• Elastomers and Composites
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• v.48 no.2
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• pp.172-179
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• 2013

Impact modifier reinforced polymers are frequently used. In this study, Izod impact test has been simulated to analyze the mechanism of impact reinforcement of Nylon6 which contains impact modifier. The modeling of rubber particles added to Nylon6 as an impact modifier has been attempted. Based on the modeling, simulation of Izod impact test has been performed to observe the distribution and direction of stress at the cross-section of impact specimen. Three computer simulation models for Nylon6 were investigated. Those were without impact modifier, containing impact modifier without surface treatment, and containing impact modifier with surface treatment in the Nylon6. Simulation results showed that the stress which originated at the notch surface propergated to the inside of specimen round a impact modifier. In addition to that, impact modifier reinforced Nylon6 specimen showed low stress ditribution in the cross-section specially at notch surface. Principal stress in perpendicular direction to crack was also lowered in impact modifier reinforced Nylon6. These enhanced impact resistance reduced and crack propergations. Through this study it was realized that the computer simulation can be utilized to investigate the property enhacement of composite materials.

• Elastomers and Composites
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• v.49 no.4
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• pp.284-292
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• 2014

Polymer has low mechanical strength than metal. In particular, the impact strength is very weak. Impact modifier reinforced polymers are frequently used. Impact strength of reinforced polymer is changed according to content and distribution of impact modifier. In this study, izod impact test has been simulated to analyze the mechanism of impact modifier reinforced Nylon 6. Computational results were compared for numbers and distributions of impact modifier. As the total volume of rubber particles decreased, the stress at the notch increased for the simulation model that the volume decreases as particle number increases. As the surface area of particle sphere increased, the stress and difference of principle stress increased for the simulation model that the total surface increases as particle number increases.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.7
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• pp.4081-4086
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• 2014

Cellulose acetate butyrate (CAB) is a biodegradable resin with excellent optical properties, but it is difficult to apply film process. In this study, an attempt was made to improve the processability of CAB using polyactic acid and the mechanical properties using an impact modifier. Polylacitc acid (PLA)/Cellulose acetate butyrate (CAB) blends with an impact modifier were prepared using a twin screw extruder. The temperature range was $140^{\circ}C$ to $200^{\circ}C$, and the screw speed was fixed to 200 rpm. To evaluate the miscibility of impact modified CAB/PLA, the glass transition behavior and morphology were observed by DSC and FE-SEM. The mechanical properties were investigated by dynamic mechanical analysis (DMA) and a Universal Testing Machine (UTM). In addition, the effect of an impact modifier in the polymer matrix was determined using a notched Izod impact strength tester. Finally, the PLA/CAB/impact modifier 75/25/10 ratio was found to be a compatible system. In the 10wt.% impact modifier, the sample had a 4 times higher izod impact strength than the non-toughening composition.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.2
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• pp.919-925
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• 2012

We tried to blend PLLA and PDLA at overall compositions to form PLA stereocomplexes (SC). The presence of the SC crystalline phase in the PLLA matrix was verified by differential scanning calorimetry (DSC). As a result, a various PDLA composition of the PLA SC blends can influence PLA SC formation. And the largest amount of PLA SC crystallites was formed when PLLA/PDLA ratio is 50/50. In addition, we have tried to do PLA SC toughening with two impact modifiers in 92/8, 85/15 ratio of PLLA/PDLA to enhance the mechanical properties such as impact strength. Thermal and mechanical properties of PLA SC were investigated by DSC, HDT, Izod impact tester and UTM. PLA SC formation decreased when 10-20 wt% of Strong120 (impact modifier) was added. On the other hand, there is no effect on PLA SC formation when 10-20% of Elvaloy (impact modifier) was added. HDT values dramatically increased over $100^{\circ}C$ with the addition of PDLA. However, HDT decreased as Strong120 and Elvaloy content increased. Finally, we could find well balanced composition of toughened PLA SC with 10wt% of impact modifier in flexural modulus and impact strength.

• Elastomers and Composites
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• v.28 no.4
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• pp.283-292
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• 1993

The morphology and impact strength of alloys of high density polyethylene(HDPE) and nylon-6(PA) with modified $ethylene-{\alpha}-olefin$ copolymer(OCP) as compatibilizer and impact modifier were measured by the scanning electron microscope(SEM) and the notched Izod impact test(and the high rate impact test), respectively. HDPE is incompatible with PA and specimens obtained from simple mechanical mixing show the inferior properties. However, it was indicated that OCP played roles of not only impact modifier but also compatibilizer. High rate impact test results were different from those of the notched Izod impact test, but in both tests OCP was effective for HDPE/PA blends. From SEM observation, the size of the dispersed phase in alloys prepared with OCP is much smaller than that of alloys without OCP and the interfacial adhesion of alloys prepared with OCP is also better. Toughening mechanism of polymer blends was discussed by combining the morphology analysis with mechanical and thermal properties.

• Journal of the Semiconductor & Display Technology
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• v.11 no.2
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• pp.75-80
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• 2012

Polymer composites which have electrical properties have been studied in various industries. The Multi-walled carbon nanotube (MWCNT) are thought to be reinforcements for polymers because of their high aspect ratio and specially mechanical, thermal and electrical properties. We introduced MWCNT and impact modifier in order to improve thermal and mechanical properties of Polyphenylene sulfide (PPS) and give electric characteristic to PPS. The thermal properties were investigated by Differential scanning calorimeter (DSC) and Thermogravimetric analysis (TGA). The morphology, mechanical properties and electrical characteristic were performed by Field emission scanning electron microscopy (FE-SEM), Izod impact tester and surface resistance meter. As a result, we could find that the PPS/MWCNT composites have high conductivity and good mechanical properties than neat PPS resin.

• Polymer(Korea)
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• v.26 no.2
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• pp.237-244
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• 2002

Mechanical properties, flow characteristics and chemical resistance of polycarbonate (PC)/polybutylene terephthalate (PBT) /impact modifier (IM) blends were investigated over the various composition ranges of PC and PBT. Mechanical properties of the PC/PBT/IM blends for different IMs, butadiene based IM and butyl acrylate based IM, were studied for various compositions of the IMs. Impact strength at low temperature was also observed. For the study of chemical resistance of the PC/PBT/IM blends, the blonds were dipped in organic solvent, thinner, and then variations of mechanical properties were analyzed. Tensile and flexural strengths were increased linearly and heat distortion temperature (HDT) also increased as PC content in the blends increased. Impact strength increased drastically as PC content increased up to 50 wt% and stayed stable value. Flowability decreased as PC content increased. Impact strengths of the blend were various for different IMs. Butyl acrylate based IM showed slightly higher impact strength than butadiene based IM for the temperature above $0^{\circ}C$. However, butadiene based IM showed remarkably higher impact strength than butyl acrylate based IM for the temperature below $0^{\circ}C$. Through the experiment of chemical resistance it was observed that tensile and flexural strengths decreased, and impact strength increased as PC content in the blends increased. PC in the blend would become mild and ductile when it contacted with organic solvent. Thus the impact strength increased while tensile and flexural strength decreased.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.44 no.5
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• pp.39-45
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• 2012

For a fundamental study for high concentration pigment coating, the effects of alkali swellable emulsion (ASE) type rheology modifier and surface adsorption emulsion (SAE) type rheology modifier on both the stability and the viscoelastic behavior of a coating color were elucidated. The coating color prepared with SAE type rheology modifier showed superior thermal and mechanical stability than that with ASE type. In the high concentration and high speed coating process, the mechanical stability of a coating color was a key parameter since both impact force and shear force were increased with the increase of coating color concentration and coating speed, respectively.

• The Korean Journal of Rheology
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• v.9 no.4
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• pp.151-162
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• 1997

다층 구조를 갖는 고무/아크릴 충격보강제가 poly(methyl methacrylate) (PMMA)/ 충격보강제 블렌드의 몰폴로지와 유변학적 성질에 미치는 영향을 고찰하였다. TEM으로 측 정한 블렌드 내의 충격보강제 몰폴로지는 그 함량에 관계없이 균일한 크기의 구형을 이루는 것으로 나타났으며 파괴 단면의 SEM 측정으로부터 충격보강제와 매트릭스 수지와의 강한 결합력을 확인할수있었다. 블렌드의 유변물성 측정 실험에서는 충격보강제 함량이 복합 점 도에 크게 영향을 준 반면, capillary rheometer로부터 얻은 정상상태 점도에는 별 영향을 주지않음이 확인되었다. 특히 동적응력 실험의 고진동 주파수 영역에서는 일정 충격보강제 함량이상 일 때 충격보강제 자체의 점도와 근사해졌으며 이와같은 현상을 충격보강제의 shell 분자 상호간 또는 매트릭스 분자와의 엉킴에서 비롯되는 물리적인 상호 작용측면에서 설명해보았다. 또한 실험 결과를 Palierne[16]의 비상용성 블렌드계의 이멀젼 모델과 비교한 결과 상당한 차이를 확인할수 있었으며 이러한 차이는 위에서 언급한 shell 분자 상호간 또 는 매트릭스 분자와의 엉킴에 기인한다고 추정된다.

• Elastomers and Composites
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• v.45 no.2
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• pp.129-136
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• 2010

In this work, PLLA/EGMA blends were prepared by melt blending of biodegradable Poly-L-lactic acid(PLLA) with Poly(ethylene-co-glycidyl methacrylate)(EGMA) and Engage as impact modifiers by twin screw extruder. Blend compositions of PLLA/Impact modifier blends were 100/0, 75/25, 50/50, 25/75 and 0/100, respectively. Also, Talc was added to 3 PLLA rich phases on PLLA/EGMA blends. The morphology, viscoelastic/mechanical properties were characterized by FESEM, DMA, UTM and Izod impact tester. DMA and Izod impact test data showed that storage modulus at room temperature with increasing EGMA and Engage contents decreased, and impact strength increased. However, storage modulus at room temperature increased by adding talc. From FESEM image, we observed that domain phase was well dispersed into matrix. Although the tensile strength and flexural modulus were decreased with increasing the content of EGMA and Engage in them, they could be supplemented by adding talc.