• 제목/요약/키워드: neutralization system

검색결과 109건 처리시간 0.031초

기능성 레진을 이용한 구조화된 나노 입자의 특성

  • 신진섭;박영준;김중현
    • 한국결정학회:학술대회논문집
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    • 한국결정학회 2002년도 정기총회 및 추계학술연구발표회
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    • pp.53-53
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    • 2002
  • Alkali-soluble random copolymer (ASR) was used as a functional resin in the emulsion polymerization of styrene to prepare structured nanoparticles. The calorimetric technique was applied to study the kinetics of emulsion polymerization of styrene using ASR and conventional ionic emulsifier, sodium dodecyl benzene sulfonate (SDBS). ASR could form aggregates like micelles and the solubilization ability of the aggregates was dependent on the neutralization degree of ASR. The rate of polymerization in ASR system was lower than that in SDBS system. This result can be explained by the creation of a hairy ASR layer around the particle surface, which decreases the diffusion rate of free radicals through this region. Although a decrease in particle size was observed, the rate of polymerization decreased with increasing ASR concentration. The higher the concentration of ASR is, the thicker and denser ASR layer may be, and the more difficult it would therefore be for radicals to reach the particle through this layer of ASR. The rate of polymerization decreased with increasing the neutralization degree of ASR. The aggregates with high neutralization of ASR are less efficient in solubilizing the monomer and capturing initiator radicals than that of the lower neutralization degree, which leads to decrease in rate of polymerization.

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SVM을 이용한 비선형 화학공정 모델링: pH 중화공정에의 적용 예 (Nonlinear Chemical Plant Modeling using Support Vector Machines: pH Neutralization Process is Targeted)

  • 김동원;유아림;양대륙;박귀태
    • 제어로봇시스템학회논문지
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    • 제12권12호
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    • pp.1178-1183
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    • 2006
  • This paper is concerned with the modeling and identification of pH neutralization process as nonlinear chemical system. The pH control has been applied to various chemical processes such as wastewater treatment, chemical, and biochemical industries. But the control of the pH is very difficult due to its highly nonlinear nature which is the titration curve with the steepest slope at the neutralization point. We apply SVM which have become an increasingly popular tool for machine teaming tasks such as classification, regression or detection to model pH process which has strong nonlinearities. Linear and radial basis function kernels are employed and each result has been compared. So SVH based on kernel method have been found to work well. Simulations have shown that the SVM based on the kernel substitution including linear and radial basis function kernel provides a promising alternative to model strong nonlinearities of the pH neutralization but also to control the system.

Multimax Reactor System을 이용한 안료제조시 중화공정의 열적위험성 평가 (Evaluation of Thermal Hazard in Neutralization Process of Pigment Plant by Multimax Reactor System)

  • 이근원;한민수
    • 한국안전학회지
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    • 제23권6호
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    • pp.91-99
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    • 2008
  • The identification of thermal hazards associated with a process such as heats of reaction and understanding of thermodynamics before any large scale operations are undertaken. The evaluation of thermal behavior with operating conditions such as a reaction temperature, stirrer speed and reactants concentration in neutralization process of pigment plant are described. The experiments were performed by a sort of calorimetry with multimax reactor system The aim of the study was to evaluate the results of heat of reaction in terms of safety reliability to be practical applications. It suggested that we be proposed safe operating conditions and securities for accident prevention on reactor explosion through this study.

음절말 자음 중화의 원인 (Why do Obstruents Neutralize in Syllable Final Position\ulcorner)

  • 양순임
    • 대한음성학회지:말소리
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    • 제41호
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    • pp.31-47
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    • 2001
  • The purpose of this study is to explain the cause of obsturents neutralization in syllable final position. Most of the previous phonological studies did not reflect phonetic reality sufficiently because of the limited use of the binary feature system. Using binary distinctive features, we can't explain the cause of neutralization. In order to explain the cause of neutralization, I use the multi-valued phonetic feature -[vocal tract aperture]. By [vocal tract aperture] I mean the distance between articulators in the hold stage. In this study, I claim that the cause of neutralization is assimilation to [vocal tract aperture] 0 degree. The neutralized sounds become aplosives, as a consequence of assimilation to [vocal tract aperture].

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Hybrid neutralization and membrane process for fluoride removal from an industrial effluent

  • Meftah, Nouha;Ezzeddine, Abdessalem;Bedoui, Ahmed;Hannachi, Ahmed
    • Membrane and Water Treatment
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    • 제11권4호
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    • pp.303-312
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    • 2020
  • This study aims to investigate at a laboratory scale fluorides removal from an industrial wastewater having excessive F- concentration through a hybrid process combining neutralization and membrane separation. For the membrane separation operation, both Reverse Osmosis (RO) and Nanofiltration (NF) were investigated and confronted. The optimized neutralization step with hydrated lime allowed reaching fluoride removal rates of 99.1± 0.4 %. To simulate continuous process, consecutive batch treatments with full recirculation of membrane process brines were conducted. Despite the relatively high super saturations with respect to CaF2, no membrane cloaking was observed. The RO polishing treatment allowed decreasing the permeate fluoride concentration to 0.9± 0.3 mg/L with a fluoride rejection rate of 93± 2% at the optimal transmembrane pressure of around 100 psi. When NF membrane was used to treat neutralization filtrate, the permeate fluoride concentration dropped to 1.1± 0.4 mg/L with a fluoride rejection rate of 88± 5% at the optimal pressure of around 80 psi. Thus, with respect to RO, NF allowed roughly 20% decrease of the driving pressure at the expense of only 5% drop of rejection rate. Both NF and RO permeates at optimal operating transmembrane pressures respect environmental regulations for reject streams discharge into the environment.

휴대 단말기용 MIMO 안테나의 격리도 향상에 관한 연구 (A Study on the Improvement of MIMO Antenna Isolation for Mobile Applications)

  • 윤인섭;염효가;김상욱;조윤현;박효달
    • 한국전자통신학회논문지
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    • 제10권9호
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    • pp.987-992
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    • 2015
  • 본 논문에서는 neutralization line 구조를 이용하여 안테나 간의 격리도를 향상시킨 MIMO 안테나 구조를 설계하였다. 제안된 MIMO 안테나 구조의 크기는 $116mm{\times}64mm{\times}5mm$이며, ${\varepsilon}r=4.4$인 FR-4 유전체를 사용하여 설계하였다. 또한 두 안테나 간의 격리도를 확보하기 위해 neutralization line을 추가하였다. 측정결과는 VSWR 3:1 기준으로 LTE B13 대역을 만족시켰고, 격리도를 -15 dB 이하로 확보하였다. H-평면에서 전방향성 방사특성을 나타내었으며, LTE B13 대역에서 -2.61 dBi에서 -1.18 dBi까지의 이득과 33.49 %에서 46.45 %까지의 방사효율을 얻었다. 측정결과와 시뮬레이션 결과를 비교하여 제안된 MIMO 안테나는 이동통신 휴대 단말기에 적용 가능함을 확인할 수 있다.

다관능기를 도입한 아이오노머 필름의 기체투과 특성 (Permeation Property of Ionomer Film with New Multifunctional Ionic Site)

  • 이보미;정삼봉;남상용
    • 한국재료학회지
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    • 제22권5호
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    • pp.227-236
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    • 2012
  • Ionomer is a thermoplastic that is composed of covalent bonds and ionic bonds. It is possible to use this material in processes such as injection molding or extrusion molding due to the material's high oil resistance, weatherproof characteristics, and shock resistance. In this study, a new ionomer having a multifunctional group was prepared by a stepwise neutralization system with the addition of acidic and salt additives. In step I, to increase the contents of the multifunctional group and the acid degree in ethylene acrylic acid (EAA), MGA was added to the ionomer resin (EAA). A new ionomer was prepared via the traditional preparation method of the ionic cross-linking process. In step II, metal salt was added to the mixture of EAA and MGA. The extrusion process was performed using a twin extruder (L/D = 40, size : ${\varphi}30$). Ionomer film was prepared for evaluation of gas permeability by using the compression molding process. The degree of neutralized and ionic cross-linked new ionomer was confirmed by FT-IR and XRD analysis. In order to estimate the neutralization of the new ionomer film, various properties such as gas permeation and mechanical properties were measured. The physical strength and anti-scratch property of the new ionomer were improved with increase of the neutralization degree. The gas barrier property of the new ionomer was improved through the introduction of an ionic site. Also, the ionic degree of cross-linking and gas barrier property of the ionomer membrane prepared by stepwise neutralization were increased.

중화약품과 마이크로버블 장치를 이용한 폐수처리장 바이오가스 처리 (Biogas Treatment from Wastewater Treatment Plant by Micro-bubble Generation System with Neutralization Chemicals)

  • 정재억;정용준
    • 한국습지학회지
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    • 제23권1호
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    • pp.54-59
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    • 2021
  • 폐수처리장에서 발생하는 바이오가스 중의 황화수소를 처리하기 위하여 습식스크러빙 장치가 적용되었다. 유입 H2S의 농도가 5,000mg/L이상에서 DIWS 장치에 물만을 사용할 경우 25%의 제거율을 나타내어 후속으로 소각처리 공정이 도입되어야만 98% 이상의 제거율을 나타냈다. 유입 H2S의 농도가 5,000mg/L일 때 CH4과 CO2는 각각 8.7%와 28.6% 감소하여 배출되었다. DIWS 장치에 중화약품으로 Na2CO3와 NaOH를 사용하였을 때 pH가 11.2~11.5를 유지하면서 H2S는 97.2% 제거되었다.

Electrodialysis of metal plating wastewater with neutralization pretreatment: Separation efficiency and organic removal

  • Park, Yong-Min;Choi, Su-Young;Park, Ki-Young;Kweon, Jihyang
    • Membrane and Water Treatment
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    • 제11권3호
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    • pp.179-187
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    • 2020
  • Electrodialysis has been applied for treatment of industrial wastewater including metal electroplating. The wastewater from metal plating industries contains high concentrations of inorganics such as copper, nickel, and sodium. The ions in the feed were separated due to the electrical forces in the electrodialysis. The concentrate compartment is exposed to the elevated concentrations of the ions and yielded inorganic precipitations on the cation exchange membranes. The presence of organic matter in the metal plating wastewater affects complex interfacial reactions, which determines characteristics of inorganic scale fouling. The wastewater from a metal plating industry in practice was collected and the inorganic and organic compositions of the wastewater were analyzed. The performance of electrodialysis of the raw wastewater was evaluated and the effects of adjusting pH of the raw water were also measured. The integrated processes with neutralization and electrodialysis showed great removal of heavy metals sufficient to discharge to aquatic ecosystem. The organic matter in the raw water was also reduced by the neutralization, which might enhance removal performance and alleviate organic fouling in the integrated system.

굴껍질을 이용한 도금폐수의 중화 및 중금속 이온 제거 (Neutralization and removal of heavy metal ions in Plating wastewater utilizing Oyster Shells)

  • 성낙창;김은호;김정권;김형석
    • 한국환경보건학회지
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    • 제22권3호
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    • pp.81-87
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    • 1996
  • The purpose of this research is to examine the utilization of oyster shells for neutralization and removal of heavy metal ions in plating wastewater, because oyster shells have been known to be very porous, to have high specific surface area and to have alkaline minerals such as calcium and magnesium. The results obtianed from this research showed that oyster shells had a buffer capacity to neutralize an acidic.alkali system in plating wastewater. Generally, it could be showed that the removal efficiencies of heavy metal ions were very influenced by reaction times and oyster shell dosages. In point of ocean waste, if oyster shells substituted for a valuable adsorbent such as actviated carbon, they could look forward to an expected economical effect.

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