• Title/Summary/Keyword: element substitution

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Studies of Element Substitution on Superconductivity in Bi-Sr-Ca-Cu-O Oxides (Bi계 치환 고온 초전도체)

  • 권오흥;박천제
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2000.11a
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    • pp.124-128
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    • 2000
  • The high Tc phase disappeared and low Tc phase increased in the substitution of transistion elements for Bi ions. The high Tc phase decreased in the substitution of Si and Sn for Bi ions. The high Tc phase increased in the substitution of Sb, As and P Which Were the same group of Bi for Bi ions. The substitution of P ions was the most effective and then the high Tc phase was formed in large quantity by replacing Bi ions with 30%of P ions.

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Studies of Element Substitution on Superconductivity in Bi-Sr-Ca-Cu-O Oxides (Bi계 치환 고온 초전도체)

  • 권오흥;박천제
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.124-128
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    • 2000
  • The high Tc phase disappeared and low Tc phase increased in the substitution of transition elements for Bi ions. The high Tc phase decreased in the substitution of Si and Sn for Bi ions. The high Tc phase increased in the substitution of Sb, As and P which were the same group of Bi for Bi ions. The substitution of P ions was the most effective and then the high Tc phase was formed in large quantity by replacing Bi ions with 30% of P ions.

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Control of $NaAlSiO_4:Eu^{2+}$ photoluminescence properties by charge-compensated aliovalent element substitutions

  • Kim, Jihae;Kato, Hideki;Kakihana, Masato
    • Journal of Information Display
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    • v.13 no.3
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    • pp.97-100
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    • 2012
  • We have conducted two kinds of the so-called charge-compensated aliovalent element substitutions to control the photoluminescence properties of $NaAlSiO_4:Eu^{2+}$ with a special focus on the enhancement of the excitation intensity at 400 nm. The aliovalent element substitutions include cation-cation and cation-anion co-substitutions according to the general formulas $Na_{1-x}M_xAl_{1+x}Si_{1-x}O_4:Eu^{2+}$ and $Na_{1-x}M_xAlSiO_{4-x}N_x:Eu^{2+}$ (M = $Mg^{2+}$, $Ca^{2+}$, and $Sr^{2+}$), respectively. The increase in the relative excitation intensity at 400 nm has been achieved in both types of the co-substitutions. Thus, the present research has demonstrated the effectiveness of the charge-compensated element substitution.

A Study on Material Substitution Design and Evaluation Method for Structural Components of Rolling Stocks (철도차량 구조부품의 소재대체 설계 및 평가기법 연구)

  • 구정서;정현승
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.4
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    • pp.74-84
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    • 2004
  • In this paper, a theoretical method was derived to redesign carbody members by substituting light-weight materials, and to estimate their structural characteristics. Some performance indices to estimate structural behaviors were derived in order to obtain equivalent designs in case of material substitutions under important design constraints of rolling stock, such as bending stiffness, natural frequency, bending and buckling strength. Validity of the theoretical method was evaluated by comparing its results with finite element results in some examples where the aluminium alloy was substituted for the structural steel. The numerical results of the examples show that the proposed method gives reasonable initial guesses for the material substitution designs.

A Study of the effective method of LU factorization for Newton-Raphson Load Flow (Newton-Raphson법을 이용한 조류계산을 위한 효율적인 LU분해 계산 방법에 관한 연구)

  • Gim, Jae-Hyeon;Lee, So-Young
    • Proceedings of the KIEE Conference
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    • 2000.07a
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    • pp.274-275
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    • 2000
  • This paper introduces new ordering algorithms using the graph of data structure and forward/backward substitution of LU decomposition using recursive function. The performance of the algorithm is compared with Tinney's algorithm using 14 bus systems. Test results show that the new fill-in element of Jacobian matrix using the proposed ordering algorithm is same as that of Tinner scheme 3 and the forward/backward substitution can reduce the computation time

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Piezoelectric and Electric Field Induced Strain Properties of PMW-PNN-PZT Ceramics with the Substitution of Ba (Ba 치환에 따른 PMW-PNN-PZT 세라믹스의 압전 및 전계유기왜형 특성)

  • 윤광희;김규수;최병수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.1
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    • pp.20-25
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    • 2001
  • To develop the piezoelectric actuator, the structural, dielectric and piezoelectric properties and electric fieldinduced strain of the ceramics(Pb$\_$1-2/Ba$\_$x/)[Mg$\_$1/2/W$\_$1/2/)$\_$0.03/-Ni$\_$1/3/Nb$\_$2/3/)$\_$0.12/-(Zr$\_$0.5/Ti$\_$0.5/)$\_$0.85/]O$_3$(x=0, 0.01, 0.03, 0.05, 0.07, 0.1) were investigated with the substitution of Ba. The tetragonality of crystal structure and grain size decreased by the substitution of Ba. Curie temperature decreased due to the decrease of the tetragonality, and dielectric constants increased with the substitution of Ba. The coercive field, remnant polarization and electromechanical coupling factor also decreased, whereas the piezoelectric constatns d$\_$33/ and d$\_$31/ were showed the highest value of 430 and 209(x10$\^$-12/C/N), respectively, because of the increase of dielectric constant. The strain induced by 60Hz AC electric field had the maximum value of 204x10$\^$-6/Δℓ/ℓ at the substitution of Ba 3mol%. As the applied electric field approaches to the coercive field, the piezoelectric element is depolarized and the electric field induced strain revealed non-linearity.

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Introduction to the material substitution design method for the weight reduction of rolling stock carbody (철도차량차체 경량화를 위한 소재대체설계기술)

  • Kwon, Tae-Soo;Koo, Jeong-Seo;Huh, Shin
    • Proceedings of the KSR Conference
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    • 2003.10c
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    • pp.446-454
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    • 2003
  • This paper derived a theoretical method to estimate structural characteristics of carbody members when material substitution designs were performed, and verified the theoretical method with finite element analyses. For important factors in rolling stock design, such as bending stiffness, natural frequency, bending strength and buckling strength, some performance indices to estimate structural behaviors were developed in order to derive an equivalent design in spite of material substitutions. The developed method was used to reduce the weights of carbody components, as example problems, by substituting the aluminium alloy for the structural steel. The analysis results of the examples show that the proposed technique gives a reasonable initial guess in the case of a material substitution design.

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Effects of ${Co_3}{O_4}$, and ${La_2}{O_3}$on the Magnetic Properties of Sr-Ferrite (${Co_3}{O_4}$${La_2}{O_3}$ 첨가가 Sr 페라이트의 자기적 특성에 미치는 영향)

  • Jang, Se-Dong;Kim, Chong-O;Kim, Jong-Hui
    • Korean Journal of Materials Research
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    • v.11 no.8
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    • pp.685-689
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    • 2001
  • We carried out these experiments to examine the effects of element substitution of Co and La-Co for Sr-ferrite. The calcined properties of Co and La-Co element substitution were examined, and also the sintered magnetic properties were measured with the stoichiometric condition. The magnetic properties of $(La-Co)_{0.3}-SrM$ composition are as follows; $(M_s)$: 71.08 emu/g, $iH_c$: 4.38 kOe and $B_r$ : 4.18 kG, $iH_ c$ :4.35 kOe, $BH_{max}$: 4.3 MGOe. The $BH_{max}$ value was increased up to 10 % compared with conventional values. Our results imply that the magnetic properties of Sr-ferrite can be improved by the substitution of those elements.

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Resin Synthesis of Adsorbent Metal Ions using 1-Aza-12-Crown-4 (1-Aza-12-Crown-4를 이용한 금속 이온 흡착제 수지 합성)

  • Kim Joon-Tae;Roh Gi-Hwan
    • Journal of environmental and Sanitary engineering
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    • v.19 no.3 s.53
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    • pp.52-57
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    • 2004
  • Content of chlorine in s쇼rene-DVB copolymer was decreased as crosslink increased and it is because as crosslink increased $1\%,\;2\%,\;5\%\;and\;10\%$ DVB content increased and crosslink density increased and cavity was reduced. Functional group of resin almost disappeared as C-C1 peak around $700cm^{-1}$ was substituted with 1-aza-12-C-4 macrocyclic ligand and new peak of C-N around $1020cm^{-1}$ appeared, so it was confirmed that styrene-DVB copolymer and ligand were compounded. As crosslink increased in the analysis of element contents, it resulted in the reduction of nitrogen content and it is because as crosslink increased, it led to the reduction of chlorine content in the process of substitution reaction and it affected macrocyclic ligand substituted. Form of functional synthetic resin showed distortion of its particles as macrocyclic ligand was introduced to styrene-DVB copolymer and hydrogen of ligand caused substitution with chlorine element of styrene molecule.