• 약학회지
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• 제13권1호
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• pp.1-15
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• 1969

A new method of qualitative and quantitative determination of barbiturates in the pharmaceuticals by means of $\alpha$-picoline-copper (II) was studied. Barbiturates in the pharmaceuticals were dissolved in the mixed solvent of 33% $\alpha$-picoline-Carbontetrachloride to yield Complex Compounds of barbiturates-copper (II)-$\alpha$-picoline. Complex Compounds of barbiturates show uniformly maximum absorption at the wavelength of 540m.mu. and wre to be identified at the concentration of 1 X 10$^{-4}$ Mole, and also was to be quantitatively determined at the concentration of 1 X 10$^{-3}$ Mole. By this method barbiturates in the pharmaceuticals could be determined in the presence of various compounds such as sulpyrine, isopropylantipyrine, antipyrine, phenacetin and etc. But Barbiturates could be also determined by this method after seperation with aminopyrine, acetaminophen, acetylsalicylic acid and etc. by column chromatography. And barbiturates and acetylsalicylic acid could be also determined by simultaneous equation while their complex compounds show uniformly each maximum absorption at the Wavelength of 540 m${\mu}$ and 620 m${\mu}$. I.R. spectra of these complex compounds show identification of Barbiturates derivatives. The composition ratio of these complex compounds were : barbiturates : Cu : ${\alpha}$-picoline=2:1:2.

• 한국환경과학회지
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• 제21권1호
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• pp.49-55
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• 2012

In this study, the characteristic of offensive major odorous compound from the Bon-San industrial complex in Gimhae were determined by analytical methods of Gas Chromatography, High Performance Liquid Chromatography and UV/VIS Spectrophotometer. The kind of major odorous compounds examined acetaldehyde, sulfur compounds, ammonia and styrene. The concentration of all odorous compounds at 3 sampling points of industrial complex were lower than those of regulation standard levels of the industrial complex in Korea. The mean concentration of hydrogen sulfide was 0.0235 ppm at sampling point 2, it was higher than other sampling point. Complex odors was lower than regulation standard levels of the industrial complex in Korea.

• Archives of Pharmacal Research
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• 제8권3호
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• pp.109-117
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• 1985

The interaction of salicylic acid (S. A.), salicylamide (S,M) with nucleic acid base derivatives such as 9-ethyl adenine (A), 1-cyclohexyl uracil (U), 2', 3'-benzylidine-5' trityl-cytidine (C), gaunosine-2', 3', 5'-isobutylate (G) has been spectroscopically investigated to determine the binding mechanism. NMR and IR spectra were measured in nonpolar solvents. The association constant K of the formation of complex was calculated from the IR spectra. Compounds S. A. and A form a 1:1 or 1:2 cyclic hydrogen-bonded complex depending on the sample concentration. Compounds S. A. and U form a 1:1 or 1:2 hydrogen-bonded complex on the sample concentration. Compounds S. A. and C form a 2:1 hydrogen-bonded complex at low concentration (0.0016M). Compound S. A. binds compound G, but its binding does not completely break the self-association of compound G, Compound S. M. binds compounds A. U. C. G. very weakly.

• 한국대기환경학회지
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• 제23권2호
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• pp.147-157
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• 2007

This study was carried out to investigate the characteristics of fourteen odor compounds from a total of 10 sampling sites in residential areas around Banwol-Sihwa industrial complex. The measurement data are analyzed and compared with sensation of odor unit. Only a hydrogen sulfide out of four sulfur compounds was quantified above the detection limit (0.06 ppb) in the residential area around Banwol industrial complex with leather companies and a sewage treatment plant. The concentrations of VOCs were higher than those measured from a big city, and styrene showed the relatively high concentration from all sampling sites ($2.1{\sim}37.8\;ppb$). In the case of carbonyl compounds, acetaldehyde was found most frequently with the mean of 3.97 ppb, and its concentration difference was not significant between Banwol and Sihwa industrial complex. Of the nitrogen compounds, ammonia was measured at the relatively high concentration from all the sampling sites ($12{\sim}707\;ppb$), and a trimethylamine was found at the odor threshold level (0.1 ppb). The concentrations of styrene and ammonia showed relatively seasonal variation, the concentration of styrene in summer was five times higher than that in autumn, the concentration of ammonia in autumn was two times higher than that in summer. However other odorous compounds did not show such strong seasonal variation. Odor-concentration relationship between odor unit and $H_{2}S$ concentrations from industrial sources was examined and used as odor sensation evaluation, and thus the neighbourhood odor complaints maybe caused during the four seasons from the results.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2002년도 추계학술대회 논문집(II)
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• pp.943-947
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• 2002

Volatile Organic Compounds(VOCs) contribute to the formation of ozone and PAN which are injurious to health through complex photochemical reactions. Growing consumption of fossil fuels results in significant emission of VOCs and other air pollutants into the atmosphere. This study was carried out to evaluate of Volatile Organic Compounds(VOCs) concentrations in Kumi industrial complex. Ambient air sampling was determined at five sites from August to September in 2002. The Volatile Organic Compounds samples were collected using the silicocan canisters, and were determined by GC/MS which connected preconcentrator system. The Kumi industrial complex of VOCs concentrations were generally similar with Yeochun's but some of VOCs concentrations of Kumi were higher than Yeochun industrial complex's. Also the industrial area was higher than downtown and residential district.

• 한국환경과학회지
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• 제13권3호
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• pp.205-214
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• 2004

This study focuses on the measurement of airborne Volatile Organic Compounds (VOCs) in the Kumi electronic industrial complex during the time periods of August and September, 2002 and January and February, 2003. This study was based on the US-EPA method TO-14 while the VOCs were analyzed with GC/MSD. The toluene level revealed high concentration at all measurement sites. The areal rank of average concentrations of VOCs is as follows: industry1 > industry2 > urban > middle > residential. Concentrations of VOCs in Kumi electronic industrial ones were generally higher than at Yeochon and Ulsan industrial complexes. Dichloromethane and trichloroethylene, which are used as a cleaner in the process of electronic industries, were observed 4 to 8 times higher than those of other areas. Among the aromatic compounds, toluene showed the highest level, while the concentrations of dichloromethane and trichloroethylene were higher than those of other halogen compounds. In Kumi, toluene, trichloroethylene, and dichloromethane were confirmed as the major compounds of VOCs by this research.

• Carbon letters
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• 제10권2호
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• pp.101-108
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• 2009

Various silanes, amino silane, vinyl silane, TESPD, and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/hard clay/carbon black (CB) compound and they are investigated with respect to the vulcanization characteristics, the processability, and the mechanical properties. In hard clay/CB filled system, only ZS silane added compound shows both lower Mooney viscosity and extrusion torque while vinyl silane added compound showed only a lower extrusion torque. All the ZS added compounds showed the lowest viscosity among them. The silane added compounds showed an increased modulus. In 'fatigue to failure' count test, the ZS added compound showed superior counts compared to other silane (amino, vinyl, TESPD) added compounds. The mechanical properties were significantly increased when the S2 and ZS were added into CIIR/hard clay/CB compound. The ZS added compounds showed a significant improvement on elongation modulus.

• 한국지구과학회지
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• 제27권2호
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• pp.209-220
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• 2006

본 연구에서는 악취민원이 빈발한 경기도 안산시에 위치한 반월공단의 주거지역과 공단지역 등을 중심으로 주요 관리대상으로 설정된 악취성분들에 대한 환경대기 중 농도분포 특성을 2년여 기간동안 6차례에 걸쳐 조사하였다. 이들의 거동을 이해하기 위해, 시간적(오전과 오후) 및 공간적(공단 내외부의 위치) 기준으로 분포특성에 대한 비교를 시도하였다. 그 결과, 오전시간대에 비해 오후시간대에 고농도 분포가 현저하게 높은 것으로 나타났다. 이와 유사하게 공간적인 기준으로 비교한 결과도 공단 내부에서 관측한 결과에서 대부분의 성분들이 고농도를 유지하는 것을 확인할 수 있었다. 본 연구의 결과는 안산시 주변 및 공단지역의 환경대기 중에 존재하는 악취성분들이 시간적 및 공간적 기준으로 다양한 분포특성을 취한다는 것을 보여주었다.

• 한국염색가공학회지
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• 제4권2호
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• pp.64-68
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• 1992

The charge-transfer(CT) complexes derived from phenothiazine as donor and quinonoid compounds as accepters were evaluated as coloring matter. Light fastness of the intermolecular charge-transfer(CT) complex dyes as well as absorption wavelength is an important factor when the complexes are applied to coloring matters. The photofading mechanism of CT complex dyes of phenothiazine and accepters were examined. The addition of effective radical scavenger, antioxidant and photostabilizer gave a remarkable enhancement of the photostability of CT dyes.

• 대한화학회지
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• 제19권1호
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• pp.43-49
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• 1975

소량의 요오드 화합물이 윤활류에 함유될 때 금속표면사이의 마찰을 감소시키고 내마모성을 향상시키는데 이는 금속표면에 박층상구조의 이요오드화물이 형성되기 때문이라고 한다. 그러나 금속표면에서의 화학반응성, 마모와 극압실험 및 hot wire method에 의한 결과에 의하면 윤활기구는 이 요오드화물의 박층상 구조가 아니고 다른 기구에 의한 것임을 알았다. 유기 요오드화합물중에서 특히 N-iodopyridinium dichlorodate는 double charge transfer complex로써 다른 methyl iodide계의 화합물 보다 금속표면 사이의 마찰을 더욱 감소시키고 윤활기구는 interhalogen의 화학반응에 의한 것임을 알았다.