• Title/Summary/Keyword: hydrothermal alteration

Search Result 217, Processing Time 0.029 seconds

K-Ar Age and Geochemistry of Hydrothermal Alteration in the Barton Peninsula, King George Island, Antarctica (남극 킹조지섬 바톤반도의 열수변질작용에 관한 K-Ar 연대와 지구화학)

  • Hur, Soon-Do;Lee, Jong-Ik;Hwang, Jeong;Choe, Moon-Young
    • Ocean and Polar Research
    • /
    • v.23 no.1
    • /
    • pp.11-21
    • /
    • 2001
  • K-Ar ages of the altered rocks from the Barton Peninsula are belows; altered tuffaceous andesite from southwestern part is 42 Ma, altered rocks contacted with quartz vein from southern part are 28 and 33 Ma, and advanced argillic altered andesite from northeastern part are 33 and 35 Ma. Those K-Ar ages are 10 My younger than granitic rocks of the Barton Peninsula. Hydothermal alteration of the Barton Peninsula was originated from mixing of magmatic water from parent magma of granitic rocks with meteoric water. The Al content in the hostrock is relatively constant during hydrothermal alteration, on the contrary the Mg content is in proportion to total alkali. The variation of total alkali and Mg contents in hydrothermal alteration indicates that those elements was washed out during hydrothermal alteration. The sequences of hydrothermal alteration of the Barton Peninsula is chloritization of amphiboles, sericitization of feldspars and kaolitization of sericite.

  • PDF

Spectral Characteristics of Hydrothermal Alteration in Zuru, NW Nigeria

  • Aisabokhae, Joseph;Tampul, Hamman
    • Korean Journal of Remote Sensing
    • /
    • v.35 no.4
    • /
    • pp.535-544
    • /
    • 2019
  • This study demonstrated the ability of a Landsat-8 OLI multispectral data to identify and delineate hydrothermal alteration zones around auriferous prospects within the crystalline basement, North-western Nigeria. Remote sensing techniques have been widely used in lithological, structural discrimination and alteration rock delineation, and in general geological studies. Several artisanal mining activities for gold deposit occur in the surrounding areas within the basement complex and the search for new possible mineralized zones have heightened in recent times. Systematic Landsat-8 OLI data processing methods such as colour composite, band ratio and minimum noise fraction were used in this study. Colour composite of band 4, 3 and 2 was displayed in Red-Green-Blue colour image to distinguish lithologies. Band ratio ${\frac{4}{2}}$ image displayed in red was used to highlight ferric-ion bearing minerals(hematite, goethite, jarosite) associated with hydrothermal alteration, band ratio ${\frac{5}{6}}$ image displayed in green was used to highlight ferrous-ion bearing minerals such as olivine, amphibole and pyroxenes, while ratio ${\frac{6}{7}}$ image displayed in blue was used to highlight clay minerals, micas, talc-carbonates, etc. Band rationing helped to reduce the topographic illumination effect within images. The result of this study showed the distribution of the lithological units and the hydrothermal alteration zone which can be further prospected for mineral reserves.

Oxygen isotope study on the hydrothermal alteration in the Wolf River Batholith, Wisconsin in U.S.A

  • Kim, Sun-Joon
    • The Journal of the Petrological Society of Korea
    • /
    • v.2 no.1
    • /
    • pp.19-31
    • /
    • 1993
  • Oxygen isotope compositions of whole rock and/or mineral separates (quartz and feldspar) have been determined for the granitic and related rocks from the Wolf River Batholith, Wisconsin. Hydrothermal alteration resulting in the decrease of ${\Delta}_{Q-F}$/ values was obaserved locally throughout the batholith. Feldspars of different colors (pink, gray and red) were separated whenever feasible and analyzed. Most red feldspars (An$_{10-30}$/) show the highest and constant ${\delta}^18O$/ values (9.3~10.0 permil) suggesting nearly complete isotope exchange with hydrothermal fluid. Based on ${\delta}^18O$/ values and the alteration temperatures (260~$350^{\circ}C$) estimated from fluid inclusion study, ${\delta}^18O$/ of fluid is calculated to be $5.0{\pm}1.4$ permil. Phanerozoic sedimentary formation water in Wisconsin is most likely the source of the fluid.

  • PDF

Hydrothermal Solution-Rhyolite Reaction and Origin of Sericitite in the Yukwang Mine (유문암-열수 반응과 유광 견운모 광상의 성인)

  • Park, Maeng-Eon;Choi, In-Sik;Kim, Jin-Sup
    • Economic and Environmental Geology
    • /
    • v.25 no.3
    • /
    • pp.225-232
    • /
    • 1992
  • The hydrothermal alteration is evaluated using multicomponent equilibrium calculations with the program CHILLER for the reactions between hydrothermal water and rhyolite at the temperature of $300^{\circ}C$ and pressure of 500 bars. The chemical-reaction model on the depositional processes of the sericitite confirms that the hydrothermal water-rock interaction(hydrothermal alteration) is the main mechanism of the sericitite formation. The principal change in the aqueous phase during the reaction is the pH increase. Overall trends for the major species are the increase in total molalities of K, Ca, $SiO_2$, Al, Mg, Fe, Na, and sulfide in solid phase with hydrothermal water-rhyolite reaction and the decrease of them in aqeous solution by precipitation of hydrothermal products. Quartz and sericite are the first minerals to form. The sequence of minerals to precipitate following them is chlorite, epidote, pyrite and microcline as water/rock ratio decreases. Although calculated results cannot duplicate the complexities of natural hydrothermal alteration, the calculation provides thermodynamic constraints on the natural process. The calculation results resemble those of experimental studies. Sericitite forms where pH decreases and water/rock ratio increases.

  • PDF

Anaysis of Fe in Seepage Water and Precipitates around a Hydrothermal Alteration Zone

  • Yun, Hyun-Seok;Moon, Seong-Woo;Lee, Jin-Kook;Jeong, Gyo-Cheol;Seo, Yong-Seok
    • The Journal of Engineering Geology
    • /
    • v.27 no.3
    • /
    • pp.345-351
    • /
    • 2017
  • Acid drainage in civil engineering structures such as tunnels may lead to the deposition of precipitates that clog drainage channels and pipework. In evaluating acid drainage, the Fe content of water and precipitates, indicated by reddish brown coloration of rock surfaces, rivers, and soils, may be an important factor. In this study, acid drainage was evaluated by analyzing the Fe content of reddish brown seepage water that occurred in part of a tunnel. Geological investigations around the tunnel revealed a hydrothermal alteration zone cutting the bedrock, and cropping out in the upper parts of the tunnel. Analysis of drillcore revealed many fracture zones and veins. Inductively coupled plasma spectrophotometric analyses of water, precipitates, and soil samples, collected in the seepage water zone and around the tunnel, were conducted to evaluate acid drainage. The Fe content of seepage water in the tunnel was 0.030-0.333 mg/kg, which is 2-22 times higher than in local groundwater. The Fe content of precipitates in the tunnel was 165,403-301,051 mg/kg, similar to the 206,167-422,964 mg/kg content of drillcore from the hydrothermal alteration zone located above the tunnel. It is concluded that the seepage water is derived from Fe-containing acid drainage flowing in perforated tunnel drainpipes along the fracture zones and veins around the hydrothermal alteration zone.

Geochemical Variation of Hwangsan Volcanic Complex by Large Hydrothermal Alteration (대규모 열수변질작용에 따른 황산 화산암복합체의 지구화학적 변화특성)

  • Kim, Eui-Jun;Hong, Young-Kook;Chi, Se-Jung
    • Economic and Environmental Geology
    • /
    • v.44 no.2
    • /
    • pp.95-107
    • /
    • 2011
  • The Hwangsan volcanic rocks, hosting the Moisan epithermal Au-Ag deposit arc widely distributed throughout the Seongsan district, and associated with large hydrothermal alteration. They were analyzed as the Moisan and around voleanic rocks, and most of them show dacitic to rhyolitic compositions. Hydrothermal alteration related to epithermal system causes the host rocks to show the geochemical variation due to high mobility of alkali elements. These features can be applied for quantitative estimates of alteration intensity. Alteration intensity of volcanic rocks from the Moisan ranges from subtle to intense, based on AI vs. $Na_2O$ diagram. The pattern that ($CaO+Na_2O$) content decrease with increasing $K_2O$ content results from sericitic alteration, in which hydrothermal fluids continually provide $K^+$ into country rocks but remove $Ca^{2+}$ and $Na^{2+}$ of feldspars within country rocks. The decrease of ($CaO+Na_2O$) with decreasing $K_2O$ in some samples from the Moisan may be caused by advanced argillic alteration that all alkali elements are entirely removed from country rocks by acid hydrothermal fluids. Two alteration trends, based on Al and CCPI alteration indices suggest both sericitic alterations of feldsaprs to illite and sericite+chlorite$^{\circ}{\ae}$pyritc alteration of high Mg and Fe activities. Trace and Rare Earth Elements patterns show the similar geochemical variation related to hydrothermal alteration. Of LIL elements, strong depletion of $Sr^{2+}$, substituting for $Ca^{2+}$ in feldspars, appears to be resulted from removal of $Ca^{2+}$, during replacement of feldspars to alumino-silicates or phyllo silicates minerals by hydrothermal fluids. Relatively low total REEs contents (Moisan: 119-182 ppm; Seongsan: 111-209 ppm) and gently negative slopes suggest that significant mobility of LREEs appear to occur during hydrothermal alteration.

Genesis of the Lead-Zinc-Silver and Iron Deposits of the Janggun Mine, as Related to Their Structural Features Structural Control and Wall Rock Alteration of Ore-Formation (장군광산(將軍鑛山)의 연(鉛)·아연(亞鉛)·은(銀) 및 철(鐵) 광상(鑛床)의 성인(成因)과 지질구조(地質構造)와의 관계(關係) - 광상(鑛床) 생성(生成)의 지질구조(地質構造) 규제(規制)와 모암(母岩)의 변질(變質) -)

  • Lee, Hyun Koo;Ko, Suck Jin;Naoya, Imai
    • Economic and Environmental Geology
    • /
    • v.23 no.2
    • /
    • pp.161-181
    • /
    • 1990
  • The lead-zinc-silver-iron deposits from the Janggun mine are of hydrothermal-metasomatic origin, characterized by the marked hydrothermal alteration of the wallrocks, such as hydrothermal manganese enrichment of carbonate rocks, silicification, chloritization, sericitization, montmorillonitization and argillic alteration. The ore deposits have been emplaced within the Janggun Limestone of Cambro-Ordovician age at the immediate contacts with apophyses injected from the Chunyang Granite plutons of Late Jurrasic age. They have been structurally controlled by fractures in the carbonate rocks and the irregular intrusive contacts of granitic rocks, and are closely associated with hypogene manganese carbonate deposits. In the mine nine seperate orebodies are being mined. On the basis of the petrological study, hydrothermal alteration zone of this mine may be divided into the following four zones from wallrock to orebody. (I) Primary calcite and dolomite zone${\rightarrow}$(II) dolomitic limestone zone${\rightarrow}$(III) dolomitic zone${\rightarrow}$(IV) rhodochrosite zone${\rightarrow}$ orebody. There was not recongnized Mn and Fe elements in the primary calcite and dolomite zone. But, in the dolomitic limestone and dolomite zone, calcite and dolomite were subjected to weak hydrothermal manganese enrichment and the grade of the manganese enrichment increase oreward. By means of electron probe microanalysis, it was found that manganoan dolomite occured between primary dolomite grains, cross the cleavage of the primary dolomite and around the dolomite grains. Above these result supports that the Janggun manganese carbonate deposits are of hydrothermal metasomatic origin.

  • PDF

Comparative Anatomy of the Hydrothermal Alteration of Chonnam and Kyongsang Hydrothermal Clay Alteration Areas in Korea (전남 및 경상 열수변질 점토광상의 생성환경 비교)

  • Koh, Sang Mo;Chang, Ho Wan
    • Economic and Environmental Geology
    • /
    • v.30 no.2
    • /
    • pp.81-87
    • /
    • 1997
  • Chonnam and Kyongsang clay alteration areas are distributed in volcanic fields of the Yuchon Group in late Cretaceous period. The host rock of the Chonnam alteration area is generally acidic and that of the Kyongsang alteration area is acidic to dominantly intermediate volcanics. The important difference of two alteration areas is source of fluid; the Chonnam alteration area is characterized by dominantly meteoric water and the Kyongsang alteration area is characterized by dominantly magmatic water. Accordingly, the high temperature minerals such as pyrophyllite and andalusite, and boron bearing minerals such as dumortierite and tourmaline are common in the Kyongsang alteration area. In contrast to this, the lower temperature minerals such as kaolin and alunite are common in the Chonnam alteration area. The mineralogical difference of two alteration areas were depended on the difference of the formation temperature of clay deposits. The other important geochemical difference is the chemistry of hydrothermal solution such as pH. The alteration of "acid-sulfate type" with alteration mineral assemblage of alunite-kaolin-quartz is dominant in the Chonnam alteration area, which was caused by the attack of strong acid and acid solution. In contrast to this, the that of "quartz-sericite type" with the mineral assemblage of sericite-quartz is dominant in the Kyongsang alteration area, which was caused by the attack of neutral or weak acid solution. Also, the Kyongsang and Chonnam alteration areas show the difference in structural setting; the Chonnam alteration area is commonly associated with silicic domes and the Kyongsang alteration area is commonly associated with calderas.

  • PDF

열수변질 점토맥과 산사태

  • Jo, Hwan-Ju;Jeong, Gyeong-Mun;Jo, Ho-Yeong
    • Mineral and Industry
    • /
    • v.29
    • /
    • pp.56-66
    • /
    • 2016
  • In Korea, where hydrothermal alteration zones are widely distributed, clay veins formed by hydrothermal alteration processes on natural slopes or artificial slopes can play an important role in the slope stability. When the surface water infiltrates the ground where the clay vein exists, the pore water pressure in the ground can be locally increased due to impermeable properties of clay minerals. Infiltration of the surface water induces the increase in the pore water pressure, which can cause erosion of the fine clay particles. The eroded clay particles flow and deposit in an area where the flow velocity is slowed down. Where clay minerals are deposited, ground water can leak due to an increase in local pore pressures, which can cause slope failure. In this paper, studies related to hydrothermal clay vein and landslide are introduced.

  • PDF