• 제목/요약/키워드: iron state

검색결과 397건 처리시간 0.034초

Aerosol Synthesis and Growth Mechanism of Magnetic Iron Nanoparticles

  • Tolochko, O.V.;Vasilieva, E.S.;Kim, D.;Lee, D.W.;Kim, B.K.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.446-447
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    • 2006
  • Magnetic oxide-coated iron nanoparticles with the mean size ranging from 6 to 75 nm were synthesized by aerosol method using iron carbonyl as a precursor under the flowing inert gas atmosphere. Oxide shells were formed by passivation of asprepared iron particles. The influence of experimental parameters on the nanoparticles' microstructure, phase composition and growth behavior as well as magnetic properties were investigated and discussed in this study.

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Effect of Batch Melting Temperature and Raw Material on Iron Redox State in Sodium Silicate Glasses

  • Mirhadi, Bahman;Mehdikhani, Behzad
    • 한국세라믹학회지
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    • 제48권2호
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    • pp.117-120
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    • 2011
  • In this study, the redox state of iron in sodium silicate glasses was varied by changing the melting conditions, such as the melting temperature and particle size of iron oxide. The oxidation states of the iron ion were determined by wet chemical analysis and UV-Vis spectroscopy methods. Iron commonly exists as an equilibrium mixture of ferrous ions, $Fe^{2+}$, and ferric ions $Fe^{3+}$. In this study, sodium silicate glasses containing nanoparticles of iron oxide (0.5% mol) were prepared at various temperatures. Increase of temperature led to the transformation of ferric ions to ferrous ions, and the intensity of the ferrous peak in 1050 nm increased. Nanoparticle iron oxide caused fewer ferrous ions to be formed and the $\frac{Fe^{2+}}{Fe^{3+}}$ equilibrium ratio compared to that with micro-oxide iron powder was lower.

Generation of Free Radicals by Interaction of Iron with Thiols in Human Plasma.

  • Lee, S. J.;K. Y. Chung;J. H. Chung.
    • 한국식품위생안전성학회:학술대회논문집
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    • 한국식품위생안전성학회 2002년도 춘계학술발표대회 및 심포지움
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    • pp.138-138
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    • 2002
  • Oxidative stress has been associated with a number of diseases in human. Among the sources that can generate oxidative stress, it has been reported that iron can generate reactive oxygen species (ROS)with thiol. In iron overload state, increased thiol levels in plasma appeared to be associated with human mortality. In this study we examined whether iron could interact with thiols in plasma, generating ROS. In human plasma, unlike with Fe(III), Fe(II) increased lucigenin-enhanced chemiluminescence in concentration-dependent manner, and this was inhibited by SOD. Boiling of plasma did not affect chemiluminescence induced by Fe(II). Hovever, thiol depletion in plasma by pretreatment with N-ethylmaleimide (NEM)decreased Fe(II)-induced chemiluminescence significantly, suggesting that Fe(II) generated superoxide anion by the nonenzymatic reaction with plasma thiol. Consistent with this findings, albumin, the major thiol contributor in plasma, also generated ROS with Fe(II) and this generation was inhibited by pretreatment with NEM. Treatment with Fe(II) to plasma resulted un significant reduction of oxygen radical absorbance capacity (ORAC) value, suggest that total antioxidant capacity could diminished in iron overload state. In conclusion, In iron overload state, plasma may be affected by oxidative stress mediated by nonenzymatic reaction of Fe (II)with plasma thiol.

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Expression and Purification of Intact and Functional Soybean (Glycine max) Seed Ferritin Complex in Escherichia coli

  • Dong, Xiangbai;Tang, Bo;Li, Jie;Xu, Qian;Fang, Shentong;Hua, Zichun
    • Journal of Microbiology and Biotechnology
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    • 제18권2호
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    • pp.299-307
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    • 2008
  • Soybean seed ferritin is essential for human iron supplementation and iron deficiency anemia prevention because it contains abundant bioavailable iron and is frequently consumed in the human diet. However, it is poorly understood in regards its several properties, such as iron mineralization, subunit assembly, and protein folding. To address these issues, we decided to prepare the soybean seed ferritin complex via a recombinant DNA approach. In this paper, we report a rapid and simple Escherichia coli expression system to produce the soybean seed ferritin complex. In this system, two subunits of soybean seed ferritin, H-2 and H-1, were encoded in a single plasmid, and optimal expression was achieved by additionally coexpressing a team of molecular chaperones, trigger factor and GroEL-GroES. The His-tagged ferritin complex was purified by $Ni^{2+}$ affinity chromatography, and an intact ferritin complex was obtained following His-tagged enterokinase (His-EK) digestion. The purified ferritin complex synthesized in E. coli demonstrated some reported features of its native counterpart from soybean seed, including an apparent molecular weight, multimeric assembly, and iron uptake activity. We believe that the strategy described in this paper may be of general utility in producing other recombinant plant ferritins built up from two types of subunits.

스테인리스강-주철 이중복합관의 제조개발에 관한 연구 (Fabrication Development of Stainless Steel - cast Iron Dual Tube)

  • 최상호;강춘식
    • 한국주조공학회지
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    • 제8권4호
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    • pp.429-436
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    • 1988
  • The influences of some casting conditions on bonding ratio and state at bonding zone of stainless steel-cast iron dual tube produced by centrifugal casting process were investigated to estimate fabrication technics. 1) Bonding ratio is increasing such as increasing of inner surface temperature of outer metal(stainless steel STS 304), if pouring temperature of inner metal (cast iron) is constant. 2) The more pouring temperature of inner metal (cast iron) increase, the more bonding ratio increase when inner surface temperature of outer metal (cast iron) is constant. 3) As the mold rotary speed is increase, the hatching area of bonding map (perfect bonding area) goes down to the low pouring temperature of inner metal. 4) In order to predict bonding state of two different metal, we are able to make and use the bonding map about casting conditions such as inner surface temperature of outer metal, pouring temperature of inner metal and mold rotary speed.

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Three-poles Touch-type Corrosion Sensor for Edge Detection of Initial State of Iron Rust

  • Yonemoto, Naruto;Shida, Katsunori
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1998년도 제13차 학술회의논문집
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    • pp.308-311
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    • 1998
  • Some nondestructive diagnostic methods including various types of corrosion sensors have been investigated. Under these conditions, a new structure of sensor that has a pair of electrode and magneto-supply was proposed. In order to detect the edge of the iron rust part, three-poles touch-type corrosion sensor is now proposed. The iron rust pattern where the sensor touches is estimated by means of the impedance of the sensor, and the edge of the iron rust is recognized by comparing the three measured impedances. As the result, our proposed sensor is useful to detect the initial state of iron rust.

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국산 Kaolin 광물에 수반된 철화합물의 종류 및 존재상태 구명에 관한 연구 (A Study on Iron Compounds Accompanied in Korean Kaolin Minerals)

  • 박금철;최석진;박영갑
    • 한국세라믹학회지
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    • 제11권2호
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    • pp.22-30
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    • 1974
  • This study was carried out to investigate the species of iron compounds in kaolin mineral and the bonding relation between the major kaolin and its subordinate iron compound existing as incidental mineral in common clay by means of chemical composition, X-ray diffraction, thermal differential and thermogravimetrie analysis for the application of clays in the field of ceramic raw material. The domestic clay are produced abounduntly in many places, but San-Cheong kaolin, Chu-An clay, and Yeong-Am clay were selected as samples in this experiment because of their frequent utilization in porcelain industry. Two kinds of samples with low and high iron content are picked up respectively from the place of production and elutriated under two micron size to determine the properties and concentration of iron compound very fine particles or colloidal substance of low crystalline grade. Therefore, hydrothermal treatment in autoclave was conducted considering the existence of low crystalline grade of iron compounds known as an amorphoue state in X-ray diffraction pattern furthermore, de-iron treatment of hydrothermal compound was done in order to identify the related iron compound before and after hydrothermal reaction and iron compound which is one of the samples was synthesized for the determination of their compounds state in more detail. The obtained results in this study are as follows: In San-Cheong kaolin, Chu-An clay and Yeong-Am clay 1) It is proved that species accompanying iron compound is $\alpha$-FeOOH form. 2) Iron compound is composed of very fine particles or colloidal substance. 3) The iron substance encircles the fine parts of clay minerals under 2 micron and acts as cementizing agent.

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Application of Gossypol Acetic Acid as a Reagent For Iron (Iii) Ions

  • U. K. Abdurakhmanova;M. R. Askarova;H. K. Egamberdiev
    • 대한화학회지
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    • 제68권1호
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    • pp.20-24
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    • 2024
  • This article presents the advantages of utilizing gossypol and its derivatives as reagents for iron (III) (Fe (III)) ions. A novel spectrophotometric method has been developed for the determination of Fe (III) using gossypol derivatives in the presence of a universal buffer solution. Optimal conditions have been identified, and the composition and stability constants of the Fe (III) complex with gossypolacetic acid have been determined.

Chitosan-Iron casein succinylate nanoparticles as oral delivery systems: increasing the stability and enhancing the absorption of iron nanoparticles.

  • Cho, Jung-Hye;Oungbho Kwunchit;Park, Jeong-Sook;Kim, Chong-Kook
    • 대한약학회:학술대회논문집
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    • 대한약학회 2003년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2-2
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    • pp.249.1-249.1
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    • 2003
  • The objective of the study was to develop an oral delivery system to increase the stability and efficacy of iron casein succinylate. Aqueous nanoparticles were prepared using complex coacervation of the oppositely charged chitosan and iron casein succinylate with polyethyleneglycol (PEG). The physicochemical properties of nanoparticles were investigated using dynamic light scattering, zeta potential and scanning electron microscopy. Chitosan-iron casein succinylate interactions were investigated in solid state by differential scanning calorimetry (DSC) and FT-IR spectrometry. (omitted)

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