• Journal of the Korean Society of Safety
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• v.31 no.4
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• pp.42-47
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• 2016

The combustible properties(flash point, explosion limit and autoignition temperature) are the important safety items which are considered in the typical MSDS(material safety data sheet). In this study, for the safe handling of n-butyl methacrylate(n-BMA) being used in various ways in the chemical industry, the flash point and the autoignition temperature(AIT) of n-butyl methacrylate was experimented. And, the lower explosion limit of n-butyl methacrylate was calculated by using the lower flash point obtained in the experiment. The flash points of n-butyl methacrylate by using the Setaflash and Pensky-Martens closed-cup testers measured $44^{\circ}C$ and $51^{\circ}C$, respectively. The flash points of n-butyl methacrylate by using the Tag and Cleveland open cup testers are measured $53^{\circ}C$. The AIT of n-butyl methacrylate by ASTM 659E tester was measured as $295^{\circ}C$. The lower explosion limit by the measured flash point $44^{\circ}C$ was calculated as 0.85 vol.%. It was possible to predict lower explosion limit by using the experimental flash point or flash point in the literature.

• Journal of the Korean Society of Safety
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• v.27 no.5
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• pp.70-76
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• 2012

For the safe handling of n-tetradecane, the lower flash points and the upper flash point, fire point, AITs (auto-ignition temperatures) by ignition delay time were experimented. Also lower and upper explosion limits by using measured the lower and upper flash points for n-tetradecane were calculated. The lower flash points of n-tetradecane by using closed-cup tester were measured $104^{\circ}C$ and $112^{\circ}C$. The lower flash points and fire point of n-tetradecane by using open cup tester were measured $113^{\circ}C$ and $115^{\circ}C$, respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-tetradecane. The experimental AIT of n-tridecane was $207^{\circ}C$. The calculated lower and upper explosion limit by using measured lower $104^{\circ}C$ and upper flash point $140^{\circ}C$ for n-tetradecane were 0.63 Vol.% and 3.18 Vol%.

• Journal of the Korean Society of Safety
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• v.28 no.4
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• pp.53-57
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• 2013

For the safe handling of n-pentadecane, the lower flash points and the upper flash point, fire point, AITs(auto-ignition temperatures) by ignition delay time were experimented. Also lower and upper explosion limits by using measured the lower and upper flash points for n-pentadecane were calculated. The lower flash points of n-pentadecane by using closed-cup tester were measured $118^{\circ}C$ and $122^{\circ}C$. The lower flash points and fire point of n-pentadecane by using open cup tester were measured $126^{\circ}C$ and $127^{\circ}C$, respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-pentadecane. The experimental AIT of n-pentadecane was $195^{\circ}C$. The calculated lower and upper explosion limit by using measured lower $118^{\circ}C$ and upper flash point $174^{\circ}C$ for n-pentadecane were 0.54 Vol.% and 6.40 Vol.%.

• Journal of the Korean Society of Safety
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• v.29 no.3
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• pp.39-45
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• 2014

For the safe handling of n-hexadecane, the lower flash points and the upper flash point, fire point, AITs(auto-ignition temperatures) by ignition delay time were experimented. Also lower and upper explosion limits by using measured the lower and upper flash points for n-hexadecane were calculated. The lower flash points of n-hexadecane by using the Setaflash and the Pensky-Martens closed testers were measured $128^{\circ}C$ and $126^{\circ}C$, respectively. The lower flash points of the Tag and the Cleveland open cup testers were measured $136^{\circ}C$ and $132^{\circ}C$, respectively. The fire points of the Tag and the Cleveland open cup testers were measured $144^{\circ}C$. respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-hexadecane. The experimental AIT of n-hexadecane was $200^{\circ}C$. The calculated lower and upper explosion limit by using measured lower $128^{\circ}C$ and upper flash point $180^{\circ}C$ for n-hexadecane were 0.42 Vol.% and 4.70 Vol.%.

• Journal of the Korean Society of Safety
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• v.27 no.3
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• pp.83-88
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• 2012

For the safe handling of n-tridecane, the lower flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. Also lower explosion limits by the lower flash points were calculated. The lower flash points of n-tridecane by using closed-cup tester were experimented $92^{\circ}C$ and $96^{\circ}C$. The lower flash points and fire point of n-tridecane by using open cup tester were experimented 100 oC and 103 oC, respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-tridecane. The experimental AIT of n-tridecane was 223 oC. The calculated lower explosion limit by using measured lower flash point 92 oC for n-tridecane was 0.6 Vol.%.

• Fire Science and Engineering
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• v.27 no.2
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• pp.11-17
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• 2013

For the safe handling of n-undecane, the lower flash points and the upper flash point, fire point, AITs (auto-ignition temperatures) by ignition delay time were experimented. Also lower and upper explosion limits by using measured the lower and upper flash points for n-undecane were calculated. The lower flash points of n-undecane by using closed-cup tester were measured $59^{\circ}C$ and $67^{\circ}C$. The lower flash points of n-undecane by using open cup tester were measured $67^{\circ}C$ and $72^{\circ}C$, respectively. The fire point of n-undecane by using Cleveland open cup tester was measured $74^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-undecane. The experimental AIT of n-undecane was $198^{\circ}C$. The estimated lower and upper explosion limit by using measured lower flash point $59^{\circ}C$ and upper flash point $83^{\circ}C$ for n-undecane were 0.65 Vol.% and 2.12 Vol.%.

• Fire Science and Engineering
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• v.17 no.2
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• pp.50-55
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• 2003

The lower flash points for the binary system, n-butanol+n-decane, were measured by Pensky-Martens closed cup tester. The experimental results showed the minimum in the flash point versus composition curve. The experimental data were compared with the values calculated by the reduced model under an ideal solution assumption and the flash point-prediction models based on the Van Laar and Wilson equations. The predictive curve based upon the reduced model deviated form the experimental data for this system. The experimental results were in good agreement with the predictive curves, which use the Van Laar and Wilson equations to estimate activity coefficients. However, the predictive curve of the flash point prediction model based on the Willson equation described the experimentally-derived data more effectively than that of the flash point prediction model based on the Van Laar equation.

• Journal of the Korean Society of Safety
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• v.29 no.4
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• pp.85-90
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• 2014

For the safe handling of acetic anhydride, this study was investigated the explosion limits of acetic anhydride in the reference data. And the lower flash points, upper flash points, and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower and upper explosion limits of acetic anhydride by the investigation of the literatures recommended 2.9 Vol% and 10.3 Vol.%, respectively. The lower flash point of acetic anhydride by using Setaflash closed-cup tester was experimented $49^{\circ}C$. The lower flash point acetic anhydride by using Tag and Cleveland open cup tester were experimented $55^{\circ}C$and $62^{\circ}C$, respectively. Also, this study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for acetic anhydride. The experimental AIT of acetic anhydride was $350^{\circ}C$.

• Journal of the Korean Society of Safety
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• v.31 no.5
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• pp.42-48
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• 2016

The usage of the correct combustion properties of the treated substance for the safety of the process is critical. For the safe handling of n-nonane being used in various ways in the chemical industry, the flash point and the autoignition temperature(AIT) of n-nonane was experimented. And, the explosion limit of n-nonane was calculated by using the flash point obtained in the experiment. The flash points of n-nonane by using the Setaflash and Pensky-Martens closed-cup testers measured $31^{\circ}C$ and $34^{\circ}C$, respectively. The flash points of n-nonane by using the Tag and Cleveland open cup testers are measured $37^{\circ}C$ and $42^{\circ}C$. The AIT of n-nonane by ASTM 659E tester was measured as $210^{\circ}C$. The lower explosion limit by the measured flash point $31^{\circ}C$ was calculated as 0.87 vol%. And the upper explosion limit by the measured upper flash point $53^{\circ}C$ was calculated as 2.78 vol%. It was possible to predict lower explosion limit by using the experimental flash point or flash point in the literature.

• Fire Science and Engineering
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• v.29 no.4
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• pp.21-25
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• 2015

The usage of the correct combustion characteristics of the treated substance for the safety of the process is critical. For the safe handling of bromobenzene being used in various ways in the chemical industry, the flash point and the autoignition temperature (AIT) of bromobenzene was experimented. And, the lower explosion limit of bromobenzene was calculated by using the lower flash point obtained in the experiment. The flash points of bromobenzene by using the Setaflash and Pensky-Martens closed-cup testers measured $44^{\circ}C$ and $50^{\circ}C$, respectively. The flash points of bromobenzene by using the Tag and Cleveland automatic open cup testers are measured $56^{\circ}C$ and $64^{\circ}C$. The AIT of bromobenzene by ASTM 659E tester was measured as $573^{\circ}C$. The lower explosion limit by the measured flash point $44^{\circ}C$ was calculated as 1.63 Vol%. It was possible to predict lower explosion limit by using the experimental flash point or flash point in the literature.