• Title/Summary/Keyword: hybrid film

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Fabrication of Organic-Inorganic Hybrid Thin Film by Molecular Layer Deposition

  • Han, Gyu-Seok;Kim, Su-Hwan;Han, Gi-Bok;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.251-251
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    • 2010
  • Organic-inorganic hybrid materials have attracted because of its combined properties, such as flexibility and high electrical performance. In addition, the hybrid materials are expected to have synergic effect which are not shown in just one component. Here, we fabricated organic-inorganic hybrid thin film. Organic-inorganic hybrid thin film have been deposited from diethyl zinc and 1, 2, 4-trihydroxybenzene (THB) by molecular layer deposition (MLD). UV-VIS, Using Infrared spectrum and X-ray photoelectron spectroscopy confirm that Zinc and THB hybrid film (ZnTHB) consist of Zn-O and THB - oxide units and the micro structure and composition of hybrid film. hat the sequential surface reactions of diethyl zinc and ethylene glycol are sufficiently self-limiting and saturating to enable well-controlled MLD growth. Transmission electron microscopy image shows lamination growth of ZnTHB film according to cycle.

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Film Compensation of Twisted Nematic LC mode using Hybrid Film (하이브리드 필름을 이용한 비틀린 네마틱 액정 모드의 필름보상 연구)

  • Kim, Seong-Su;Hwang, Seong-Han;Kang, Hoon;Lee, Myong-Hoon;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.390-391
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    • 2007
  • We have studied improvement of light leakage of twisted nematic liquid crystal display (TN-LCD) in dark state using the hybrid aligned compensation film made of rod-like LC. When the voltage is applied properly to the TN-LCD, the director tilts up but LC director on the substrate don't tilts up due to surface anchoring energy of the LC cell. Accordingly, LC director from surface to middle LC of TN -LCD become hybrid state such as hybrid aligned film. Consequently, in this paper we achieve wide viewing angle performances of TN mode using developed hybrid aligned film which especially decreases light leakage at vertical direction in dark state.

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Fabrication and characterization of silica-titania hybrid film using silane treated $TiO_2$ sol (실리카-타이타니아 하이브리드 코팅막의 제조 및 특성평가)

  • Han, Dong-Hee;Kang, Dong-Jun;Kim, Suk-Joon;Kang, Dong-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.553-554
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    • 2007
  • By sol-gel method, we have fabricated silica-titania hybrid film using silane treated colloidal $TiO_2$ and characterized the film through FT-IR, TGA, UV-VIS and AFM. The silica-titania hybrid film showed Ti-O-Si chemical bond at FT-IR peak of $910{\sim}940cm^{-1}$. The fabricated hybrid film showed thermal stability of around $350^{\circ}C$(5wt% loss temperature) and transparency more than 90%. In addition, the good surface smoothness was confirmed by AFM. Therefore, the silica-titania hybrid film with outstanding properties can be potential for application in electronics and displays.

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Technology and Application of Hybrid Insulation Film for Electric Magnet Wire (하이브리드 절연필름의 전동기권선 적용 특성 연구)

  • Han, Se-Won;Han, Dong-Hee;Kang, Dong-Phil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.210-211
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    • 2006
  • This study presents the technology and application of hybrid insulation film for electric magnet wire. In order to make the high efficient motor with high space factor, it is necessary to develop a self-lubrication heat-resistant insulation film that can be used when the space factor 70% or more. A key to achieving high windability is to increase the lubricity and bonding strength of vanish, which for a magnet wire generally determines the mechanical scratches characteristics. Effective ways to reduce scratches include improving insulation film prepared by organic and inorganic hybrid synthesis methods.

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The Characterization of ZnO Hybrid Structure Grown by Metal-organic Chemical Vapor Deposition

  • Kim, A-Yeong;Jang, Sam-Seok;Lee, Do-Han;Im, So-Yeong;Byeon, Dong-Jin
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.37.2-37.2
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    • 2011
  • The growth of three-dimensional ZnO hybrid structures by metal-organic chemical vapor deposition was controlled through their growth pressure. Vertically aligned ZnO nanorods were grown on c-plane sapphire substrate at $600^{\circ}C$ and 400 Torr. ZnO film was then formed in-situ on the ZnO nanorods at $600^{\circ}C$ and 10 Torr. High-resolution X-ray diffraction and transmission electron microscopy measurements showed that the ZnO film on the nanorods/sapphire grew epitaxially, and that the ZnO film/nanorods hybrid structures had well-ordered wurtzite structures. The hybrid ZnO structure was shown to be about 5 ${\mu}m$ by field-emission scanning electron microscopy. The hybrid structure showed better crystalline quality than mono-layer film on sapphire substrate. Consequently, purpose of this work is developing high quality hybrid epi-growth technology using nano structure. These structures have potential applicability as nanobuilding blocks in nanodevices.

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THE NEW THICK-FILM HYBRID CONVERTERS FOR HALOGEN AND FLUORESCENT LAMPS

  • Gondek, J.;Dzialek, K.;Kocol, J.;Kawa, B.
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2001.04a
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    • pp.57-65
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    • 2001
  • Economical consumption of energy, longer life of lamps, higher lighting comfort and new aesthetic of illumination is subject of numerous research and development works. The halogen lamps are an example of positive solution some of above mentioned problems. The electronic transformers are more frequent used for their supply. In comparison with conventional transformers they have less weight, less volume and 60% less power tosses. Their advantages are particular visible, when the hybrid technique is applied. The paper presents the results of engineering research and development works carried out ill Private Institute of Electronic Engineering, in R. & D. Center for Hybrid Microelectronics and Resistors and in Technical School of Communications in Krakow, in the field of the design and exploitation tests of hybrid converters 220V AC /12V DC (electronic transformers) and electronic ballasts destined for the supply of halogen lamps 20W to 150W and fluorescent lamps respectively. To perform the converters, thick film technology and surface mount technology were used. For the protection of converter electronic circuit the thick film temperature sensor and transistors were applied. Moreover the paper presents the base application circuits of elaborated converters, their technical parameters and exploitation results. The development perspectives of hybrid domain of hybrid circuits are also discussed.

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Preparation of PEDOT-TiO2 Composite Thin Film by Using Simultaneous Vapor Phase Polymerization (동시-기상중합법을 이용한 Poly(3,4-ethylenedioxythiophene)(PEDOT)-TiO2 하이브리드 박막 제조)

  • Ko, Young Soo;Han, Yong-Hyeon;Yim, Jin-Heong
    • Polymer(Korea)
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    • v.38 no.4
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    • pp.525-529
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    • 2014
  • PEDOT-$TiO_2$ hybrid conductive thin film including semiconductive metal oxide was successfully prepared via simultaneous vapor phase polymerization (VPP). The mechanical properties such as pencil hardness and anti-scratch property as well as optoelectrical properties of PEDOT-$TiO_2$ hybrid thin film could be improved as compared with pristine PEDOT thin film. Physicochemically stable crosslinked $TiO_2$ layer derived from a sol-gel process by FTS was generated in the PEDOT thin film layer by simultaneous VPP, resulting in improving mechanical properties of the hybrid thin films without any deterioration of their original optoelectrical properties. PEDOT-$TiO_2$ hybrid thin film showed better electrical conductivity as compared with PEDOT film. It might be due to the fact that the surface morphology of hybrid thin film prepared by simultaneous VPP showed smoother than that of pristine PEDOT thin film.

Optical and Electrical Properties of ZnO Hybrid Structure Grown on Glass Substrate by Metal Organic Chemical Vapor Deposition (유기금속화학증착법으로 유리기판 위에 성장된 산화아연 하이브리드 구조의 광학적 전기적 특성)

  • Kim, Dae-Sik;Kang, Byung Hoon;Lee, Chang-Min;Byun, Dongjin
    • Korean Journal of Materials Research
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    • v.24 no.10
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    • pp.543-549
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    • 2014
  • A zinc oxide (ZnO) hybrid structure was successfully fabricated on a glass substrate by metal organic chemical vapor deposition (MOCVD). In-situ growth of a multi-dimensional ZnO hybrid structure was achieved by adjusting the growth temperature to determine the morphologies of either film or nanorods without any catalysts such as Au, Cu, Co, or Sn. The ZnO hybrid structure was composed of one-dimensional (1D) nanorods grown continuously on the two-dimensional (2D) ZnO film. The ZnO film of 2D mode was grown at a relatively low temperature, whereas the ZnO nanorods of 1D mode were grown at a higher temperature. The change of the morphologies of these materials led to improvements of the electrical and optical properties. The ZnO hybrid structure was characterized using various analytical tools. Scanning electron microscopy (SEM) was used to determine the surface morphology of the nanorods, which had grown well on the thin film. The structural characteristics of the polycrystalline ZnO hybrid grown on amorphous glass substrate were investigated by X-ray diffraction (XRD). Hall-effect measurement and a four-point probe were used to characterize the electrical properties. The hybrid structure was shown to be very effective at improving the electrical and the optical properties, decreasing the sheet resistance and the reflectance, and increasing the transmittance via refractive index (RI) engineering. The ZnO hybrid structure grown by MOCVD is very promising for opto-electronic devices as Photoconductive UV Detectors, anti-reflection coatings (ARC), and transparent conductive oxides (TCO).

Colloidally stable organic-inorganic hybrid nanoparticles prepared using alkoxysilane-functionalized amphiphilic polymer precursors and mechanical properties of their cured coating film

  • Kim, Nahae;Li, Xinlin;Kim, Se Hyun;Kim, Juyoung
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.209-219
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    • 2018
  • Colloidally stable organic-inorganic (O-I) hybrid nanoparticles could be prepared using an alkoxysilanefunctionalized amphiphilic polymer (AFAP) precursor. O-I hybrid sols could maintain colloidal stability for six months even at 45% solid content and be coated onto glass as well as PET film to form transparent O-I hybrid films. The formation of O-I hybrid nanoparticles dispersed in cured coating films could be confirmed using scanning electron microscopy. The cured coating film showed 3H and 5H pencil hardness on PET and glass, respectively. Nanoindentation measurements also showed that their modulus and hardness was varied with the type of AFAP used in its preparation.

Study on the Characteristics of the Hybrid Parylene Thin Films (하이브리드 타입 패럴린의 박막 특성 연구)

  • Cha, Gook-Chan;Lee, Ji-Yeon;Jung, Seong-Hee;Song, Jeom-Sik;Lee, Suk-Min
    • Elastomers and Composites
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    • v.45 no.4
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    • pp.298-308
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    • 2010
  • The mechanical properties and surface characteristics of parylene thin film were improved using Xylydene-based dimers (DPX-C, DPX-D, and DPX-N). A single-parylene-C, D, N film and a hybrid chemical and physical parylene thin films in which two types are mixed were manufactured for each dimer by adjusting the deposition conditions and the thickness of the thin film by input. Parylene was deposited by chemical vapor deposition (CVD) and the thermal characteristics of the single thin film and the hybrid thin film were compared by thermal analysis. The mechanical properties of the thin films were characterized by tensile strength, elongation, and tear force tests, and the surface characteristics of the thin films were evaluated by contact angle and surface energy measurements. The hybrid chemical parylene thin film in which two types are mixed can complement the strengths and weaknesses of the different dimers, while the physical parylene thin film can freely adjust the thin film characteristics of the coated surface and the opposite surface.