• Title/Summary/Keyword: metalloid

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Effects of Metalloid Elements on the Mechanical Properties of Fe-Based Bulk Amorphous Alloys

  • Kim, Yongchan;Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.26 no.12
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    • pp.671-675
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    • 2016
  • In this study, the glass-forming ability and mechanical properties of newly developed Fe-Mn-Cr-Mo-B-C-P-Si-Al bulk amorphous alloys were investigated, and metalloid elements such as B, C, and P were found to have a strong influence on the properties of the Fe-based amorphous alloys. When the total metalloid content (B, C, and P) is less than 5 %, only the crystal phase is formed, but the addition of more than 10 % metalloid elements enhances the glass forming ability. In particular, the alloys with 10 % metalloid content exhibit the best combination of very high compressive strength (~2.8 GPa) and superior fracture elongation (~30 %) because they consist of crystal/amorphous composite phases.

Comparison of Trace Element, Metal, and Metalloid Contents in North and South Korean Plants

  • Park, Jeong-Soo;Chung, Ha-Sook;Lee, Eun-Ju
    • Journal of Environmental Science International
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    • v.23 no.6
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    • pp.995-1001
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    • 2014
  • When relations improve between North and South Korea, there will be demand for North Korean edible plants because of the low labor cost and similar environmental conditions. However, there is no reliable information about trace elements, metals, and metalloids in edible plants from North Korea. Selenium (Se) and germanium (Ge) have positive effects on basic human health and are therapeutical in diverse illnesses. Metal and metalloid (Cd, Pb) poisoning, on the other hand, can cause many health problems. Plants collected from North Korea had higher selenium content than those from South Korea. Although none of the collected species exceeded the permissible levels of cadmium and lead, their content in plants was significantly higher in North Korea than in South Korea. The high metal contents in plants collected from North Korea may be associated with the soil physicochemical properties as well as the accumulated amounts of elements in the soil.

ANTIMUTAGENIC STUDY OF SELENIUM COMPOUNDS

  • Bronzetti, Giorgio;Leonardo Caltavuturo, Marco Cini;Croce, Clara Della
    • Proceedings of the Korean Society of Toxicology Conference
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    • 2001.10a
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    • pp.10-10
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    • 2001
  • Selenium is an essential nutritional element for several animal species and human. It has been also seen, that low levels of selenium in the diet can cause many diseases. This metalloid was defined like a "double face" element because it possesses antioxidant, antimutagen, anticarcinogen but also mutagenic and carcinogenic effects. The most important metabolic role of selenium in the animal species is its presence in the Glutathione Peroxidase(GSH-Px). (omitted)

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Effects of Metal and Metalloid Contamination on Microbial Diversity and Activity in Agricultural Soils

  • Tipayno, Sherlyn C.;Chauhan, Puneet S.;Woo, Sung-Man;Hong, Bo-Hee;Park, Kee-Woong;Chung, Jong-Bae;Sa, Tong-Min
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.1
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    • pp.146-159
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    • 2011
  • The continuous increase in the production of metals and their subsequent release into the environment has lead to increased concentration of these elements in agricultural soils. Because microbes are involved in almost every chemical transformations taking place in the soil, considerable attention has been given to assessing their responses to metal contaminants. Short-term and long-term exposures to toxic metals have been shown to reduce microbial diversity, biomass and activities in the soil. Several studies show that microbial parameters like basal respiration, metabolic quotient, and enzymatic activities, including those of oxidoreductases and those involved in the cycle of C, N, P and other elements, exhibit sensitivity to soil metal concentrations. These have been therefore, regarded as good indices for assessing the impact of metal contaminants to the soil. Metal contamination has also been extensively shown to decrease species diversity and cause shifts in microbial community structure. Biochemical and molecular techniques that are currently being employed to detect these changes are continuously challenged by several limiting factors, although showing some degree of sensitivity and efficiency. Variations and inconsistencies in the responses of bioindicators to metal stress in the soil can also be explained by differences in bioavailability of the metal to the microorganisms. This, in turn, is influenced by soil characteristics such as CEC, pH, soil particles and other factors. Therefore, aside from selecting the appropriate techniques to better understand microbial responses to metals, it is also important to understand the prevalent environmental conditions that interplay to bring about observed changes in any given soil parameter.

A Mathematical Model Development for Microbial Arsenic Transformation and Transport

  • Lim, Mi-Sun;Yeo, In-Wook;Lee, Kang-Kun
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.318-322
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    • 2004
  • Arsenic is a toxic and carcinogenic metalloid, whose sources in nature include mineral dissolution and volcanic eruption. Abandoned mines and hazardous waste disposal sites are another major source of arsenic contamination of soil and aquatic systems. To predict concentrations of the toxic inorganic arsenic in aqueous phase. the biogeochemical redox processes and transport behavior need to be studied together and be coupled in a reactive transport model. A new reaction module describing the fate and transport of inorganic arsenic species (As(II)), dissolved oxygen, nitrate, ferrous iron, sulfate, and dissolved organic carbon are developed and incorporated into the RT3D code.

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A Study on the Rinsing Control Method in the Gilding Process (도금공정에서의 세척수 제어기법에 관한 연구)

  • Kim Ki Joon
    • Journal of Korea Society of Industrial Information Systems
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    • v.9 no.4
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    • pp.8-15
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    • 2004
  • Gilding process make thin membrane with other metals to surface of metal and metalloid. It control the hydrogen ion and oxalic acid density with rinsing work since the process used to acid and alkali. Therefore, in this study, several control method applied the gilding process. It desired to the optimal controller and their results can be save on water resource by useful feed of rinsing. And there is quite a possibility of uniform production due to fixed control of acid and alkali. Also it can be contributed the competition power because of lower production unit cost. Especially, this control method to be developed can be applied to any process without mathematical model. And it can be changed their algorithm more easily, if control object is changed.

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Membrane-Associated Hexavalent Chromium Reductase of Bacillus megaterium TKW3 with Induced Expression

  • Cheung K.H.;Lai H.Y.;Gu Ji-Dong
    • Journal of Microbiology and Biotechnology
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    • v.16 no.6
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    • pp.855-862
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    • 2006
  • Hexavalent chromium ($Cr^{6+}$) is a highly harmful pollutant, which can be detoxified and precipitated through reduction to $Cr^{3+}$. Bacillus megaterium TKW3 previously isolated from chromium-contaminated marine sediments was capable of reducing $Cr^{6+}$ in concomitance with metalloids ($Se^{4+}$, $Se^{6+}$, and $As^{5+}$). Notwithstanding approximately 50% inhibition, it was the first report of simultaneous bacterial reduction of $Cr^{6+}$ and $Se^{4+}$ (to elemental Se). No significant difference was observed among electron donors (glucose, maltose, and mannitol) on $Cr^{6+}$ reduction by B. megaterium TKW3. The reduction was constitutive and determined to be non-plasmid mediated. Peptide mass fingerprints (PMF) revealed a novel aerobic membrane-associated reductase with $Cr^{6+}$-induced expression and specific reductive activity (in nmol $Cr^{6+}$/mg protein/min) of 0.220 as compared with 0.087 of the soluble protein fraction. Respiratory inhibitor $NaN_3$ did not interfere with the reductase activity. Transmission electron microscopy with energy dispersive X-ray (TEM-EDX) analysis confirmed the aggregation of reduced chromium along the intracellular membrane region. Future identification of the N-terminal amino acid sequence of this reductase will facilitate purification and understanding of its enzymatic action.