• Title/Summary/Keyword: blend

Search Result 1,430, Processing Time 0.031 seconds

Preparation and Characterizations of Polymethylmethacrylate (PMMA)/Acrylate Rubber (ACM) Blend for Light Diffuser Applications

  • Lee, Byung Hwan;Chang, Young-Wook;Lim, Hyung Mi
    • Elastomers and Composites
    • /
    • v.50 no.1
    • /
    • pp.49-54
    • /
    • 2015
  • Dynamically vulcanized PMMA/ACM (80 wt%/20 wt%) blend using DCP as a curing agent was prepared using internal mixer. The morphology, mechanical properties, optical properties, melt viscosity and die swell were characterized by using FE-SEM, tensile test, Izod impact test, dynamic mechanical analysis, ARES and capillary rheometer, respectively. The blends show a phase-separated morphology in which ACM are dispersed in PMMA matrix. Dynamically vulcanized blend exhibits higher mechanical properties, higher melt viscosity, and die swell as compared to simple blend. And, the dynamically vulcanized blend showed total transmittance of more than 75% and haze of higher than 90%, which enable it to find potential applications to fabricate an optical diffuser by extrusion process.

A Study on the Performance of Small Diesel Engine Using Blend Fuel Oil ( 3 ) - Rape Seed Oil 20 % and Diesel Oil 80 % - (혼합 연료를 사용한 소형 디이젤 기관의 성능에 관한 연구 ( 3 ) - 유연기름 20 % 와 디이젤유 80 % -)

  • 고장권
    • Journal of the Korean Society of Fisheries and Ocean Technology
    • /
    • v.20 no.2
    • /
    • pp.127-132
    • /
    • 1984
  • Performance tests of small diesel engine were carried out, using the blend fuel oil as the substitute fuel oil and the following results were obtained. (1) The character at the blend oil as substitute fuel for small diesel engine was examined. (2) In the case of operating small diesel engine with blend oil, the exhaust gas volume increases at 8% in comparison with diesel oil. (3) In the case of operating small diesel engine with blend oil, the fuel consumption Increases at 3% in comparison with diesel oil. (4) In the brake thermal efficiency, blend oil is similar to diesel oil.

  • PDF

A Study on the Preparation and Flame Retardancy of Compatibilized Blend/Layered Silicate Nanocomposites with Inorganic Flame Retardant (무기계난연제 첨가형 상용화블렌드/층상실리케이트 나노복합재료의 제조 및 난연특성에 관한 연구)

  • Kang, Young-Goo;Song, Jong-Hyeok
    • Journal of the Korean Society of Safety
    • /
    • v.21 no.1 s.73
    • /
    • pp.79-85
    • /
    • 2006
  • Olefinic compatibilized blend(R-PP/R-PE)/layered silicate composites have been prepared by melt intercalation technique directed from $Na^{+}$ montmorillonite(MMT) or organophilic montmorillonites while using magnesium hydroxide as flame retardant. Morphology and flammability properties were characterized by X-ray diffraction(XRD), transmission electron microscopy(TEM), scanning electron microscopy(SEM), thermogravimetry analysis(TGA), limiting oxygen index(LOI), UL94 test. It is found that the compatibilized blend/layered silicate(Cloisite 20A) nanocomposites have a mixed immiscible-intercalated structure and there is better intercalation when a compatibilizer is combined with the polymer and layered silicate to be melt blended. A very large increase in the LOI value was observed with hybrid filler addition and further enhancement in thermal stability and compatibility of blend was obtained for the compatibilized blend containing small amount of layered silicate.

Structure -Properties Relations of Polypropylene/ Liquid Crystalline Polymer Blends

  • Sahoo, N.G.;Das, C.K.;Jeong, Hye-Won;Ha, Chang-Sik
    • Macromolecular Research
    • /
    • v.11 no.4
    • /
    • pp.224-230
    • /
    • 2003
  • The blends of polypropylene (PP) with glass filled thermotropic liquid crystalline polymer (LCP-g) have been prepared by melt mixing techniques at different blend ratios. The thermal, dynamic mechanical, crystalline and morphological characteristics of these blends were investigated. Higher percent crystallinity was observed for 10% level of LCP-g in the blend in comparison to that of other blend ratios. The thermal stability increased with LCP-g concentration in the blend with PP. The variation of storage modulus, stiffness and loss modulus as a function of blend ratios suggested the phase inversion at the 50% level of LCP-g in the blend. The scanning electron microscopy (SEM) photographs showed the creation of voids and destruction of the fiber structures during the dynamic mechanical measurements. Processing behavior of the blends depended on the fiber forming characteristics of LCP-g, which again varied with the molding temperatures.

Modeling of Blend Surfaces by Bezier Surface Patches (비지어곡면에 의한 블렌드곡면의 모델링)

  • 주상윤
    • Korean Journal of Computational Design and Engineering
    • /
    • v.2 no.2
    • /
    • pp.122-129
    • /
    • 1997
  • Ball rolling blending is a popular technique for blending between parametric surfaces. The ball rolling blend surface is conceptually a trajectory of a ball rolling between two base sufaces. It is constructed by sweeping a circular arc along a ball contact curve pair. Since a ball rolling blend surfaces does not have a polynomial form like a Bezier surface patch, it is impossible to apply this method directly to a commercial CAD/CAM system. In this paper an algorithm is developed to approximate a ball rolling blend surface into Bezier surface patches. Least square method is applied to obtain proper Bezier surface patches under a given tolerance. The Bezier surface patches have degree three or more and guarantee VC1-continuity.

  • PDF

Degradation and Preparation of Blend Films Using Natural Polymers Chitosan and Algin (키토산과 알긴을 이용한 블랜드필름의 제조와 분해)

  • 류정욱;이홍열;오세영
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.28 no.2
    • /
    • pp.417-422
    • /
    • 1999
  • Algin and chitosan are known as biodegradable natural polymers. PVA is useful for the production of water soluble packaging, paper, textile sizes. PVA/Algin and PVA/chitosan films were prepared by solution blends method in the weight ratio of chitosan, algin for the purpose of useful biodegradable films. Thermal and mechanical properties of blend films such as DSC, impact strength, tensile strength and morphology by SEM were determined. As a result, The ratio of 10.0wt% PVA/chitosan films were similar to PVA at thermal and mechanical properties. PVA/Algin films were found that phase separation was occured as more than 25wt% increasing the blend ratio of algin. PVA/Algin films were observed to be less partially compatibility than 10wt% increasing the blend ratio of algin by DSC, mechanical properties and SEM. Blend films were completely degraded pH 4.0 better than 7.0, 10.0 in the buffer solution. Also, they were rapidly degraded in the enzyme( glucosidase) solution better than pH solution by enzymolysis.

  • PDF

A Study on Fabrication of Polyester Copolymers (Ⅵ) -Physical Properties of PET/PETG Copolymer Blend by the Drawing Conditions- (폴리에스테르 공중합체의 Fabrication 연구 (Ⅵ) -PET/PETG 공중합체 블렌드의 연신조건에 따른 물리적 특성-)

  • 현은재;이소화;김기영;제갈영순;장상희
    • Polymer(Korea)
    • /
    • v.26 no.3
    • /
    • pp.335-343
    • /
    • 2002
  • Blend resin (PET/PETG 70/30 blend) of poly (ethylene terephthalate) (PET) and poly (ethylene terephthalate glycol) (PETG) of weight percent 70/30 was prepared by a twin-screw extruder. Undrawn films of the blend and pure PETG were made by melt-press in hot press. Drawn films were made by capillary rheometer. Crystallinity, shrinkage, thermal, dynamic mechanical, and mechanical properties of these blends and PETG drawn films were investigated by wide angle X-ray diffractometer, dry oven, DSC thermal analyzer, and tensile tester. The crystallinity and density of these films increased with increasing draw ratio and draw rate but decreased with increasing draw temperature. The crystallinity and density of the blend films were higher than those of PETG films. The tensile strength and tensile modulus of these drawn alms increased with increasing draw ratio and draw rate but decreased with increasing draw temperature. The tensile strength and tensile modulus of blend films were higher than those of PETG films. Shrinkage of PETG md blend films decreased with draw ratio and draw rate. Shrinkage of undrawn blend film was 600% higher than that of pure PET film.

Effect of Relative Levels of Mineral Admixtures on Strength of Concrete with Ternary Cement Blend

  • Mala, Kanchan;Mullick, A.K.;Jain, K.K.;Singh, P.K.
    • International Journal of Concrete Structures and Materials
    • /
    • v.7 no.3
    • /
    • pp.239-249
    • /
    • 2013
  • In the present scenario to fulfill the demands of sustainable construction, concrete made with multi-blended cement system of OPC and different mineral admixtures, is the judicious choice for the construction industry. Silica fume (SF) and fly ash (FA) are the most commonly used mineral admixtures in ternary blend cement systems. Synergy between the contributions of both on the mechanical properties of the concrete is an important factor. This study reports the effect of replacement of OPC by fly ash (20, 30, 40 and 50 % replacement of OPC) and/or silica fume (7 and 10 %) on the mechanical properties of concrete like compressive strength and split tensile strength, with three different w/b ratio of 0.3, 0.4 and 0.45. The results indicate that, as the total replacement level of OPC in concrete using ternary blend of OPC + FA + SF increases, the strength with respect to control mix increases up to certain replacement level and thereafter decreases. If the cement content of control mixes at each w/b ratio is kept constant, then as w/b ratio decreases, higher percentage of OPC can be replaced with FA + SF to get 28 days strength comparable to the control mix. A new method was proposed to find the efficiency factor of SF and FA individually in ternary blend cement system, based on principle of modified Bolomey's equation for predicting compressive strength of concrete using binary blend cement system. Efficiency factor for SF and FA were always higher in ternary blend cement system than their respective binary blend cement system. Split tensile strength of concrete using binary and ternary cement system were higher than OPC for a given compressive strength level.

Effect of Graft Copolymer Composition on the Compatibility of Biodegradable PCL/PCL-g-PEG Blend (PCL/PCL-g-PEG 생분해성 블렌드에서 그래프트 공중합체의 조성에 따른 상용성의 영향)

  • Cho, Kuk-Young;Lee, Ki-Seok;Park, Jung-Ki
    • Polymer(Korea)
    • /
    • v.33 no.3
    • /
    • pp.248-253
    • /
    • 2009
  • Blend films based on the poly($\varepsilon$-caprolactone) (PCL) and amphiphilic biodegradable polymer, poly(ethylene glycol) grafted poly($\varepsilon$-caprolactone) (PCL-g- PEG), were prepared with different blend ratios in order to develop new biomedical material. PCL was the main component in the blend. The miscibility and characteristics of the blends were investigated. The crystallization temperature of the blend shifted to high temperatures with an increase of the graft copolymer contents when the homopolymer PCL was the main component of the blend. The PEG side chain in the blend affected the crystallization rate of the PCL crystals in the blend and alternating extinction bands were observed by optical microscopy. The protein adhesion behavior of the film was influenced by the water uptake of the film.

Comparison study of the effect of blending method on PVDF/PPTA blend membrane structure and performance

  • Li, Hongbin;Shi, Wenying;Zhang, Yufeng;Zhou, Rong
    • Membrane and Water Treatment
    • /
    • v.6 no.3
    • /
    • pp.205-224
    • /
    • 2015
  • A novel hydrophilic poly (vinylidene fluoride)/poly (p-phenylene terephthalamide) (PVDF/PPTA) blend membrane was prepared by in situ polycondensation of p-phenylene diamine (PPD) and terephthaloyl chloride (TPC) in PVDF solution with subsequent nonsolvent induced phase separation (NIPS) process. For comparison, conventional solution blend membrane was prepared directly by adding PVDF powder into PPTA polycondensation solution. Blend membranes were characterized by means of viscometry, X-ray photoelectron spectroscopy (XPS), Field Emission Scanning Electron Microscopy (FESEM). The effects of different blending methods on membrane performance including water contact angle (WCA), mechanical strength, anti-fouling and anti-compression properties were investigated and compared. Stronger interactions between PVDF and PPTA in in situ blend membranes were verified by viscosity and XPS analysis. The incorporation of PPTA accelerated the demixing rate and caused the formation of a more porous structure in blend membranes. In situ blend membranes exhibited better hydrophilicity and higher tensile strength. The optimal values of WCA and tensile strength were $65^{\circ}$ and 34.1 MPa, which were reduced by 26.1% and increased by 26.3% compared with pure PVDF membrane. Additionally, antifouling properties of in situ blend membranes were greatly improved than pure PVDF membrane with an increasing of flux recovery ratio by 25%. Excellent anti-compression properties were obtained in in situ blend membranes with a stable pore morphology. The correlations among membrane formation mechanism, structure and performance were also discussed.