• Economic and Environmental Geology
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• v.34 no.1
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• pp.1-12
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• 2001

The crystal structure of biotite-1M from Bancroft, Ontario, was determined by Rietveld refinement method using high-resolution neutron powder diffraction data at -26.3$^{\circ}C$, 2$0^{\circ}C$, 30$0^{\circ}C$, $600^{\circ}C$, 90$0^{\circ}C$. The crystal structure has been refined to a R sub(B) of 5.06%-11.9% and S (Goodness of fitness) of 2.97-3.94. The expansion rate of a, b, c unit cell dimensions with elevated temperature linearly increase to $600^{\circ}C$. The expansivity of the c dimension is $1.61{\times}10^{40}C^{-1}$, while $2.73{\times}10^{50}C^{-1}$ and $5.71{\times}10^{-50}C^{-1}$ for the a and b dimensions, respectively. Thus, the volume increase of the unit cell is dominated by expansion of the c axis as increasing temperature. In contrast to the trend, the expansivity of the dimensions is decreased at 90$0^{\circ}C$. It may be attributed to a change in cation size caused by dehydroxylation-oxidation of $Fe^{2+}$ to $Fe^{3+}$ in vacuum condition at such high temperature. The position of H-proton was determined by the refinement of diffraction pattern at low temperature (-2.63$^{\circ}C$). The position is 0.9103${\AA}$ from the O sub(4) location and located at atomic coordinates (x/a=0.138, y/b=0.5, z/c=0.305) with the OH vector almost normal to plane (001). According to the increase of the temperature, $\alpha$* (tetrahedral rotation angle), $t_{oct}$ (octahedral sheet thickness), mean distance increase except 90$0^{\circ}C$ data. But the trend is less clearly relative to unit cell dimension expansion because the expansion is dominant to the interlayer. Also, ${\Psi}$ (octahedral flattening angle) shows no trends as increasing temperature and it may be because the octahedron (M1, M2) is substituted by Mg and Fe.

• Geophysics and Geophysical Exploration
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• v.22 no.3
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• pp.149-159
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• 2019

Borehole elemental concentration logging, measuring neutron-induced gamma rays by inelastic scattering and neutron capture interactions between neutron and formation, delivers concentrations of the most common elements found in the minerals and fluids of subsurface formation. X-ray diffraction and X-ray fluorescence analysis from core samples are traditionally used to understand formation composition and mineralogy, but it represents only part of formations. Additionally, it is difficult to obtain elemental analysis over the whole intervals because of poor core recovery zones such as fractures or sand layers mainly responsible for groundwater flow. The development of borehole technique for in situ elemental analysis plays a key role in assessing subsurface environment. Although this technology has advanced consistently starting from conventional and unconventional resources evaluation, it has been considered as exclusive techniques of some major service company. As regards domestic research and development, it has still remained an unexplored field because of some barriers such as the deficiency of detailed information on tools and calibration facility for chemistry and mineralogy database. This article reviews the basic theory of spectroscopy measurements, system configuration, calibration facility, and current status. In addition, this article introduces the domestic researches and self-development status on borehole elemental concentration tools.

• Proceedings of the Korean Magnestics Society Conference
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• 2007.05a
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• pp.289.1-289.1
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• 2007

• Journal of Magnetics
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• v.15 no.2
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• pp.56-60
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• 2010

In this study, we investigated the optical, magnetic, and electrical transport properties of $Si_{1-x}Mn_x$ (0.1 < x < 0.9) single crystals grown by the vertical Bridgman method. The alloys with a Mn concentration of up to 64% demonstrated weak ferromagnetic ordering around $T_C=30\;K$. The $Si_{0.25}Mn_{0.75}$ and $Si_{0.18}Mn_{0.82}$ alloys showed weak ferromagnetic ordering at 70 K and antiferromagnetic ordering at 104 K, as confirmed by magnetization, neutron diffraction, and transport studies.

• Journal of Advanced Marine Engineering and Technology
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• v.21 no.5
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• pp.463-468
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• 1997

잔류응력이 부품의 성능에 미치는 영향에 대해 많은 연구가 되어져왔고, 이를 성능개선에 효과적으로 응용하는 많은 방법들이 소개되었다. 또한, 부품의 가공성, 변형 등에 대한 잔류응력의 영향을 정량적 또는 정성적으로 해석하는 연구가 지속되어져 왔을 뿐 아니라, 복합재료 내에서의 잔류응력과 그의 영향에 대해서도 활발한 연구가 계속되고 있다. 이처럼 잔류응력의 분야는 그의 측정, 응용 및 구조물내의 역할 등에 대한 연구의 잠재성이 큰 분야이다. 잔류응력이 부품의 성능에 미치는 영향에 대한 정확한 예측과 효율적 응용을 위해서는 잔류응력을 비파괴적으로, 정량적으로 정확히 그리고 부품 전체에 걸쳐 현장에서 신속히 측정할수 있는 방법이 절실히 요구되어지고 있지만 아직 이러한 방법은 존재하지 않는다. 여기에 대한 연구가 이루어지고 방법이 개발되어질 수 있다면 이는 대단히 획기적인 연구가 될 것이다. Neutron diffraction technique이 이에 가장 근접한 방법이 되겠으나 현장에서의 신속한 측정에는 아직 매우 미흡하다.

• International Journal of Korean Welding Society
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• v.5 no.1
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• pp.1-9
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• 2005

Multipass welds of 316L stainless steel have been widely employed to the pipes of Liquid Metal Reactors. Owing to localized heating and a subsequent rapid cooling by the welding process, residual stress arises in the weld of the pipe. In this study, the residual stresses in the 316L stainless steel pipe welds were calculated by the finite element method using the ANSYS code. Also, the residual stresses both on the surface and in the interior of the thickness were measured by the HRPD(High Resolution Powder Diffractometer) instrumented in the HANARO Reactor. The experimental data and the calculated results were compared and the characteristics of the distribution of the residual stress were discussed.

• Journal of Mechanical Science and Technology
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• v.16 no.6
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• pp.757-761
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• 2002

When a layer of cylindrical composite component containing an axisymmetric residual stress state is removed from the inner or outer surface, the dimension of the remaining material changes to balance internal forces. Therefore, in order to machine cylindrical composite components within tolerances, it is important to know dimensional changes caused by residual stress redistribution in the body. In this study, analytical solutions for dimensional changes and the redistribution of residual stresses due to the layer removal from a residually stressed cylindrically orthotropic cylinder were developed. The cylinder was assumed to have axisymmetric radial, tangential and axial residual stresses. The result of this study is useful in cases where the initial residual stress distribution in the component has been measured by a non-destructive technique such as neutron diffraction with no information on the effect of layer removal operation on the dimensional changes.

• Proceedings of the Materials Research Society of Korea Conference
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• 1992.05a
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• pp.1-1
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• 1992

Shape Memory Alloys have attracted the interest of a great number of researchers in the world, and Mexico is not the exception. Research in this field started ten years ago, and is actually an active line covering the classical Cu-based and Ti-Ni alloys, but also the new Fe-based alloys. Although more basic studies have been performed at the present time, interest for applied research and technological goals is increasing. In this work we present a series of studies carried on these Shape Memory Alloys by the groups in Mexico, and explain what the interest of our groups are in the next future in this are of the Materials Science. Interdisciplinary work has been necessary in the characterization of the different alloys, and multiple techniques have been used, like Mossbauer spectroscopy, thermoelectric power, electron microscopy, ultrasound techniques, neutron and x-ray diffraction, calorimetry, among others. Collaboration With other groups in Europe and in the United States have become highly useful and productive, and some examples of such activities are also reported.

• Proceedings of the Korean Magnestics Society Conference
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• 2003.06a
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• pp.62-63
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• 2003

Electron-phonon interaction plays a significant role in forming of colossal magnetoresistance effect (CMR). Polaron formation was observed by neutron diffraction and by extended X-ray absorption fine structure (EXAFS) analysis. Local probe as given by the EXAFS is a useful method to study the polaronic charge and its dependence on temperature and ions size. Here we present the EXAFS study of polaronic charge in $La_{0.7}Ca_{0.3-x}Ba_{x}MnO_3$ compositions.

• Macromolecular Research
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• v.13 no.6
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• pp.499-505
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• 2005

Ordered mesoporous materials with a hydrothermally-stable, protozeolitic framework were prepared by exploring the direct conversion of inorganic species based on co-surfactant templating systems. To confer hydrothermal stability on the mesoporous aterials, the organic-inorganic hybrids were heat-treated in strongly basic media. Co-surfactant templating systems of cetyltrimethylammonium bromide [$C_{16}H_{13}(CH_{3})_{3}$NBr, CTAB] with 1,3,5-trim­ethylbenzene (TMB) or a nonionic block copolymer of poly(ethylene oxide )-b-poly(propylene oxide )-b-poly(ethyl­ene oxide) ($EO_{20}PO_{70}EO_{20}$) were employed to improve the hydrothermal stability of the organic-inorganic self-assembly during the solid rearrangement process of the inorganic species. The mesoscopic ordering of the pore structure and geometry was identified by X-ray diffraction, small angle neutron scattering and electron microscopy.