimental results showed that COD and T-N was little removed in unit system at different pH condition (pH 8 and 11) on 100V. However, in multi-paired system that applied 600V, COD was eliminated 80.85% (anode-cathode-anode, A-C-A) and 85.11% (cathode-anode-cathode, C-A-C), respectively. T-N was also removed 96.88% (A-C-A) and 90.63% (C-A-C), simultaneously. Current efficiency was estimated both single and multi-paired system. At unit bipolar packed bed reactor, current efficiency was almost zero, however in multi-paired system, current efficiency was 300~500% at A-C-A and 250~350% at C-A-C. Current efficiency was over 100% hence it was confirmed that this system is more effective than conventional electrochemical oxidation system.

Implementation of Wearable Heart Activity Monitoring System having Modified Bipolar Electrode and Correlation Analysis with Clinical Electrocardiograph(ECG) (수정된 바이폴라 전극을 갖는 착용형 심장활동 모니터링 시스템 구현 및 임상 심전도와의 상관관계 분석)

  • Lee, Kang-Hwi;Lee, Jeong-Whan;Lee, Young-Jae;Kim, Kyeong-Seop;Yang, Heui-Koung;Shin, Kun-Su;Lee, Myoung-Ho
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.6
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    • pp.1102-1108
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    • 2008
  • Wearable physiological signal monitoring systems are regarded as an important sensing unit platforms in ubiquitous/mobile healthcare application. In this paper, we suggested the modified bipolar electrodes implemented on the portable heart activity monitoring system, which minimized the distance of electrodes formed on a attachable pad. The proposed electrode configuration is useful in mobile measurement environments, but has a disadvantage of reduced amplitude of the heart action potential. In order to overcome the shortcoming of the suggested electrode configuration, we implemented the amplifying circuit to increase the signal-gain and decrease the artifacts. For evaluations, we analyzed the specificity of measured cardiography using the proposed electrodes through the comparing of heart activity monitoring system with standard clinical ECG(lead2) by pearson correlation coefficients. The result showed that the average correlation coefficient is $0.903{\pm}0.036,\;0.873{\pm}0.072$ at V3, V4 chest lead position, respectively. Thus, the modified bipolar electrode is quite suitable to monitor the electrical activity of the heart in the situation of the mobile environment, and could be considered having high similarity with standard clinical ECG.

Influences of Inter-electrode Distance on Electrogastrography Measurements (위전도 측정을 위한 전극간 부착거리에 관한 연구)

  • Han, Wan-Taek;Song, In-Ho;Kim, In-Young
    • Journal of Biomedical Engineering Research
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    • v.30 no.4
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    • pp.341-346
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    • 2009
  • Cutaneous electrogastrography is the measurement of electrical activity of the stomach on the abdominal surface. The validity of cutaneous electrogastrography is dependent upon the quality of the recording technique. The locations of electrodes are an important issue. We examined the influences of the inter-electrode distance of bipolar leads on electrogastrography measurements. The sensitivity distributions of EGG leads were calculated based on a 2D body fat model and evaluated according to the region of interest sensitivity ratio (ROISR). We simulated the ROISR of the inter-electrode distance in relation to various body fat thicknesses. The distance between the electrodes was proportional to the distance between the ROI and the surface of the abdomen. The results imply that inter-electrode distance can be applied in electrogastrography according to human body fat thickness.

Resistance Switching Characteristics of Metal/TaOx/Pt with Oxidation degree of metal electrodes

  • Na, Hee-Do;Kim, Jong-Gi;Sohn, Hyun-Chul
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.187-187
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    • 2010
  • In this study, we investigated the effect of electrodes on resistance switching of TaOx film. Pt, Ni, TiN, Ti and Al metal electrodes having the different oxidation degree were deposited on TaOx/Pt stack. Unipolar resistance switching behavior in Pt or Ni/TaOx/Pt MIM stacks was investigated, but bipolar resistance switching behavior in TiN, Ti or Al /TaOx/Pt MIM stacks was shown. We investigated that the voltage dependence of capacitance was decreased with higher oxidation degree of metal electrodes. Through the C-V results, we expected that linearity ($\alpha$) and quadratic ($\beta$) coefficient was reduced with an increase of interface layer between top electrode and Tantalum oxide. Transmission Electron Microscope (TEM) images depicted the thickness of interface layer formed with different oxidation degree of top electrode. Unipolar resistance switching behavior shown in lower oxidation degree of top electrode was expected to be generated by the formation of the conducting path in TaOx film. But redox reaction in interface between top electrode and Tantalum oxide may play an important role on bipolar resistance switching behavior exhibited in higher oxidation degree of top electrode. We expected that the resistance switching characteristics were determined by oxidation degree of metal electrodes.

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HVOF Thermal Sprayed AISI316-WC Coating Layer on Stainless Steel for PEMFC Bipolar Plate (고분자 전해질 연료전지용 분리판으로서 스테인리스강에 HVOF 용사된 AISI316-WC 코팅층)

  • Nam, Dae-Geun
    • New & Renewable Energy
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    • v.4 no.1
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    • pp.31-36
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    • 2008
  • Stainless steels have been widely considered as metallic bipolar plates, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the bipolar plates and the electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

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Positive Peaked Electrically Compound Action Potentials in Cochlear Implant Recipients (인공와우 이식자에서 Positive Peaked 청신경 복합활동전위)

  • Heo, Seung-Deok
    • Phonetics and Speech Sciences
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    • v.1 no.2
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    • pp.25-30
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    • 2009
  • Animal experiments have shown that the positive peaked electrically compound action potentials (ECAPs) can be recorded in round window, intracochlear, and nerve trunk by stimulating a monopolar pulse. However, positive peaked ECAPs of cochlear implant recipients have never been reported because ECAPs are recorded from intracochlear electrodes after bipolar stimulation. In our experiment, the positive peaked ECAPs were recorded from 18 intracochlear electrodes in cochlear implant recipients with multiple cochlear anomalies. Thresholds in each channel were measured and the latency of P-, N-wave, and amplitude of P-N were analyzed. These results were identical with the electrically auditory brainstem response (EABR) on the input-output characteristics. In conclusion, the positive peaked ECAPs from the cochlear implant recipients are antidromic ECAPs recorded by perimodiolar electrodes stimulating cochlear implants with multiple anomalies. Therefore, positive peaked ECAPs can be used as useful audiological tools to evaluate the eighth nerve ending.

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Development of urinary incontinence therapy system using silicone electrodes (실리콘 전극을 이용한 요실금치료기의 개발)

  • Lee, Jong-Kuk;Khang, Hyun-Soo;Kwon, Sung-Ho;Lee, Soo-Yeol
    • Proceedings of the KOSOMBE Conference
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    • v.1998 no.11
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    • pp.139-140
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    • 1998
  • Urinary incontinence therapy system has been developed using electric stimulation and biofeedback techniques. In the electric stimulation, bipolar current pulses with the frequency of 10-50Hz were applied to vagina muscle. To alleviate possible skin burning caused by locally focussed current silicone electrodes rather than conventional steel electrodes have been developed.

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