• Title/Summary/Keyword: gasfication

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A study on the Dioxin behavior in the process of representative pyrolysis/gasfication/melting plant (대표적인 열분해가스화 용융시설의 공정별 다이옥신 배출거동에 관한 연구)

  • Shin, Chan-Ki;Shin, Dae-Yun
    • Journal of environmental and Sanitary engineering
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    • v.22 no.1 s.63
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    • pp.1-16
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    • 2007
  • The incineration process has commonly used for wastes amount reduction and thermal treatments of pollutants as the technologies accumulated. However, the process is getting negative public images owing to matter of hazardous pollutants emission. Specially dioxins became a main issue and is mostly emitted from municipal solid wastes incineration. In this reason, pyrolysis/gasfication/melting process is presented as a alternative of incineration process. The pyrolysis/gasfication/melting process, a novel technology, is middle of verification of commercial plant and development of technologies in Korea. But the survey about the pollutant emission from the process, and background data in these facilities is necessary. So in this survey, it Is investigated that the behavior of dioxins in three pyrolysis/gasfication/melting plant (S, T, P) of pilot scale. In case of S plant, concentration of dioxins shows high at latter part of cogenerated boiler and stack which are operate on low temperature conditions than a latter parts of pyrolysis and melting furnace which are operate on high temperature condition. Concentration of gas phage dioxins had increased after combusted gas passed cogenerated boiler and this is attributed to react of precursor materials such as chlorobenzene and chlorophenol. Concentration of dioxins in T plant showed lower levels at latter part of cooling equipment which are operate with water spray type on low temperature conditions than a latter parts of gasfied melting furnace which are operate on high temperature condition. Removal efficiency of dioxins at gas treatment equipment was 78.8 %. Concentration of dioxins in P plant was low at latter part of SDA/BF which is operate at low temperature conditions than a latter parts of pyrolysis gasfied chamber which are operate at high temperature condition. Removal efficiency of dioxins of SDA/BF was 85.9 % and therefore, it showed high efficiency at those of stoker type incineration facility. However, concentration of dioxins which emitted at high temperature condition were low in three facilities and satisfied present standard emission level of dioxins. To consider the distribution ratio of dioxins, Particulate phase dioxins at S and P plants showed similar ratio with which shows in current stoker type for middle scale domestic waste incineration facility. It is necessary to continuos monitoring the ratio of distribution of dioxins in T plant in because ratio of gas phage dioxins showed high.

A Room-Corner Fire Model을 적용한 건축내장재의 화재확산 특성 평가(1)

  • Kim, Un-Hyeong
    • Fire Protection Technology
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    • s.24
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    • pp.32-39
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    • 1998
  • A room-corner fire scenario of ISO 9705 with flame spread model developed by Quintiere is applied to the interior finish materials to show the sensitivity of properties derived from AST, E-1321 and ASTM E-1354 is investigated and various range of thermal properties by the author were analyzed in the model. There are including flame heat flux and thermal inertia, lateral flame spread parameter, heat of combustion and effective heat of gasfication. The time for total energy release rate to reach 1MW is examined. Though some areas are neede for improvements, The model appears to predict good results with all the range of input properties and could be

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Initial strength charactistic of Prepacked Grouting Mold with IGCC Ultra-Fine Fly Ash (초고분말 IGCC 플라이애시가 혼입된 프리팩트 그라우팅 몰드의 초기 강도 특성)

  • Lim, Chang-Min;Kwon, Hyun-Woo;Kim, Young-Min;Lee, Gun Chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.23-24
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    • 2022
  • In this study, the Prepacked infilling mortar to which IGCC Ultra-Fine Fly Ash was added was evaluated when grouting aggregates. Efflux, Consistency, and Compressive Strength were measured, and it was found to have high fluidity when mixing IGCC Ultra-Fine Fly Ash, but the initial compressive strength was low

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A Fire Hazard Assessment of Interior Finish Materials (건물 내장재의 화재위험성 평가 방법)

  • 김운형
    • Fire Science and Engineering
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    • v.12 no.2
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    • pp.17-28
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    • 1998
  • To propose a new fire hazard assessment criteria of interior finish materials, the properties and incident heat flux of interior finish materials in a compartment fires are investigated and compared by using flame spread model developed by Quintiere. The properties considered on which fire growth depend are including flame heat flux and thermal inertia, lateral flame spread parameter, heat of combustion and effective heat flux and thermal inertia, lateral flame spread parameter, heat of combustion and effective heat of gasfication. ISO Room Corner Test(9705) is applied in the model and the time for total energy release rate to reach 1MW is examined. The results are compared for the 24 different materials tested by EUREFIC. Dimensionless parameter a, b and ${\gamma}$b are used to develope a new method in which fire hazard of interior finish materials can be classified resulting from correlation between b and flashover time. Results show that if b greater than about zero, flashover time in the ISO Room-Corner Test is principally proportional to ignition time only.

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小型 디이젤機關에 있어서 알코올 利용에 관한 硏究

  • 노상순;허병무
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.11 no.3
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    • pp.386-394
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    • 1987
  • The method of methanol using in diesel engines hasn't been established yet because of it's low ignition characters. But many studies about it with many methods have been doing recently. If alcohol can be used in diesel engines, smoke and NO$\sub$x/, which is a big problem in diesel engines, can be reduced large. The purpose of this study is to establish using method of alcohol, as a substitute fuel. In this study, Combustion characters, engine performance and exhaust gas emissions are checked by using gasfication diesel method. Concluding remarks of this study are as follows. (1) Methanol can be used within 30% of total inducing energy, if above that rate, it can't be used because of knocking and bad operating condition. (2) Under the low load, the effect of methanol inducing of fuel consumption is somewhat bad, but under the high load, the effect is very good. (3) Under the high load, smoke limit is a marked improvement with methanol inducing.

APPLICATIONS OF A MODEL TO COMPARE AFLAME SPREAD AND BEAT RELEASE PROPERTIES OF INFERIOR FINISH MATERIALS IN A COMPARTMENT

  • Kim, Woon-Hyung;James G. Quintiere
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1997.11a
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    • pp.193-200
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    • 1997
  • Flame spread and heat release properties and incident heat flux of interior materials subject to an igniter heat flux in a compartment are investigated and compared by using computer model. A comer fire ignition source is maintained for 10 minutes at 100 kw and subsequently increased to 300kw. In executing the model, base-line material properties are selected and one is changed for each run. Also 4 different igniter heat flux conditions and examined. Results are compared for the 12 different materials tested by the ISO Room Comer Test (9705). The time for total energy release rate to reach 1MW is examined. The parameters considered include flame heat flux and thermal inertia, lateral flame spread parameter, heat of combustion and effective heat of gasfication. The model can show the importance of each property in causing fire growth on interior Hnish materials in a compartment. The effect of ignitor heat flux and material property effects were demonstrated by using dimensionless parameters a, b and Tb. Results show that for b greater than about zero, flashover time in the ISO Room-Corner test is principally proportional to ignition time and nothing more.

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The Process Simulation of Entrained Flow Coal Gasification in Dynamic State for 300MW IGCC (300MW급 IGCC를 위한 건식 분류층 석탄 가스화 공정의 동적 상태 모사)

  • Kim, Mi-Yeong;Joo, Yong-Jin;Choi, In-Kyu;Lee, Joong-Won
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.5
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    • pp.460-469
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    • 2010
  • To develop coal gasfication system, many studies have been actively conducted to describe the simulation of steady state. Now, it is necessary to study the gasification system not only in steady state but also in dynamic state to elucidate abnormal condition such as start-up, shut-down, disturbance, and develop control logic. In this study, a model was proposed with process simulation in dynamic state being conducted using a chemical process simulation tool, where a heat and mass transfer model in the gasifier is incorporated, The proposed model was verified by comparison of the results of the simulation with those available from NETL (National Energy Technology Laboratory) report under steady state condition. The simulation results were that the coal gas efficiency was 80.7%, gas thermal efficiency was 95.4%, which indicated the error was under 1 %. Also, the compositions of syngas were similar to those of the NETL report. Controlled variables of the proposed model was verified by increasing oxygen flow rate to gasifier in order to validate the dynamic state of the system. As a result, trends of major process variables were resonable when oxygen flow rate increased by 5% from the steady state value. Coal flow rate to gasifier and quench gas flow rate were increased, and flow rate of liquid slag was also increased. The proposed model in this study is able to be used for the prediction of gasification of various coals and dynamic analysis of coal gasification.

A Study on the Chlorobenzene and Chlorophenol Behavior in Plasma Type Pyrolysis/Gasfication/Melting Process (플라즈마 방식 열분해 가스화용융시설의 공정별 클로로벤젠 및 클로로페놀 배출거동에 관한 연구)

  • Shin, Chan-Ki;Shin, Dae-Yun;Kim, Ki-Heon;Son, Ji-Whan
    • Journal of environmental and Sanitary engineering
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    • v.22 no.2
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    • pp.9-20
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    • 2007
  • The incineration process has commonly used for wastes amount reduction and thermal treatments of pollutants as the technologies accumulated. However, the process is getting negative public images owing to matter of hazardous pollutants emission. Specially dioxins became a main issue and were mostly emitted from municipal solid wastes incineration. In this reason, pyrolysis/gasification/melting process is presented as an alternative of incineration process. The pyrolysis/gasification/melting process, a novel technology, is middle of verification of commercial plant and development of technologies in Korea. But the survey about the pollutant emission from the process, and background data in these facilities is necessary. So in this survey, t is investigated that the behavior of chlorobenzenes and chlorophenols in plasma type pyrolysis/gasification/melting plant of pilot scale. We investigated discharging behavior of each phase of chlorobenzene through each process in the plsasma type pyrolysis/gasification/melting process. From this result, it was found that about 99 percent of particle-phase chlorobenzene was removed, but on the other hand gas-phase chlorobenzene was increased by about 600 percent through heat exchanger, flue gas cooling, system and semi dry absorption bag filter(SDA/BF). Also, this investigation presented that di-chlorobenzene(DCB) tri-chlorobenzene(TCB), tetra-chlorobenzene(TeCB), penta-chlorobenzene (PCB), except mono-chlorobenzene(MCB) and hexa-chlorobenzene(HCB) were increased through the flue gas cooling system and the semi dry absorption bag filter(SDA/BF). It was investigated that concentration of particle-phase chlorophenol was decreased by about 66 percent, but on the other hand, concentration of gas-phase chlorophenol was increased by about 170 percent through heat exchanger, flue gas cooling system, and semi dry absorption bag filter(SDA/BF). Also, it was found that di-chlorophenol(DCP), tri-chlorophenol(TCP), and penta-chlorophenol(PCP) were increased through the flue gas cooling system, and the semi dry absorption bag filter(SDA/BF). It can be considered that small-scale pilot facility and short investigation period might cause the concentration increase through the flue gas cooling system and the semi dry absorption bag filter(SDA/BF). A further study on real-scale pilot facility and accurate investigation may be required.

A Study on the Validity of Rural Type Low Carbon Green Village Through Case Analysis (사례분석을 통한 농촌형 저탄소 녹색마을 타당성 검토)

  • Do, In-Hwan;Hwang, Eun-Jin;Hong, Soo-Youl;Phae, Chae-Gun
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.12
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    • pp.913-921
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    • 2011
  • This study examined the overall feasibility of low carbon green village formed in rural area. The check method is analyzing its environmental and economic feasibility and energy self-reliance. The biomass of the villages was set as 28 ton/day of livestock feces and 2 ton/day of cut fruit tree branches which make up the total of 30 ton/day. The facility consisted of a bio gasfication facility using wet (livestock feces) biomass and combined heat power generator, composting facility and wood boiler using dry (cut fruit tree branches) biomass. When operating the system, 540,540 kWh/yr of electricity and 1,762 Gcal/yr of heat energy was produced. The region's electricity energy and heat energy self-reliance rate will be 100%. The economic feasibility was found as a loss of 140 million won where the facility installation cost is 5.04 billion won, operation cost is 485.09 million won and profit is 337.12 million won. There will be a loss of about 2.2 billion won in 15 years but in the environmental analysis, it was found that crude replacement effect is about 178 million won, greenhouse gas reduction effect is about 92 million won making up the total environmental benefit of 270 million won. This means, there will be a yearly profit of about 130 million won. In terms of its environmental and economic feasibility and energy self-reliance, this project seemed to be a feasible project in overall even if it manages to get help from the government or local government.