• Bulletin of the Korean Chemical Society
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• v.16 no.5
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• pp.422-427
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• 1995

In a stream of water sample, trace metal ions are quantitatively coprecipitated with Indium hydroxide and filtered. The filtered precipitate is continuously dissolved in 3 M nitric acid and introduced to ICP directly. The lead, cadmium, and copper are concentrated more than 10-fold and determined with ICP-AES at a sampling frequency of 10/hour. The detection limits are 2.89, 1.43,0.52 ppb for lead, cadmium, and copper respectively. Recoveries of lead, cadmium, and copper are 98.7, 94.3, and 104.5% respectively. The RSD values for three elements are about 3-5% currently.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.7 no.2
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• pp.233-244
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• 1997

In order to investigate the concentration of trace metals in human hairs from residents living in urban area and rural area, the 120 hair samples of adults were taken from urban areas(industrial area, bus terminal, downtown area) and rural area(Kasan-ri, Yeoju-up, Yeoju-goon) during July - September 1995. Mean concentrations of trace metals including lead and cadmium in human hair were compared by region, sex, presence of smoker, type of water, period of residence. The results were as follows; 1. The average concentrations of lead and cadmium in hairs of urban area are $0.92{\mu}g/g$ ($1.01{\mu}g/g$ industrial area, $1.01{\mu}g/g$ bus terminal, $0.74{\mu}g/g$ downtown area), $0.38{\mu}g/g$ ($0.54{\mu}g/g$ industrial area, $0.49{\mu}g/g$ bus terminal, $0.12{\mu}g/g$ downtown area). The mean concentrations of lead and cadmium in urban area are higher than the corresponding levels in the rural area. 2. Lead concentration for male in the urban and rural area is 0.94 and $0.62{\mu}g/g$, 0.90 and $0.60{\mu}g/g$ for female. But, It does not have any statistical significance. Cadmium concentration for male in the urban and rural area is 0.38 and $0.12{\mu}g/g$, 0.38 and $0.11{\mu}g/g$ for female. But It does not have any statistical significance. 3. Mean concentrations of lead and cadmium in smokers shows higher than non-smokers. It showed that the longer period of residence in urban area, the higher concentrations of three metals.

• Journal of the Korean Ceramic Society
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• v.51 no.5
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• pp.472-476
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• 2014

In this work, a new method that utilizes L-cysteine salicylaldehyde Schiff-base modified macroporous polystyrene resin (PS-CSC) as an effective sorbent has been developed for preconcentration of trace cadmium and lead in environmental water samples. The effect of pH, the contact time, the elution conditions, the flow rate, the initial concentration of target metal ions, and the effects of interfering ions on the preconcentration of the analytes were investigated. The maximum adsorption capacity of PS-CSC under optimum conditions for cadmium and lead were found to be 6.03 - 18.17 mg/g and 12.58 - 36.13 mg/g when the initial concentration of metal ions between 5.0 - 90 mg/L. The limits of detection for cadmium and lead were 2.46 ng/L and $0.52{\mu}g/L$, with a preconcentration factor of 200. The developed method has been validated by analyzing certified reference material and successfully applied for the enrichment and determination of trace cadmium and lead from environmental water samples.

• Journal of the Korean Society of Food Science and Nutrition
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• v.30 no.1
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• pp.32-36
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• 2001

This study was conducted to estimate the contents of trace metals in vegetable which were produced in Korea. The levels of trace metals determined using a mercury analyzer, and ICP (inductively coupled plasma spectrometer) and an AAS (atomic absorption spectrophotometer) after wet digestion. The values of trace metals [minimum~maximum (mean), mg/kg] in vegetables were a follows ; Hg : 0.0001~0.019 (0.002), Pb : 0.001~0.28 (0.02), Cd : 0.001~0.078 (0.016), As : 0.001~0.06 (0.02), Cu : 0.06~24.81 (0.77), Mn : 0.17~15.12 (2.32), Zn : 0.13~28.70 (2.51). These results showed that metal contents in vegetables on domestic markets were similar to those reported in other countries. The weekly average intakes of lead, cadmium and mercury from vegetables take 2~7% of PTWI (Provisional Tolerable Weekly Intakes) that the FAO/WHO Joint Food Additive and Contaminants Committee had set to evaluate their safeties.

• Journal of Environmental Science International
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• v.23 no.6
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• pp.995-1001
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• 2014

When relations improve between North and South Korea, there will be demand for North Korean edible plants because of the low labor cost and similar environmental conditions. However, there is no reliable information about trace elements, metals, and metalloids in edible plants from North Korea. Selenium (Se) and germanium (Ge) have positive effects on basic human health and are therapeutical in diverse illnesses. Metal and metalloid (Cd, Pb) poisoning, on the other hand, can cause many health problems. Plants collected from North Korea had higher selenium content than those from South Korea. Although none of the collected species exceeded the permissible levels of cadmium and lead, their content in plants was significantly higher in North Korea than in South Korea. The high metal contents in plants collected from North Korea may be associated with the soil physicochemical properties as well as the accumulated amounts of elements in the soil.

• Bulletin of the Korean Chemical Society
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• v.19 no.10
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• pp.1036-1042
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• 1998

The preconcentration and determination of trace elements in water samples were studied by a solvent sublation utilizing dithizonate complexation. After metal dithizonates were formed, trace amounts of cadmium, cobalt, copper and lead were floated and extracted into small volume of a water-immiscible organic solvent on the surface of sample solution and determined in the solvent directly by GF-AAS. Several experimental conditions as formation condition of metal-dithizonate complexes, pH of solution, amount of dithizone, stirring time, the type and amount of surfactants, N2 bubbling rate and so on were optimized for the complete formation and effective flotation of the complexes. And also four kinds of light solvents were compared each other to extract the floated complexes, effectively. After the pH was adjusted to 4.0 with 5 M HNO3, 8.0 mL of 0.05% acetone solution of dithizone was added to 1.00 L water sample. The dithizonate complexes were flotated and extracted into the upper methyl isobutylketone (MIBK) layer by the addition of 2.0 mL 0.2% ethanolic sodium lauryl sulfate solution and with the aid of small nitrogen gas bubbles. And this solvent sublation method was applied to the analysis of real water samples and good results of more than 85% recoveries were obtained in spiked samples.

• Journal of Food Hygiene and Safety
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• v.9 no.1
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• pp.49-56
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• 1994

This study was carried out to investigate the levels of copper, zinc, manganese, nickel, cadmium and mercury content in breast milk among urban, rural and industrial lactating women in Korea. A total of 59 samples, which were collected from 17 in urban, 20 in rural and 22 in industrial area, and from 21-38 years-old healthy lactating women, were analyzed by Rigaku Mercury Analyzer for mercury, and by atomic absorption apectrophotometry for the other metals. The results are summarized as follows : The mean trace metal contents in breast milk were determined to be 0.34$\pm$0.14 ppm for copper, 2.01$\pm$1.43 ppm for zinc, 8.49$\pm$5.11 ppb for manganese, 7.75$\pm$5.73 ppb for nickel, 1.65$\pm$2.42 ppm for cadmium, 34.45$\pm$26.71 ppb for lead and 0.90$\pm$0.68 ppb for mercury. For the trace metal content in breast milk by area, the highest of copper, zinc, cadmium and mercury content were in urban, the highest of manganese content was in industrial, and the highest of nickel and lesd content were in rural. For copper, zinc, manganese and lead content in breast milk by lactation period, the highest levels were found in under 4 weeks after lactating, and subsequently the levels declined as lactation progressed, but the levels of zinc and manganese content increased from over 25 weeks after lactating. For cadmium and mercury content in breast milk by lactation period, the lowest levels were found in under 4 weeks after lactating, the highest levels were found in 5-12 weeks after lactating, and subsequently the levels declined as lactation progressed.For nickel content in breast milk by lactation period, the highest level was in 13-24 weeks after lactating, the lowest level was in 5-12 weeks after lactating.

• Environmental Analysis Health and Toxicology
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• v.12 no.3_4
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• pp.67-73
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• 1997

This study was carried out to investigate the contents of heavy metals such as iron, copper, lead, cadmium, magnesium, platium in connection with water pollution in sea weed (dried laver) collected from the west, south, south- west, and east coasts of Korea. The results of the study are as follows; Iron was shown the highest value (1.280ppm) in the wild laver from the south coast. Copper was detected in larger qauntities (0.169 ppm) in green laver than in any other kinds of laver observed in this study. Lead was detected in larger quantities (0.195ppm) in the usual laver and green laver from the south-west coast as compared with the other coasts. Although cadmium and platium was also detected from every kind of laver, the concentrations were not over the allowance of the residual.

• Journal of the Korean Society of Marine Environment & Safety
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• v.15 no.2
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• pp.157-164
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• 2009

The metals such as Al, Ag, Au, Cu, Cd, Co, Fe, Ni, Pb, Zn, etc are present at very low concentration in seawater and are classified as so-called trace metals. Whiles some of them are used in metabolism of living organism as a micronutrient, they may show toxic effects on organisms in case of a limited threshold concentration of them Plenty of studies on trace metals have been performed bemuse trace metals have a persistent influence and an adverse effect on marine environment and ecosystem. For long years, when the concentration of trace metals in natural waters such as seawater and fresh water are measured with high precision and accuracy, some systematic errors have been recognized to be present in measurements. Since 1975 in US and European countries, the measured concentration of trace metals in seawater have been found to be lower by factors of 10-1,000 than the previous data of trace metals measurements and the vertical profiles of the measurements have been shown to reflect well-known biological, physical and geochemical processes. These results are attributed to great advances in analytical instrumentation and methodology for trace metals measurements. Precautions against the contamination of samples are required to be taken in the process of sampling, storage, and analysis of samples. However, in Korea, erroneous data of trace metals with regard to ocean and marine environment related survey and investigations are reported The lock of exact understanding and information regarding precautions in sampling, storage and analysis of samples lead to the deterioration of data quality, especially in the analysis of trace metals. The major procedures to obtain the accurate data of trace metals in natural waters are introduced for applying to the study and assessment of marine environments.

• 산업보건소식
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• no.48
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• pp.9-18
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• 1987

The results of this study which had been investigated to analyse heavy metal levels and to compare lead, cadmium, copper and zinc concentration in urine of children who lived around the industrial area and the agricultural area. Samples were collected and analyzed from September to December 1986 from 7-9 years old children living in Seoul (4 7 cases), lri ( 64 cases) industrial area and Chinan (56 cases) agricultural area. The summarized results were as follows: 1) The concentrations of lead were Seoul 28.7 $\pm$17.7 ug/l, lri 25.3 $\pm$7.5 ug/l and Chinan 19.3 $\pm$5.2 ug/l 2) The concentrations of cadmium were Seoul 1.5 $\pm$0.8 ug/l, Iri 1.4 $\pm$0.5 ug/l and chinan 0.9 $\pm$0.3 ug/l 3) The concentrations of copper were Seoul 12.8 $\pm$7.0 ug/l, Iri 10.5 $\pm$8.4 ug/l and Chinan 10.0 $\pm$4.5 ug/l 4) The concentrations of zinc were Seoul 383 $\pm$279 ug/l, Iri 329 $\pm$133 ug/l and Chinan 267 $\pm$181 ug/l 5) In lead, cadmium and zinc concentration of children, there were statistical difference between the industrial area and the agricultural area 6) There were no indicated significantly levels by the Sex