• Title/Summary/Keyword: electro-chemical systems

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Fluorescent Probes for Analysis and Imaging of Monoamine Oxidase Activity

  • Kim, Dokyoung;Jun, Yong Woong;Ahn, Kyo Han
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1269-1274
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    • 2014
  • Monoamine oxidases catalyze the oxidative deamination of dietary amines and amine neurotransmitters, and assist in maintaining the homeostasis of the amine neurotransmitters in the brain. Dysfunctions of these enzymes can cause neurological and behavioral disorders including Parkinson's and Alzheimer's diseases. To understand their physiological roles, efficient assay methods for monoamine oxidases are essential. Reviewed in this Perspective are the recent progress in the development of fluorescent probes for monoamine oxidases and their applications to enzyme assays in cells and tissues. It is evident that still there is strong need for a fluorescent probe with desirable substrate selectivity and photophysical properties to challenge the much unsolved issues associated with the enzymes and the diseases.

The Fabrication of Ion Exchange Membrane and Its Application to Energy Systems (고분자 이온교환막의 제조와 이온교환막을 이용한 에너지 공정)

  • Kim, Jae-Hun;Ryu, Seungbo;Moon, Seung-Hyeon
    • Membrane Journal
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    • v.30 no.2
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    • pp.79-96
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    • 2020
  • Secondary energy conversion systems have been briskly developed owing to environmental issue and problems of fossil fuel. They are basically operated based on electro-chemical systems. In addition, ion exchange membranes are one of the significant factors to determine performance in their systems. Therefore, the ion exchange membranes in suitable conditions must be developed to improve the performance for the electro-chemical systems. These ion exchange membranes can be classified into various types such as cation exchange membrane, anion exchange membrane and bipolar membrane. Their membranes have distinct characteristics according to the chemical, physical and morphological structure. In this review, the types of ion exchange membranes and their fabrication processes are described with main characteristics. Moreover, applications of ion exchange membranes in newly developed energy conversion systems such as reverse electrodialysis, redox flow battery and water electrolysis process are described including their roles and requirements.

Planarization of Cu intereonnect using ECMP process (전기화학 기계적 연마를 이용한 Cu 배선의 평탄화)

  • Jeong, Suk-Hoon;Seo, Heon-Deok;Park, Boum-Young;Park, Jae-Hong;Lee, Ho-Jun;Oh, Ji-Heon;Jeong, Hae-Do
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.79-80
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    • 2007
  • Copper has been used as an interconnect material in the fabrication of semiconductor devices, because of its higher electrical conductivity and superior electro-migration resistance. Chemical mechanical polishing (CMP) technique is required to planarize the overburden Cu film in an interconnect process. Various problems such as dishing, erosion, and delamination are caused by the high pressure and chemical effects in the Cu CMP process. But these problems have to be solved for the fabrication of the next generation semiconductor devices. Therefore, new process which is electro-chemical mechanical planarization/polishing (ECMP) or electro-chemical mechanical planarization was introduced to solve the. technical difficulties and problems in CMP process. In the ECMP process, Cu ions are dissolved electrochemically by the applying an anodic potential energy on the Cu surface in an electrolyte. And then, Cu complex layer are mechanically removed by the mechanical effects between pad and abrasive. This paper focuses on the manufacturing of ECMP system and its process. ECMP equipment which has better performance and stability was manufactured for the planarization process.

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Unique Fluid Ensemble including Silicone Oil for the Application of Optical Liquid Lens

  • Bae, Jae-Young;Park, Sung-Soo;Kim, Jae-Hong;Park, Chin-Ho;Choi, Young-Chul;Jung, Ha-Yong
    • Bulletin of the Korean Chemical Society
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    • v.29 no.4
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    • pp.731-735
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    • 2008
  • The fluid ensemble in the liquid lens, which is composed of electrolyte and silicone oil, is the key material system to vary the focal length processing of the electrochemical desorption. In order to characterize the capability of the liquid lens according to response time and optical range, we prepared a fluid ensemble comprising the electrolyte and oil. To elucidate the physical mechanism of the effective response time, we examined the viscosity dependency while satisfying the requirements for the density and refractive index of the electrolyte and oil, respectively. The characterization results indicated that the response time (up and down) is influenced by the viscosity of the electrolyte and oil. On this basis, we prepared a fluid ensemble capable of reversibly adjusting for the focal length of the liquid lens, as well as the response time. The ensemble is applicable to various systems such as micro-lens and optical sensors.

Fabrication of 2-Dimensional ZnO Nanowall Structure (2차원 ZnO 나노벽 구조 제조)

  • Kim, Young-Jung;Cao, Guozhong;Kim, Yeong-Cheol;Ahn, Seung-Joon;Min, Joon-Won
    • Journal of the Korean Ceramic Society
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    • v.42 no.7 s.278
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    • pp.521-524
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    • 2005
  • ZnO 2-D nanowall structure with around 100 nm thickness, which is composed of tens of nm scale ZnO single crystals, was fabricated through the low temperature chemical solution growth method. Electro Chemical Deposition (ECD) technique was applied to attach the ZnO seed crystals on ITO coated glass substrate. The ZnO nanowall structure was grown in the 0.015 mol$\%$ of aqueous solution of zinc nitrate and hexamethenamine at 60$^{\circ}C$ for 20 - 40 h. The nanowall structure depends on the ECD condition or the applied voltage and duration time. The nanowall shows a photoluminescence around 550 - 700 nm spectrum range.

Reliability Improvement of the Electro Optical Tracking System by using DLC Films (DLC 박막을 통한 전자광학추적장비 신뢰성 개선)

  • Shim, Bo-Hyun;Jo, Hee-Jin;Kim, Jang-Eun
    • Journal of the Institute of Electronics and Information Engineers
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    • v.52 no.5
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    • pp.197-205
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    • 2015
  • The Diamond Like Carbon(DLC) films for the Electro Optical Tracking System(EOTS) by using Plasma Enhanced Chemical Vapor Deposition(PECVD) method is presented. We achieve that the DLC films can reduce the surface delamination of thermal observation sensor front window due to the high hardness, low friction and chemical inertness which is comparable to a Si film. According to our experiment results, DLC films can be used for various electro optical systems to eliminate surface delamination.

Electro-active Polymer and Dielectric Elastomer Technology for Haptic Interface, Muscular Enhancement, and Tunable Optical Components (전기가변 고분자 소재를 이용한 응용소자)

  • Yoon, J.W.;Park, S.K.;Mun, S.
    • Electronics and Telecommunications Trends
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    • v.34 no.4
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    • pp.108-116
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    • 2019
  • Electro-active polymers and dielectric elastomers have many intriguing properties that enable smart interfaces and electrically tunable optical systems, such as haptic feedback devices, artificial muscles, and expansion-tunable optical elements. These device classes are of great interest owing to their promising roles in next-generation technologies including virtual or augmented reality, human sensing and muscular enhancement, and artificial skins. In this report, we review basic principles, current state-of-the-art techniques, and future prospects of electro-active and dielectric elastomer technology. We describe chemical and physical properties of the most promising polymer substances, essential elementary architectures for artificial muscle-like functionalities, and their applications to haptic interfaces, muscular enhancement, and focus-tunable optical elements.

Fabrication of Electro-active Polymer Actuator Based on Transparent Graphene Electrode

  • Park, Yunjae;Choi, Hyonkwang;Im, Kihong;Kim, Seonpil;Jeon, Minhyon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.386.1-386.1
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    • 2014
  • The ionic polymer-metal composite (IPMC), a type of electro-active polymer material, has received enormous interest in various fields such as robotics, medical sensors, artificial muscles because it has many advantages of flexibility, light weight, high displacement, and low voltage activation, compare to traditional mechanical actuators. Mostly noble metal materials such as gold or platinum were used to form the electrode of an IPMC by using electroless plating process. Furthermore, carbon-based materials, which are carbon nanotube (CNT) and reduced graphene-CNT composite, were used to alter the electrode of IPMC. To form the electrode of IPMC, we employ the synthesized graphene on copper foil by chemical vapor deposition method and use the transfer process by using a support of PET/silicone film. The properties of graphene were evaluated by Raman spectroscopy, UV/Vis spectroscopy, and 4-point probe. The structure and surface of IPMC were analyzed via field emission scanning electron microscope. The fabricated IPMC performance such as displacement and operating frequency was measured in underwater.

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