• Proceedings of the Korean Institute of Industrial Safety Conference
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• 1998.11a
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• pp.329-334
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• 1998

난연성을 지닌 고분자 물질중 Chlorosulfonated Polyethylene(CSPE; Hypalon)은 Polyethylene에 염소와 황을 첨가한 것으로 염소를 첨가함으로써 기름과 화염에 대한 저항성을 향상시키고, 황 또한 기름, 화염에 대한 저항을 향상시킬 뿐 아니라 인장강도를 크게 해서 기계적 강도를 향상시킨 것이다. CSPE는 염소량의 등급에 따라 Coating재료, 호스 구조재, Wire와 Cable의 피복재료등 여러 가지 용도로 많이 쓰이고 있으며 특히 염소함량이 35%인 CSPE(Hypalon-40)의 경우 열저항과 압출 특성이 우수하기 때문에 Cable의 피복재료로 많이 쓰이고 있다.

• Elastomers and Composites
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• v.27 no.4
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• pp.255-261
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• 1992

Chlorosulfonated polyethylene(CSM) was moisture-cure after treating them with silane coupling agents such as ${\gamma}-mercapto$ propyl trimethoxy silane, ${\gamma}-glycidoxy$ propyl triethoxy silane and methyl triethoxy silane, 3-(trimethoxy silyl) propyl methacrylate and 3-thiocyanopropyl triethoxy silane. The cure reaction is composed two steps. The first is the reaction between chlorosulfonyl groups of CSM and silane coupling agents. The second is the formation of cross-links which are siloxane linkage. The linkage is formed by the condensation of silanol groups which are produced by the hydrolysis of alkoxysilyl groups. CSM was mixed with MPS etc., and dilaurate dilaurate as catalyst on two open mill and the compounds were lured in hot water at $70^{\circ}C$ Physical properties of moisture-cured CSM was measured. CSM was effectively moisture-cured and r-mercapto propyl trimethoxy silane and r-glycidoxy propyl trimethoxy silane were capable of the vulcanizing agents.

• Elastomers and Composites
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• v.10 no.1
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• pp.33-55
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• 1975

• Elastomers and Composites
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• v.36 no.4
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• pp.246-254
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• 2001

In this work, the stabilization of chlorosulfonated polyethylene (CSM) rubber emulsion with surfactants, i.e., nonionic (Span 60) or anionic (Sodium laurylsulfate, SLS) surfactants, was investigated. The phase inversion emulsification by interfacial chemical characteristics was used to emulsify the CSM rubber. As a result, the emulsion phase separation was observed in the case of any single surfactant. However, there was no phase separation in the mixture of Span 60 and SLS in the context of emulsion droplet size tests and rheological behaviors. The droplet size decreases by increasing the surfactant mixture, resulting in increasing the viscosity. The viscosity and shear stress determined from shear rate show a shear thinning and yield behaviors. It was then found that the emulsion stabilization can be improved using the phase inversion emulsification method and surfactant mixture.

• Applied Chemistry for Engineering
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• v.5 no.2
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• pp.215-222
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• 1994

As a toughness modifier for plastics chlorosulfonated polyethylene(CSM) can be used. CSM has a good resistance to oxygen and ozone. CSM has a crosslinkable functional group(sulfonyl chorid) with sulfur and metal oxide. Polyvinylchloride(PVC) is widely used industrial plastics because of its balanced properties and low cost. But it has some disadvantages such as low impact strength, light, ozone and oxygen degradation. In order to improve these properties of PVC, CSM was blended with PVC. The toughening effect appeared at about 10wt% and there is no additional effect above 30wt% of CSM. The weatherability, ozone resistance and mechanical properties of PVC were improved by blending with CSM. The toughening mechanism is studied by SEM.

• Elastomers and Composites
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• v.40 no.1
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• pp.12-21
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• 2005

In this work, magnesium carbonate and calcium hydroxide as metallic crosslinking agent were added to chlorosulfonated polyethylene rubber (CSM) emulsion to enhance the mechanical properties of emulsion film such as tensile strength, elongation at break, and tear strength and crosslinking density, thermal features, and surface energy were also investigated. Crosslinking density of the CSM emulsion film with increasing the amount of magnesium carbonate and calcium hydroxide increased, leading to the enhancement of water resistance. It was shown that compared with calcium hydroxide, magnesium carbonate had a little higher crosslinking density and $T_g$ value. The surface energy and mechanical characteristics of the CSM emulsion film, however, showed somewhat different behaviors. The highest surface energy, tensile strength, and tear strength were observed when 0.75% for magnesium carbonate and 1.0% for calcium hydroxide were added respectively. Therefore, it can be concluded that as metallic crosslinking agent to improve water resistance and mechanical properties of the CSM emulsion, magnesium carbonate is more preferable to calcium hydroxide.

• Macromolecular Research
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• v.11 no.6
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• pp.506-510
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• 2003

A Zn ion-coated nanosilica filler has been developed and tested, in chlorosulfonated polyethylene (CSPE) and polychloroprene (CR), as a vulcanizing activator, cum was reinforcing filler. In this study, ZnO was replaced by the Zn ion-coated nanosilica filler with an aim of studying the dual role of this nanofiller in CSPE and CR. In the case of CSPE vulcanizates, the presence of MgO deteriorated the state and rate of cure when the Zn ion-coated nanosilica filler was used, but in the case of CR it improved the state of cure and enhanced the modulus and tensile strength. The Zn ion-coated filler proved to be a better reinforcing-cum-curing agent than was externally added ZnO and NA-22 also proved to be a better curative in the presence of the Zn ion-coated nanosilica filler for both CSPE and CR.

• Journal of Radiation Industry
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• v.5 no.3
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• pp.237-242
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• 2011

In this research, the radiation resistance of ethylene propylene rubber (EPR) and chlorosulfonated polyethylene (CSPE) which can be used as a insulating materials of for electrical cable in the nuclear power plant were investigated. EPR and CSPE were irradiated by ${\gamma}$-ray at various doses ranging from 50 to 500 kGy at room temperature in air. The irradiated EPR and CSPE was investigated in terms of activation energy, mechanical properties, and oxidation stability. The experimental results revealed that CSPE exhibited the higher radiation resistance in comparison to that of EPR.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.66 no.5
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• pp.800-805
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• 2017

The accelerated thermal ageing of CSPE (chlorosulfonated polyethylene) was carried out for 16.82, 50.45, and 84.09 days at $110^{\circ}C$, equivalent to 20, 60, and 100 years of ageing at $50^{\circ}C$ in nuclear power plants, respectively. As the accelerated thermally aged years increase, the insulation resistance and resistivity of the CSPE decrease, and the capacitance, relative permittivity and dissipation factor of those increase at the measured frequency, respectively. As the accelerated thermally aged years and the measured frequency increase, the phase degree of response voltage vs excitation voltage of the CSPE increase but the phase degree of response current vs excitation voltage decrease, respectively. As the accelerated thermally aged years increase, the apparent density, glass transition temperature and the melting temperature of the CSPE increase but the percent elongation and % crystallinity decrease, respectively. The differential temperatures of those are $0.013-0.037^{\circ}C$ and, $0.034-0.061^{\circ}C$ after the AC and DC voltages are applied to CSPE-0y and CSPE-20y, respectively; the differential temperatures of those are $0.011-0.038^{\circ}C$ and $0.002-0.028^{\circ}C$ after the AC and DC voltages are applied to CSPE-60y and CSPE-100y, respectively. The variations in temperature for the AC voltage are higher than those for the DC voltage when an AC voltage is applied to CSPE. It is found that the dielectric loss owing to the dissipation factor($tan{\delta}$) is related to the electric dipole conduction current. It is ascertained that the ionic (electron or hole) leakage current is increased by the partial separation of the branch chain of CSPE polymer as a result of thermal stress due to accelerated thermal ageing.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.32 no.6
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• pp.490-495
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• 2019

This study performs the thermal aging of chlorosulfonated polyethylene (CSPE) for 807.36 and 1,614.48 hours at $110^{\circ}C$, which is equivalent to 40 and 80 years of aging at $50^{\circ}C$ in nuclear power plants, respectively. Flat-type CSPEs were soaked in seawater for five days and then dried for five days at room temperature. Furthermore, the soaked CSPEs were cleaned for 5 days with fresh water and dried for 1,100 days at room temperature. Through this process, the log IV of the CSPEs decreases, whereas the dissipation factor of the CSPEs increases as thermally accelerated aged years increase at the measured frequency. Although the phase degree of the response voltage versus excitation voltage of the CSPEs increases, that of the response current versus excitation voltage decreases with the thermally accelerated aging. The thermal conductivity of the CSPEs increases slightly, but the thermal diffusivity does not vary with the thermally accelerated aged year increase. The displacement of the compressive strength of the CSPEs decreases gradually as the thermally accelerated aged years increase.