• Title/Summary/Keyword: diffusivity of salt

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Prediction Model of Absorbed Quantity and Diffusivity of Salf in Radish during Salting (무우의 염절임시 소금의 침투량과 확산도 예측모델)

  • 최용희;권태연
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.20 no.6
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    • pp.572-581
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    • 1991
  • For the development of a model to predict absorbed salt quantity in radish during salting, absorbed salt quantity and water content change in radish by the hour were measured at 5%, 10%, 15% brine concentration and $10^{\circ}C,\;20^{\circ}C,\;30^{\circ}C$ respectively. Absorbed salt quantity in radish by the time showed logarithmic function, absorbed salt quantity by brine concentration and temperature showed linear relation. A model to predict absorbed salt quantity in radish at each time, brine concentration and temperature was calculated by the regression program of SPSS. Apparent diffusivity of salt in radish was calculated from appropriated diffusion equation solution of Fick's second law using computer simulation. Salt diffusivity in radish increased as brine concentration increased and the effect of temperature could by expressed by Arrhenius equation. A model equation which could predict salt diffusivity was developed by regression analysis. To specify relation between salt quantity which absorbed into radish and water content which removed out of it, Flux ratio(${\Delta}W/{\Delta}S$) was calcuated. The values showed that the removed water content was greater than the absorbed salt quantity.

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Diffusion of Sodium Chloride in Chinese Cabbage during Salting (배추의 염절임중 소금의 확산에 관한 연구)

  • Cho, Hyung-Yong;Kim, Ju-Bong;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
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    • v.20 no.5
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    • pp.711-717
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    • 1988
  • The diffusivity of sodium chloride in Chinese cabbage was evaluated from its absorption data obtained by immersing the cabbage stalk in a salt solution. By using least squares method, the absorption and desorption diffusivity of NaCl in the cabbage stalk have been estimated to be $1.7{\times}10^{-11}$ and $11.6{\times}10^{-11}m^2/s$, respectively. The apparent diffusivity was not strongly dependent on the concentration of brine and the variety of Chinese cabbage. The influence of temperature on the apparent diffusivity could be expressed as the Arrhenius type equation, in which the activation energy was estimated to be 66 KJ/mol.

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A Study on Salt Diffusion Coefficient and Deviation by Strength of High-Strength Concrete (고강도 콘크리트 강도별 염분확산계수 및 편차에 관한 연구)

  • Park, Dong-Cheon;Seok, Won-Kyun;Jeon, Hyun-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.117-118
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    • 2022
  • High-strength concrete is used for building durability on the coast. It is common to order and produce the concrete from several ready mixed concrete companies. The concrete in Busan was also commissioned by 12 ready mixed concrete companies. The compressive strength and salt diffusion coefficient were measured. The average value and deviation were analyzed.

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Application of Linear Dynamics to Salt Finger Favorable Flows (선형이론의 이중확산 유체의 적응)

  • Hwang, Jin-Hwan
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.10 no.1
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    • pp.53-58
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    • 2007
  • In an estuary, mixing and transport of contaminant sometimes occurs in the salt finger favorable condition (Hwang ang Rehmann, 2004). Linearized theory is applied to predict flow dynamics in salt finger favorable condition. The simulated results match well with previous laboratory experiments. When the density ratio is larger than 2, the heat and salt system shows $0.55{\sim}0.57$ as Turner (1967) found, and the salt and sugar system produces 0.87 of Griffiths (1980). As the ratio of molecular diffusivities of two scalars increases, the flux ratio increases. The flux and eddy diffusivity ratios decrease with increase of density ratio, and it takes longer time for flux ratio to be steady state at the higher density ratios.

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Relationship between Chloride Diffusivity and the Fundamental Properties of Concrete (염소이온의 확산계수와 콘크리트의 기초물성과의 관계)

  • Choi, Doo-Sun;Choi, Jae-Jin
    • Journal of the Korean Society of Hazard Mitigation
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    • v.9 no.1
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    • pp.15-20
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    • 2009
  • Marine concrete structure is exposed to salt injury and deteriorated by steel corrosion due to chloride ions diffusion. It, therefore, is very important to estimate the chloride diffusivity in concrete. In this paper the compressive strength and permeable pore volume of concrete are measured and the diffusion coefficient and penetration depth of chloride ions in concrete were investigated to estimate the chloride diffusivity efficiently. To correlate these results each other, regression analysis was done. The results showed a good linear relation between chloride diffusivity and the fundamental properties of concrete and the chloride diffusivity of concrete with water-cement ratios of $40%{\sim}60%$ were about $2.5{\sim}6.6{\times}10^{-12}m^2/s$.

The Chloride Ion Diffusivity of Ready-Mixed Concrete Depending on Specified Compressive Strength (레디믹스트 콘크리트의 설계기준 압축강도별 염소이온 확산특성)

  • Park, Dong-Cheon;Kim, Yong-Ro
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.6
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    • pp.543-550
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    • 2018
  • The RC buildings which are constructed on the seaside are followed by KBC(2016) to achieve the minimization of durability damage. To control the corrosion of the reinforcing steel bar by salt attack, W/C should be under 0.4 and specified concrete strength is higher than 35MPa in the concrete/building construction standard specification. Even though it has been proved that the concrete mixed with mineral admixture such as blast furnace slag and fly ash etc. have high strength and durability in previous researches, the beneficial informations are not applied to the codes. Ready-mixed concretes which usually include the admixtures in Busan were tested to certify the salt attack durability. In the same specified concrete strength, remarkable salt attack durability was evaluated in comparison to OPC. For economical and reliable durability design, chloride ion diffusivity should be measured before applying to new building construction.

The Solution of Upward Salt Diffusion in Floodeol Soil using Laplace Transformation (침수상태(湛水狀態)에서 토양(土壤) 염분(鹽分) 확산(擴散) 상승(上昇) 해석(解析)에 Laplace변환 이용)

  • Oh, Yong-Taeg;van der Molen, W.H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.28 no.3
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    • pp.233-240
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    • 1995
  • Fick's diffusion equation was transformed into algebraic subsidiary equation with its initial and boundary conditions through Laplace transformation, and the subsidiary equation was transformed back on the basis of Burington's table of inverse transformations so that it became the solution of Fick's equation. The initial and boundary condition was for upward diffusion of salts into flooding water of constant depth from uniform polder soil of infinite depth containing constant concentration of salt. The derived solution was tested through comparison for its conformability with other solutions of simpler initial and boundary conditions. The importance of shallow transplanting of rice seedlings and salt removing by growing rice was mentioned on the basis of very slow desalting rate by diffusion calculated from the derived solutions.

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Assessment on Recovery of Cesium, Strontium, and Barium From Eutectic LiCl-KCl Salt With Liquid Bismuth System

  • Woods, Michael E.;Phongikaroon, Supathorn
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.4
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    • pp.421-437
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    • 2020
  • This study provides an assessment on a proposed method for separation of cesium, strontium, and barium using electrochemical reduction at a liquid bismuth cathode in LiCl-KCl eutectic salt, investigated via cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and scanning electron microscopy with energy dispersive X-ray spectrometry (SEM-EDS). CV studies were performed at temperatures of 723-823 K and concentrations of the target species up to 4.0wt%. Redox reactions occurring during potential sweeps were observed. Concentration of BaCl2 in the salt did not seem to influence the diffusivity in the studied concentration range up to 4.0wt%. The presence of strontium in the system affected the redox reaction of lithium; however, there were no distinguishable redox peaks that could be measured. Impedance spectra obtained from EIS methods were used to calculate the exchange current densities of the electroactive active redox couple at the bismuth cathode. Results show the rate-controlling step in deposition to be the mass transport of Cs+ ions from the bulk salt to the cathode surface layer. Results from SEM-EDS suggest that Cs-Bi and Sr-Bi intermetallics from LiCl-KCl salt are not thermodynamically favorable.

A Mechanical Model for Texture Changes and Rheological Properties of Radish During Salting (염농도의 확산에 따른 무의 물성학적 특성의 예측 model에 관한 연구)

  • Lee, Seung-In;Kim, Byung-Yong;Cho, Jae-Sun
    • Korean Journal of Food Science and Technology
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    • v.24 no.4
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    • pp.335-340
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    • 1992
  • The amounts of salt diffused into radish after immersing in various concentrations of salt solution at different temperatures were measured and the changes of radish texture by the salt diffusion were estimated with the viscoelastic constants of a 3 element solid model determined by a stress relaxation test. The amount of salt diffused through radish was increased with increasing the salt concentration and soaking temperature. While the instantaneous stress, equilibrium elastic solid content and viscoelastic constants of radish were decreased as salt concentration and soaking temperature increased, the stress relaxed fast. Viscoelastic constants as well as the diffusivity were influenced by salt concentration more than by soaking temperature. The rheological equations for the predictable stress changes of radish after immersed in the salt solution at various conditions (temperature, salt concentration and impure salt) were suggested as a function of time.

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Durability Evaluation of High-Performance, Low-Heat Self-Compacting Concrete for Foundation of Tall Buildings (초고층 건축물 매트 기초용 고성능 콘크리트 내구성 평가)

  • Kim, Young-Bong;Park, Dong-Cheon
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.5
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    • pp.425-430
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    • 2022
  • Concrete used for the foundation of high-rise buildings is often placed through in an integrated pouring to ensure construction efficiency and quality. However, if concrete is placed integrally, there is a high risk of temperature cracking during the hydration reaction, and it is necessary to determine the optimal mixing design of high-performance, high-durable concrete through the replacement of the admixture. In this study, experiments on salt damage, carbonation, and sulfate were conducted on the specimen manufactured from the optimal high-performance low-heating concrete combination determined in the author's previous study. The resistance of the cement matrix to chlorine ion diffusion coefficient, carbonation coefficient, and sulfate was quantitatively evaluated. In the terms of compression strength, it was measured as 141% compared to the structural design standard of KCI at 91 days. Excellent durability was expressed in carbonation and chlorine ion diffusivity performance evaluation. In particular, the chlorine ion diffusion coefficient, which should be considered the most strictly in the marine environment, was measured at a value of 4.09×E-12m2/y(1.2898×E-10m2/s), and is expected to be used as a material property value in salt damage durability analysis. These results confirmed that the latent hydroponics were due to mixing of the admixture and high resistance was due to the pozzolane reaction.