• Title/Summary/Keyword: energy band

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Electronic Spectra and Quenching of Dimethylanilines (Dimethylanline의 Electronic Spectra와 消光)

  • Jung, Kyung-Hoon;Lee, Ik-Choon
    • Journal of the Korean Chemical Society
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    • v.8 no.4
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    • pp.158-163
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    • 1964
  • Electronic spectra and quenching constants for ten N,N-dimethylanilines (DMA) have been determined. The $250m{\mu}$ absorption band (C band) of DMA was shown to be mainly responsible for the quenching. This band was confirmed as an $n{\to}{\pi}^{\ast}$ band through substituent and medium effects on the spectra shifts. The energy absorbed by this band then transfers to triplet and down to the lowest triplet state, $^{3}La$, where the energy is lost by non-radiative collisions.

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Optical characteristics of Se thin film fabricated by EBE method (전자빔 증착법으로 제작한 Se박막의 광학적 특성)

  • 정해덕;이기식
    • Electrical & Electronic Materials
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    • v.9 no.5
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    • pp.445-449
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    • 1996
  • Structural and optical characteristics in Se thin film fabricated by EBE method had been studied. Se thin film was deposited with noncrystalline until substrate temperature of >$100^{\circ}C$ Color of its surface had red genealogy, and its optical energy band gap was about 2.45 eV. But Se film was grown with monoclinic at substrate temperature of over >$150^{\circ}C$ Also, color of its surface had gray genealogy, and its optical energy band gap was about 2.31 eV. Finally, after heat-treatment at >$150^{\circ}C$ for 15 min with substrate temperature of >$100^{\circ}C$ noncrystalline Se was proved to be hexagonal, and color of its surface had dark gray genealogy, and its optical energy band gap was about 2.06 eV. From the results, it was known that Se thin film for photoelectric device with the lowest optical energy band gap was accepted from hexagonal structure.

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Multi-resolution hierarchical motion estimation in the wavelet transform domain (웨이브렛 변환된 다해상도 영상을 이용한 계층적 움직임 추정)

  • 김진태;장준필;김동욱;최종수
    • Journal of the Korean Institute of Telematics and Electronics B
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    • v.33B no.8
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    • pp.50-59
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    • 1996
  • In this paper, a new hierarchical motion estiamtion scheme using the wavelet transformed multi-resolution image layers is proposed. Compared with the full search motion estimation method, the existing hierarchical methods remarkably reduce the amount of the computation but their efficiencies are depreciated by the local minima problem. In order to solve the local minima problem, the multi-resolution image layers are composed using the wavelet transform and the number of layers participated in the motion estimation for a block is determined by considering of its low band energy and higher band energy on the first wavelet transformed layer. The ratio between higher band energy and low band energy of each block is evaluated and in the case of the blocks which include relatively large higher band energy, the motion estimation is carried out in the high resolution layer. Otherwise, all layers are used. The final motion vectors are obtained in the first wavelet transformed layer. So less bits for motion vectors are transmitted, and the decomposition of received image using inverse wavelet transform decreases the blocking effect.

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Generation of a adaptive tetrahedral refinement mesh for GaAs full band monte carlo simulation (풀밴드 GaAs monte carlo 시뮬레이션을 위한 최적사면체격자의 발생)

  • 정학기
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.34D no.7
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    • pp.37-44
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    • 1997
  • A dadaptive refinement tetrahedron mesh has been presented for using in full band GaAs monte carlo simulation. A uniform tetrahedron mesh is used without regard to energy values and energy variety in case of the past full band simulation. For the uniform tetrahedron mesh, a fine tetrahedron is demanded for keeping up accuracy of calculation in the low energy region such as .GAMMA.-valley, but calculation time is vast due to usin gthe same tetrahedron in the high energy region. The mesh of this study, thererfore, is consisted of the fine mesh in the low energy and large variable energy region and rough mesh n the high energy. The density of states (DOS) calculated with this mesh is compared with the one of the uniform mesh. The DOS of this mesh is improved th efive times or so in root mean square error and the ten times in the correlation coefficient than the one of a uniform mesh. This refinement mesh, therefore, can be used a sthe basic mesh for the full band GaAs monte carlo simulation.

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The Calculation of the Energy Band Gaps and Optical Constants of Zincblende InyGa1-yAs1-xNx on Composition (조성비 변화에 따른 질화물계 화합물 반도체 InyGa1-yAs1-xNx의 에너지 밴드갭과 광학상수 계산)

  • Chung, Ho-Yong;Kim, Dae-Ik
    • The Journal of the Korea institute of electronic communication sciences
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    • v.14 no.5
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    • pp.877-886
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    • 2019
  • The energy band gaps and optical constants of zincblende $In_yGa_{1-y}As_{1-x}N_x$ on the variation of temperature and composition are determined by using band anticrossing method. The energy band gaps are decreasing continuously in $In_yGa_{1-y}As_{1-x}N_x$ ($0{\leq}x{\leq}0.05$, $0{\leq}y{\leq}1.0$, 300K) and the bowing parameter is calculated as 0.522eV. The calculation results of energy band gaps are consistent with those of other studies. A refractive index n and a high-frequency dielectric constant ${\varepsilon}$ are calculated by a proposed modeling equation using the results of energy band gaps.

Synthesis and Band Gap Analysis of Meso-Arylporphyrins Containing Exclusively Electron Donating or Withdrawing Groups

  • Min Su Kang;Kwang-Jin Hwang
    • Journal of the Korean Chemical Society
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    • v.67 no.3
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    • pp.175-180
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    • 2023
  • Tetra-aryl substituted A4-type porphyrins (TP, TD, TA) and trans-A2B2 porphyrins (DDP1, AAP1) with electron-donating or withdrawing groups were synthesized. The band gap energy of those porphyrins was calculated from their UV-Vis spectra and CV data. With an electron-withdrawing group, the band gap energy of porphyrin TA increased via the LUMO energy up. Meanwhile, the introduction of an electron-donating group decreased the band gap of porphyrin by HOMO level up as as in the case of porphyrin TD. The band gap (2.19-2.28 eV) of metalloporphyrin PP-Ni was greater than those (1.81-2.06 eV) of non-metalloporphyrins PP due to the LUMO level up.

Design and performance analysis of the linear phase para-unitary M bandfilter bank with application to image coding (영상 부호화를 위한 LPPU M 대역 필터군의 설계와 성능 분석)

  • 이창우;김종원;이상욱
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.21 no.5
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    • pp.1141-1154
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    • 1996
  • The para-unitary (PU) M band filter bank, which can beused for M band decomposition, has many useful properties. In this ppaer, attempts have been made to design and and analyze the linear phase para-unitary (LPPU) M band filter bank, which is appropriate to the image coding application. First, we derive a unified coding gain in terms of the correlation in the band, as well as the energy compaction. And M band filter bank has been designed, maximizing the new coding gain. Then, we analyze the image coding performance of the LPPU M band filter bank, such as the energy compaction, the correlation in the band and the entropy. From the analysis, it is shown that the coding gain for LPPU M band filter bank improves, and the coding gain for the LPPU 4 band filter bank approaches very closely to that for LPPU 8 band filter bank, as the length of the filter increases. This fact is also verified by the coding results on the real images.

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Lab-scale experimental setup to evaluate the performance of band driers (통기밴드식 건조기의 성능 평가 실험 장치)

  • Seongmin, Park;Sang Hyun, Oh;Sung Il, Kim;Wonjung, Kim
    • Journal of the Korean Society of Visualization
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    • v.20 no.3
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    • pp.36-41
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    • 2022
  • Drying process is involved in the production of various products including food, textiles, paper, pharmaceuticals, and batteries. Phase change of liquid to vapor generally requires enormous thermal energy, so in order to save energy, it is advantageous to develop an appropriate drier and use it under appropriate operating conditions, depending on the characteristics of materials. However, due to the complex, multiscale heat and mass transfer occurring during drying processes, predictions of appropriate drying conditions before actual operation are not easily achieved, leading to challenges in designing driers. Here, we developed a lab-scale experimental setup to evaluate the performance of band dries. The experimental setup was used to measure the moisture content and temperature change in the materials being dried in a belt dryer. Experimental results obtained using our lab-scale setup allow us to predict the performance of a full-scale band drier, thus suggesting a practical framework for predicting the drying process of various materials and developing band driers.

Energy Levels of $^53 Mn$ by the Nilsson Model

  • Chung, Woon-Hyuk
    • Nuclear Engineering and Technology
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    • v.7 no.3
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    • pp.207-211
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    • 1975
  • The Nilsson model was used to predict energy levels of $^{53}$ Mn without taking band mixing into consideration. The results were compared with the experimental levels and the predictions with band mixing of Malik ana Scholz. In both cases, with band mixing and without band mixing, the theoretical fit to experimental results is fair only for a few low-tying levels. However, it is found that the present calculation fits rather better to experiment than the band mixing calculation as far as higher levels are concerned.

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Temperature dependence of photocurrent spectra for $AgInS_2$ epilayers grown by hot wall epitaxy

  • Baek, Seung-Nam;Hong, Kwang-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.123-124
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    • 2007
  • A silver indium sulfide ($AgInS_2$) epilayer was grown by the hot wall epitaxy method, which has not been reported in the liteniture. The grown $AgInS_2$ epilayer has found to be a chalcopyrite structure and evaluated to be high quality crystal. From the photocurrent measurement in the temperature range from 30 K to 300 K, the two peaks of A and B were only observed, whereas the three peaks of A, B, and C were seen in the PC spectrum of 10 K. These peaks are ascribed to the band-to-band transition. The valence band splitting of $AgInS_2$ was investigated by means of the photocurrent measurement. The temperature dependence of the energy band gap of the $AgInS_2$ obtained from the photocurrent spectrum was well described by the Varshni's relation, $E_g(T)=\;E_g(0)\;eV-(7.78\;{\times}\;10^{-4}\;eV/K)T^2/(T\;+\;116\;K\;K)$. Also, Eg(0) is the energy band gap at 0 K, which is estimated to be 2.036 eV at the valence band state A and 2.186 eV at the valence band state B.

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