• Membrane Journal
• /
• v.23 no.1
• /
• pp.54-60
• /
• 2013

PEGDA/PETEDA dendrimer composite membranes was prepared by UV photopolymerizing of poly ethylene glycol diacrylate (PEGDA) containing 5~15 wt% pentaerythrityl tetraethylenediamine (PETEDA) dendrimer. The prepared composite membrane was characterized by FT-IR, $^1H$-NMR and DSC. The glass transition temperature ($T_g$) of PEGDA/PETEDA dendrimer composite decreased with the increment of PETEDA dendrimer content. The $CO_2$ separation properties over $CH_4$ were investigated by changing the PETEDA dendrimer content and pressure. The composite membrane containing 10 wt% PETEDA dendrimer exhibited on excellent $CO_2/CH_4$ ideal selectivity of 31.8 and a $CO_2$ permeability of 162.2 barrer.

• Journal of the Korean Ceramic Society
• /
• v.34 no.7
• /
• pp.747-757
• /
• 1997

ZSM-5 zeolite composite membranes have been synthesized from a silica sol solution containing TPABr as an organic template by the dip-coating and the pressurized-coating hydrothermal treatment techniques. The CO2 separation efficiency of synthesized composite membranes was also investigated. The permeation mechanism of CO2 through ZSM-5 membranses was the surface diffusion, and that of N2, O2, and He gases was Knudsen diffusion or activated diffusion depending on the synthetic method of membranes and the measurement temperature. The CO2/N2 separation factor of the membrane prepared by the dip-coating hydrothermal treatment was 2.5 at about 12$0^{\circ}C$, while the ZSM-5 composite membrane synthesized by the pressurized-coating hydrothermal treatment technique showed the CO2/N2 separation factor of 9.0 at room temperature higher than that ever reported in the literature.

• Membrane Journal
• /
• v.25 no.5
• /
• pp.456-463
• /
• 2015

In this study, we synthesize novel silane based inorganics for preparation of the polymer electrolyte membrane with high proton conductivity under high temperature condition and developed membranes are characterized. SPAES, hydrocarbon based polymer are synthesized and used as main polymeric material. We used sol-gel method to prepare inorganic material with high performance using silica, phosphate and zirconium. Three types of inorganics were prepared by control of the mole ration of each component. As a result of EDX analysis, the inorganic materials are well dispersed in the polymer membrane. The water uptake of the composite membrane is increased by introduction of the hydrophilic inorganic material in the membrane. When the content of the zirconium in the membrane is increased, the proton conductivity of the composite membrane shows the higher value than pure SPAES membrane at the high temperature. And the silica based inorganics effect to increase the proton conductivity under low temperature condition.

• Transactions of the Korean hydrogen and new energy society
• /
• v.22 no.5
• /
• pp.569-578
• /
• 2011

The $SiO_2$ membranes for polymer electrolyte membrane fuel cell (PEMFC) are preapared by electrospinning method. It leads to high porosity and surface area of membrane to accommodate the proton conducting materials. The composite membrane was prepared by impregnating of Nafion ionomer into the pores of electrospun $SiO_2$ membranes. The $SiO_2$:heteropolyacid (HPA) nano-particles as a inorganic proton conductor were prepared by microemulsion process and the particles are added to the Nafion ionomer. The characterization of the membranes was confirmed by field emission scanning electron microscope (FE-SEM), thermogravimetry analysis (TGA), and single cell performance test for PEMFC. The Nafion impregnated electrospun $SiO_2$ membrane showed good thermal stability, satisfactory mechanical properties and high proton conductivity. The addition of the $SiO_2$:HPA nano-particle improved proton conductivity of the composite membrane, which allow further extension for operation temperature in low humidity environments. The composite membrane exhibited a promising properties for the application in high temperature PEMFC.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.18 no.12
• /
• pp.3202-3218
• /
• 1994

Mode shapes and natural frequencies of vibrating laminated composite plates are taken using real-time and time-average holographic interferometry. Debonds and delamination in the laminated plates are measured nondestructively. During holographic testing of composite plates, it has been found that the conditions for the local resonance in debonds are strongly dependent on the frequency of excitation. A membrane resonance model was proposed to describe this behavior. Relations between characteristic length according to the size, shape of debonds and membrane resonance frequency are presented. Several experiments were performed to verify the membrane resonance model. The agreements between the predicted excitation frequency and the observed resonance frequency are good. The experimental results show that higher stresses and strains due to local resonance lead to the debond detection.

• Membrane and Water Treatment
• /
• v.8 no.6
• /
• pp.613-623
• /
• 2017

We report the novel thin film composite RO membrane modified by graphene oxide. The thin film composite RO membrane was exposed to 2000 mg/l sodium hypochloride; thereafter it was subjected to different graphene oxide concentration ranging from 50 mg/l to 1000 mg/l in water. The resultant membrane was crosslinked with 5000 mg/l N-hydroxysuccinimide. The performance of different membranes were analysed by solute rejection and water-flux measurement. It was found that 100 mg/l graphene oxide exposure followed by 5000 mg/l N-hydroxysuccinimide treatment resulted in the membrane with the highest solute rejection of 97.78% and water-flux of 4.64 Liter per sqm per hour per bar g. The membranes were characterized by contact angle for hydrophilicity, scanning electron micrographs for surface morphology, energy dispersive X-Ray for chemical composition of the surface, Atomic force microscope for surface roughness, ATR-FTIR for chemical structure identification. It was found that the graphene oxide modified membrane increases the salt rejection performance after exposure to high-fouling water containing albumin. Highly hydrophilic, antifouling surface formation with the nanomaterial led to the improved membrane performance. Moreover, the protocol of incorporating nanomaterial by this post-treatment is simple and can be applied to any RO membrane after it is manufactured.

• Membrane Journal
• /
• v.30 no.2
• /
• pp.111-123
• /
• 2020

Growing industrialization and climate change lead to the huge demand for clean drinking water. Desalination of sea water by membrane separation process is one of the alternative and economically viable methods to fulfil the demand for water. In the membrane separation process, the presence of 2D materials enhances the performance of membrane by facilitating the water permeation, salt rejection, flux rate, and selectivity compared to the traditional reverse osmosis thin-film-composite membranes. In this review, composite membranes with different kinds of 2D materials are discussed on the basis of materials synthesis, characterization and desalination process.

• Membrane Journal
• /
• v.20 no.1
• /
• pp.21-28
• /
• 2010

Organic/inorganic composite electrolyte membranes were prepared for dye sensitized solar cell (DSSC). Poly (ethylene glycol) (PEG)s with various molecular weight (600, 1,500, 2,000 and 3,400) were ethoxysilated to fabricate organic/inorganic composite materials through sol-gel processes. The electrolyte membranes were produced by doping the composite materials with KI and $I_2$, and their ionic conducting behaviors were investigated. The ionic conductivity of the composite membrane was highly affected by PEG molecular weight. The highest conductivity was shown by the composite membrane prepared with PEG with the molecular weight of 2,000. The composite electrolyte membranes showed considerable improvement of ionic conductivity. Compared to PEO electrolyte membranes, the composite electrolyte membrane by PEG, MW 2,000 showed much higher ionic conductivity.

• Transactions of the Korean hydrogen and new energy society
• /
• v.33 no.1
• /
• pp.28-37
• /
• 2022

In this study, we synthesized a poly(pheneylene oxide) (PPO)-based organic/inorganic composite membrane having silicotungstic acid (STA) for the development of an anion exchange membrane with excellent ionic conductivity and physicochemical stability. The organic/inorganic composite membranes were prepared by introducing different STA contents (0 wt%, 10 wt%, 30 wt%, and 50 wt%) into the quaternizaed(Q)-PPO matrix. The prepared anion exchange membranes were subjected to structural analysis by proton neclear magnetic resonance and Fourier transform infrared, and thermal behavior of membranes was confirmed by thermogravimetric analysis. Among the prepared composite membranes, the ion conductivity of Q-PPO/STA-50 (40.5 mS cm^-1) showed 1.46 times compared to that of the pristine membrane (27.6 mS cm^-1). Therefore, these results demonstrated that organic/inorganic composite membranes are promising candidates for application of anion exchange membranes.

• Proceedings of the Membrane Society of Korea Conference
• /
• 2004.11a
• /
• pp.149-151
• /
• 2004