• Journal of the Korea Concrete Institute
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• v.18 no.4 s.94
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• pp.553-558
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• 2006

In this study, fluorine-silicate hybrid type crack reducing agent(FS) consisted of fluorine and silicate compounds applied to concrete mix(specification : 25-30-18) between 0.5% and 2.0% at intervals of 0.5% based on cement weight. Experiments for material properties of concrete such as slump, air content and bleeding with elapsed time were performed. Experiment and elucidation for shrinkage crack resistance as well as adiabatic hydration temperature were also carried out. It was appeared that FS addition contributed to lower bleeding and hydration temperature without disturbance of fresh properties of concrete such as slump and air content compared to non-added concrete. Especially, shrinkage crack resistance of concrete resulted from plastic and drying shrinkage could be effectively reduced by the addition of FS ranging from 1.0% to 1.5%.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.683-686
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• 2005

This paper is related to investigate adding effect of fluorine-silicate hybrid type crack controlling agent(FS) on initial behavior, dynamic properties, adibatic hydration temp, and plastic crack behavior of concrete(Specification : 25-30-18). It is appeared that adding of FS contributed to strength elevation, lowering of hydration temperature as well as plastic crack reduction without disturbance of initial behaviors of concrete such as slump, air content and setting.

• Journal of the Korea Concrete Institute
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• v.18 no.5 s.95
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• pp.631-637
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• 2006

In this study, fundamental properties such as fresh and hardened performance of concrete mix(specification : 25-24-18) added fluorine-silicate hybrid based crack reducing agent(FS) were measured. Addition of FS ranged from 0.5% to 2.0% at intervals 0.5% based on cement weight. Adequate dosage(0.5%) of FS derived from basic properties measurements applied and compared resistance for shrinkage crack. The permeability of concrete in the absence(24-S-0.0) and presence(24-S-0.5) of evaluated at a mock-up sized concrete. Concrete added FS improved resistance for shrinkage crack and consequently crack number, length and area decreased to $50{\sim}74.4%$ compared non-added. As well, by the addition of FS, the resistance for permeability and penetration depth to concrete surface region increased 67% and 40%, respectively. Therefore it was confirmed that shrinkage crack resistance and permeability of concrete could be improved by the addition of FS.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.03a
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• pp.73-73
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• 2003

나노 크기의 기공이 규칙적으로 배열되어 있는 실리케이트 메조포러스 분말 재료는 넓은 표면적과 화합물에 대한 선택적 흡착 등이 가능하여 많은 연구가 진행퇴고 있다. 최근에는 실리케이트 메조포러스 재료를 박막으로 제조하여 전자소자 혹은 광소자의 제작에 응용하기 위한 연구가 많이 진행되고 있다. 이러한 실리케이트 기공 내부의 표면에 소수성, 극성, 광전자 활성 등, 특정한 기공 표면 특성을 부여하기 위해서 grafting 방법과 co condensation 방법을 이용하고 있다. 특히, co-condensation 방법을 이용하여 tetraalkoxysilane 과 organo-trialkoxysilane을 함께 반응시키는 경우, 유기성분의 양을 더욱 증가시킬 수 있고 물질 내부에 균일한 유기성분의 분포를 얻을 수 있다. 메조포러스 무기 network에 fluorine을 포함하는 그룹이 공유결합으로 결합되어져 있는 물질은 소수성, 흡착성 및 광학적으로 응용 가능성을 가질 것으로 기대된다.