• Title/Summary/Keyword: less noble potential

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Effect of Specimen Thickness to Corrosion Fatigue Crack Propagation Behavior of Structure Rolled Steel (일반구조용 압연강재의 부식피로균열전파거동에 미치는 시험편 두께의 영향)

  • 조약래
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.28 no.3
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    • pp.286-294
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    • 1992
  • In this paper, the corrosion fatigue crack propagation behavior of structure rolled steel (SWS 41C) was investigated by changing the thickness, and this experiment was done by the three point bending corrosion fatigue tester. The main results obtained are as follows: 1) As the thickness of specimen becomes thicker, the corrosion sensitivity to initial stage crack becomes some sensitive, and that the fatigue life becomes more sensitive. 2) The crack growth rate to initial stage crack (da/dN) was retarded as the thickness of specimen becomes thicker. But after initial stage crack, as the thickness of specimen is more thicker, da/dN is more rapid. 3) As the corrosion fatigue crack length grows, the accelerative factor of thick specimen (t=12mm) is more higher than that of thin specimen (t=6mm). 4) As the corrosion fatigue crack length grows, the corroson potential of both thick specimen and thin specimen becomes more less noble potential, however thick specimen (t=12mm) tends to more less noble potential than that of thin specimen(t=6mm).

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The Study of Corrosion of Heat Exchanger Tube for Absorption Refrigeration Machine (흡수식냉동기용 열교환기 세관의 부식에 관한 연구)

  • 임우조;정기철;윤병두
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2002.05a
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    • pp.147-152
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    • 2002
  • This paper was studied on corrosion of heat exchanger tube for absorption refrigeration machine. In the 62 % lithium bromide solution at $60^{\circ}C$, polarization test of Cu, Al-brass, 10 % cupro nickel(90-10 % Cu-Ni) and 30 % cupronickel(70-30 % Cu-Ni) tube was carried out. And polarization behavior, polarization resistance characteristics, open circuit potential, anodic polarization of heat exchanger tube for absorption refrigeration machine were considered. The main results are as following: The open circuit potential of Al-brass tube becomes less noble than that of Cu tube, corrosion current density of that becomes lower than Cu tube. The open circuit potential of cupronickel tube is more noble than that of Cu tube, corrosion current density of that is controlled than Cu tube. The passivation critical current of 30 % Cu-Ni tube is lower than that of 10 % Cu-Ni tube, potential of passive region of that is more wide than 10 % Cu-Ni tube.

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Study on the Corrosion Fatigue Crack Propagation Behavior of Steel Used for Frame of Vehicles in Marine Environment (해양환경중에서 자동차 프레임용 강재의 부식피로균열전파거동에 관한 연구)

  • 이상열;임종문;이종악
    • Journal of Ocean Engineering and Technology
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    • v.6 no.2
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    • pp.76-84
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    • 1992
  • In this study, corrosion fatigue test of SAPH45 steel was performed by the use of plane behavior of base metal (BM) and heat affected zone (HAZ) of SAPH45. The main results obtained are as follows: 1) The more aspect ratio (b/t) of corner crack decreases, the more aspect ratio (b/a) takes greatly effect by corrosion. 2) The correlation between the stress intensity factor range ($\Delta$k) and crack growth rate (da/dN) for weldment in seawater is given by Paris rule as follow: da/dN=C($\Delta$K) super(m). Where m is constant, and the value is 3.82-3.84. 3) The accelerative factor ($\alpha$) of BM and HAZ under seawater is about 1.1-1.9, and ($\alpha$) of HAZ increases more and more under the low $\Delta$K region. 4) HAZ is more susceptible to corrowion than BM because of potential of electrode (E sub(c)) of HAZ becomes more less noble potential than that of BM.

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A Study on the Corrosion Control of Glass Flake Lining for Mild Steel in Marine Environment (해양환경 중에서 Glass Flake 라이닝 강재의 부식방지에 관한 연구)

  • Lim, Uh-Joh;Kim, Seong-Hoon
    • Journal of Fisheries and Marine Sciences Education
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    • v.12 no.2
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    • pp.164-175
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    • 2000
  • Port facilities and marine structures used in marine environment were encountered to corrosion damages because of the influence of Cl-. Generally, to protect these accidents, anti-corrosion paint and epoxy coating have been used. But they were still remained erosion-corrosion damage like impingement erosion, cavitation erosion and deposit attack. It is necessary to develope the new composite lining material in order to protective those corrosion damages. In this paper, polyester glass flake, vinylester glass flake lining and epoxy coating for SS400 were investigated by the electrochemical polarization test and the impingement-cavitation erosion test for corrosion behaviour under the sea water. The main results obtained are as follows ; 1) Epoxy coating appear potentiodynamic polarization behaviour, but polyester glass flake and vinylester glass flake lining do not appear potentiodynamic polarization behaviour. 2) Open circuit potential of polyester glass flake lining is more noble than that of epoxy coating and corrosion current density of polyester glass flake lining is less drained than that of epoxy coating in sea water. 3) Open circuit potential of vinylester glass flake lining is more noble than that of polyester glass flake lining and corrosion current density of vinylester glass flake lining is less drained than that of polyester glass flake lining in the sea water.

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Stress Corrosion Cracking Behavior under Cavitation Erosion-Corrosion in Sea Water-Part (II) (해수환경중 캐비테이션 침식-부식 하에서의 응력부식균열 거동 (II))

  • 안석환;임우조
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.36 no.2
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    • pp.139-146
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    • 2000
  • Cavitation can occur in pipes when liquid is moving at high velocity, especially at pittings where the smooth bore of the pipe is interrupted. The effect is usually to produce pitting on the downstream side of the turbulence. However, stress corrosion cracking behavior under cavitation erosion-corrosion was neatly unknown. In this study, therefore, some were investigated of stress corrosion cracking behavior, others were stress corrosion cracking behavior under cavitation erosion-corrosion of water injection. And datas obtained as the results of experiment were compared between the two. Mainresult obtained are as follows: 1) Stress corrosion cracking growth rate of heat affected zone under cavitation erosion-corrosion becomes most rapid, and stress intensity factor $K_1$becomes most high. 2) Stress corrosion cracking growth mechanism by cavitation erosion-corrosion is judgement on the strength of the film rupture model and the tunnel model. 3) The range of potential as passivation of heat affected zone is less noble than that of base metal, and that value is smaller. 4) Corrosion potential under cavitation erosion-corrosion in loaded stress is less noble than that of stress corrosion, and corrosion current density is higher.

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Study on Characteristics of Corrosion Fatigue Crack Growh Rate of SUS 304 Stainlss Steel (SUS 304강의 부식피로균열 운전속도 특성에 관한 연구)

  • 임우조;김부안
    • Journal of Ocean Engineering and Technology
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    • v.1 no.2
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    • pp.93-100
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    • 1987
  • Corrosion fatigue cracking of the austenitic stainless steel(bese metal & heat affected zone by TIG weld) was studied experimentally under the environments of various specific resistance and air. The characteristics of corrosion fatigue crack growth rate and the environmental constants of paris' rule were investigated for SUS 304 weldments in the various specific resistance. The influences of stress intensity factor range and corrosion on the crack growth rate were compared. The characteristics of corrosion fatigue cracking for the weldments were inspected from mechanical, electrochemical and microstructural point of view. Main results obtained are as follows: 1) As the specific resistance decreases, the environmental constant C of paris'rule increases(hence the corrosion fatigue crack growth rate is rapid), but the environmental constant m decreases, so the effect of corrosion to the crack growth rate is more susceptible than thet of stress intensity factor range. 2) As the stress intensity factor range decreases, the corrosion fatigue crack growth rate of heat affected zone is more susceptible than that of the base metal. 3) The corrosion fatigue crack growth rate of the heat affected zone is more rapid than that of the base metal, because of the phenomenon of softening and the less noble potential coused by wedlding heat cycle. 4) The corrosion fatigue cracking of SUS 304 weldment appears transgranular fracture.

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Study on the Characteristics of Corrosion for Epoxy Coated Steel Structure (에폭시도막 강구조물의 부식특성에 관한 연구)

  • Lim, U-Jo;Cheun, Jeong-Hyun;Jeong, Gi-Cheol
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.34 no.2
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    • pp.223-230
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    • 1998
  • Recently, with the rapid development in the industries such as mechanical plants, automobiles, ships and marine structures, it is enlarged by the use of the SS 41 steel. This mechanical plants and marine structures are exposed m corrosion because of Cl-under marine environments. To protect their accidents, mainly applied anti-corrosion epoxy coating and various protective its structures. In this study, corrosion control characteristics on the epoxy coating were investigated by the galvanic corrosion of impressed voltage tester under marine environments The main results obtained are as follows; 1. Corrosion current density of amine-epoxy coating becomes more increased than that of other epoxy coating and the time area rate of pin hole and pit until 5% becomes most rapid. 2. The potential of SUS 304 stainless steel(cathode) for Al-epoxy coating is nearly zero potential. 3. Corrosion current density of Amine-epoxy by shot blast becomes more decreased than that of not shot blast and cathodic potential becomes more noble. 4. As distance of anode and cathode is more decreased, corrosion current density of epoxy coating is more increased and cathodic potential becomes less noble.

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The Effect of LiBr Concentration on Corrosion of Absorption Refrigeration Systems Using $LiBr-H_2O$ Working Fluids ($LiBr-H_2O$계 흡수식냉동기의 부식에 미치는 LiBr 농도의 영향)

  • Lim Uh Joh;Jeong Ki Cheol
    • Journal of the Korean Institute of Gas
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    • v.5 no.4 s.16
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    • pp.33-39
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    • 2001
  • This paper was studied on corrosion behavior of absorption refrigeration systems using $LiBr-H_2O$ working fluids. In the various concentration of lithium bromide solution, polarization test of SS 400, Cu(C1220T-OL) and Al-Ni bronze is carried out. And the corrosion behavior of materials forming absorption refrigeration systems is investigated. The main results are as following: 1) As concentration of lithium bromide solution increases, polarization resistance of materials of each kinds is low. And open circuit potential becomes less noble, the corrosion current density is high drained 2) Open circuit potential of SS 400 is less noble than that of Cu and Al-Ni bronze, corrosion current density of SS5 400 is high drained than that of Cu and Al-Ni bronze. 3) Anodic polarization of Cu and Al-Ni bronze in $62\%$ LiBr solution continues the active state. that of Cu and Al-Ni bronze in the natural sea water maintains the active state and the critical current for passivation appears.

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The Effect of Temperature on Corrosion of Absorption Refrigeration Systems Using LiBr-$H_2O$ Working Fluids (LiBr-$H_2O$계 흡수식냉동기의 부식에 미치는 온도의 영향)

  • 임우조;정기철;윤병두;강성수
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2001.11a
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    • pp.92-97
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    • 2001
  • This paper was studied on the effect of temperature on corrosion of absorption refrigeration systems using LiBr-$H_2O$ working fluids. In the fresh water and 62 %lithium bromide solution at $70^{\circ}C$, polarization test of SS 400, Cu(Cl220T-OL) and Ni-Al bronze was carried out. And Polarization behavior, polarization resistance characteristics, corrosion rate(mmpy) and corrosion sensitivity of materials forming absorption refrigeration systems was considered. The main results are as following: As the experimental temperature increase, the change of corrosion rate of Ni-Al bronze become duller than SS 400 and Cu in 62 % lithium bromide solution. Open circuit potential of SS 400 is less noble than that of Cu and Ni-Al bronze in fresh water, but that becomes noble than Cu and Ni-Al bronze in 62 % lithium bromide solution. The corrosion sensitivity of Ni-Al bronze was controlled than that of Cu and SS 400 in 62% LiBr solution.

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Study on the Crevice Corrosion Behavior of SS 400 in Marine Environment (해양환경중에서 SS400강재의 간극부식거동에 관한 연구)

  • 임우조;정기철;안석환;윤병두
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2000.11a
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    • pp.1-6
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    • 2000
  • This paper was studied on the crevice corrosion behavior of SS 400 in marine environment. In 0%, 2%, 3.5%, 5% NaCl solution, the aspect of the crevice corrosion and polarization behavior under the crevice corrosion was investigated. And Weight loss rate of SS 400 with crevice and non-crevice was measured according to the NaCl concentration. The main results obtained are as follows : 1) Under crevice corrosion, the corrosion potential become less noble as the concentration of NaCl solution increased. 2) The current density under open circuit potential was high drained as concentration of NaCl solution increased by 3.5% but the concentration increased over 3.5%, the current density was low drained. 3) The weight loss rate of SS400 was increased as concentration of NaCl solution increased by 3.5% but the concentration increased over 3.5%, that of SS400 was decreased.

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