• Journal of Environmental Health Sciences
• /
• v.22 no.4
• /
• pp.82-90
• /
• 1996

This study was performed to find the optimum mixing ratio of paper waste in composting of mixture of swine feces and newspaper. Using the experimental setting of aeration rate which was found in the experiment carried out priorly, and moisture contents reported in other literature, just the initial C:N ratios were differentiated by mixing different amount of newspaper with the same amount of swine feces. This study was carried out by operating 4 experimental cornposting reactors of bench scale for 3 weeks. The followings are the conclusions that were derived from this study. 1. During composting reaction, the C:N ratio of each cornposter was decreased. Degree of decrease was in order of run 3, run 2, run 4, and run 1 of which initial C:N ratio was 30, 25, 35, and 20 respectively. All of the final composts were found to be completed composting reaction. 2. Ash contents of each reactor increased rapidly in order of run 3, run 2, run 4, and run 1. The absolute values of quadratic effect coefficients of each second order regression function was 0.059, 0.038, 0.032, and 0.030 respectively. Ash contents evolution trend had a linear correlation with the C:N ratio trend. (r=-0.96932, p<0.05) 3. The range of highest temperatures reached during composting was 47.2-53.5$\circ$C. Those were not significantly different from one another. Thermophilic temperatures were maintained in the range of 48-108 hours. 4. Contents of heavy metal detected in the final compost were lower than those of Korean and European standards. 5. Concentration range of Nitrogen in the final compost was 1.11-2.27%, and that of phosphorus was 8.40-10.70 mg/kg. 6. The optimum C:N ratio which has been proposed without the consideration of types of bulking agents should be re-examined. Biodegradabilities of each bulking agents was thought to be important factor when determining the optimum initial C:N ratio for cornposting.

• Korean Journal of Microbiology
• /
• v.10 no.1
• /
• pp.9-28
• /
• 1972

1. To get the suitable yeasts for the tratment of waste liquor from pulp and paper industries, the 162 yeasts were isolated from the waste liquor, decayed trees and sewage (1, 7, 8, 9, 1971). 17 species were chosen by its ability to assimilate the carbon compounds and indentified. 2. All of the strain was increased its growing ability by agitation. In particular, the strain 912, strain 613, strain 100, strain 732 showed excellent high productive ratio(A/$A_{0}$). 3. The optimum temperature of the strains rangel $27^{\circ}C$ and $30^{\circ}C$. 4. Most of the strain was grown actively in 10C/5N-composition and strain 113, strain 432, strain 735, strain 936, and strain 912 showed its optimum growing in 15C/5N-composition and 5C/5N-composition, respectively. 5. The optimum pH of the strains lay within range pH 4.5-6. Effect of the variation of pH on the growth was nearly negligible within this range. 6. The strain 912, strain 100, strain 613, strain 311, strain 235, and strain 732 were expected for the utilization to the treatment of the waste liquor from pulp and paper industries.

• Journal of Korean Society of Water and Wastewater
• /
• v.21 no.6
• /
• pp.745-753
• /
• 2007

By struvite and hydroxyapatite crystallization, was high concentration of nitrogen and phosphorus in wastewater simultaneously. Particularly, removal of nitrogen and phosphate for crystallization have been applied to landfill leachates and animal wastewater. The purpose of this study is to decide the optimum struvite crystallization factors, sequence of $Mg^{2+}$ addition, pH control and the molar ratio of $Mg^{2+}$ over $PO_4^{3-}$. In conclusion, dosage of the magnesium followed by pH control formed magnesium hydroxide, so pH was decreased. Therefore, pH adjustment should followed by after magnesium dosage and then pH should be adjusted to 11. Over pH 10, it was not good for struvite crystallization efficiency by side reaction. Following of the $Mg^{2+}$ and the $PO_4^{3-}$ are dosed excessively, the removal efficiency of the $NH_4^+$ increased. A molar ratio of $Mg^{2+}:NH_4^+:PO_4^{3-}$, 1.3:1:1.3 was the most on effective for $NH_4^+$ removal at pH 9.5. But for the perfect removal $NH_4^+$, it is thought to be that molar ratio should be 2:1:2.

• Journal of Microbiology and Biotechnology
• /
• v.7 no.6
• /
• pp.391-396
• /
• 1997

Two series of carbon sources, linear primary $C_1$~$C_9$ alcohols and linear $C_2$~$C_{10}$ monocarboxylic acids were tested for PHA synthesis in Paracoccus denitrificans. The results showed that the growth-associated synthesis of PHA could be referred only to the carbon sources with odd number of carbon except methanol. For all carbon sources with even number of carbon, nitrogen limitation was required to induce PHA synthesis in P. denitrificans. Poly(3-hydroxyvalerate)[P(3HV)] homopolymer was synthesized from $C_5$, $C_7$, and $C_9$ while growing in the presence of nitrogen, but the nitrogen depletion in the later growth period incorporated 3-hydroxybutyrate(3HB) unit into the polymer chain. The optimum C/N ratio for P(3HV) homopolymer production was found to be 10 when the strain was grown on 10 ml/l of valeric acid for 96 h. P. denitrificans synthesized P(3HB-co-3HV) copolymers from n-hexanoic and n-octanoic acid. The microstructural characterics of the P(3HB-co-3HV) copolymer from n-propanol was investigated using $^13C$-nuclear magnetic resonance spectroscopy, showing a structural heterogeneity.

• Journal of The Korean Society of Grassland and Forage Science
• /
• v.9 no.1
• /
• pp.26-33
• /
• 1989

This pot experiments were conducted to find out the optimal fertilization ratios of the N:S:P anions and K:Ca:Mg cations of major nutrients in an orchardgrass/ladino clover mixed sward. The optimum ratios in equivalent basis were computed by the Homes systematic variations technique. The soil samples were collected from the newly reclaimed soils, which are located on colluvial hilly area with a good consideration for the hilly pasture development. The results were summarized as follows; 1, the optimum fertilization ratios of major nutrients for the high yields by the forage species in a mixed sward were obtained (Table 4 in detail); N:S:P = 3:l: 1 and K:Ca:Mg = 1:l: 1 for grass and grass plus legume, and N:S:P = 1:6:43 and K:Ca:Mg = 1: 3: 1 for legume in general. 2. The yield increases from the systematic variations in this mixed sward were laid in following order; N > P >S-group and K >Mg >Ca-group for grass and grass plus legume, and P >S >N-group and Ca >Mg > K-group for legume. Especially, the yields were greatly increased at the N-group for grass, and at the Pand Ca-groups for legume. 3. Soil pH-value was descreased at the Sgroup, and somewhat increased at the Ca- and Mg-groups. The content of available $P_2O_5$, CEC and base saturation were greatest with the Ca-group. 4. At the N-group, the N-contents were highest and the P-contents were lowest in grass and grass plus legume, which resulted in the highest Ca/P ratio of 2.15 among the anion groups. Whereas the highest Ca/P ratio of 9.20 in legume was obtained at the Ca-group. Legume showed in general higher Ca/P ratio and lower K/(Ca+Mg) ratio than these in grass. 5 . There were differences in the effects of systematic variations of major nutrients on the dry matter yields and the mineral yields. The optimum fertilization ratios of anions and cations for the high mineral yields were obtained (Table E), which showed differences comparing with the ratios for the high dry matter yields. The antagonis between the cations K and Mg was known from the point of mineral yields of mixed forages.

• Journal of Life Science
• /
• v.9 no.3
• /
• pp.268-275
• /
• 1999

Rhodopseudomonas sp. was immobilized in three supports(agar, k-carrageenan, and PVA) in order to remove nitrate in wastewater coming from fish farm. Among them 3% agar was the most suitable support when denitrification rate and bead durability were tested. Optimum bead size was 4mm-diameter when the substrate transfer into the bead and shear stress for bead were considered, and optimum cell loading was 25mg dry $cells/cm^2$gel gel. Ethanol was the best as a carbon source, and optimum C:N ratio, temperature and pH were 1.5:1, $31^{\circ}C$,, and 6, respectively. Under these conditions the maximum denitrification rate in synthetic wastewater was $$345{\MU}{\ell};N_2/Cm^3 gel{\cdot}hr;and that in modified MYC medium was 450{\MU}{\ell}};N_2/Cm^3 gel{\cdot}hr $$.

• Journal of Korean Society of Environmental Engineers
• /
• v.38 no.5
• /
• pp.228-235
• /
• 2016

Nitrite accumulation is essential for constructing an anammox process. As the pH in the reactor exerts a complicated and strong influence on the reaction rate, we investigated its effects upon treatment of an ammonic wastewater (2,000 mgN/L) through modeling and experiment. The modeling results indicated that the reaction stability is strongly affected by pH, which results in a severe reduction of the 'stable region' of operation under alkaline environments. On a coordinate of the total ammonia nitrogen (TAN) concentration vs. pH, the maximal stable reaction rates and the maximal nitrite accumulation potentials could be found on the 'stability ridge' that separates the stable region from the unstable region. We achieved a stable and high ammonia oxidation rate (${\sim}6kgN/m^3-d$) with a nitrite accumulation ratio of ~99% when operated near the 'stability ridge'. The optimum pH that can be observed in experiments varies with the TAN concentrations utilized, although the intrinsic optimum pH is fixed. The direction of change is that the optimum operational pH falls as the TAN concentration increases, which is in excellent accordance with the observations in the literature. The optimum operational pH for 95% nitritation was predicted to be ~8.0, whereas it was ~7.2 for 55% partial nitritation to produce an anammox feed in our experimental conditions.

• Journal of Korean Society of Environmental Engineers
• /
• v.33 no.4
• /
• pp.231-236
• /
• 2011

The effects of magnesium and calcium ions on phosphorus removal by aluminium coagulation were investigated with various jar tests using settled raw sewage. Maximum TP (total phosphate) removal occurred at pH around 5~6 with aluminium coagulation, and it decreased above pH 6. TP and $H_nPO_4^{n-3}$ removal efficiencies, however, were kept above 95% at pH above 6 by adding the divalent metallic ions like magnesium or calcium ions on aluminium coagulation process. At molar ratio of Al/P ($Al^{3+}/H_nPO_4^{n-3}$) above 3, TP removal efficiency was as high as 80%, and residual TP less than 0.2 mg/L occurred at Al/P ratio above 6. TP removal efficiency was improved by adding magnesium or calcium ions and the optimum $Al^{3+}/Mg^{2+}$ and $Al^{3+}/Ca^{2+}$ ratios were about 2. The required dose of aluminium coagulant was reduced for equivalent amount of TP removal by adding magnesium or calcium ions, as a result sludge generation was also reduced.

• Journal of Environmental Health Sciences
• /
• v.23 no.2
• /
• pp.44-56
• /
• 1997

When sewage sludge is treated by cornposting, higher moisture content and lower C/N ratio on sewage sludge is problems. This paper project to alesolve two problems. The almost trends in run 3 of MC 70% are similar to these in run 1 and 4 of MC 65%. A retention time of the highest temperature (>50$\circ$C) and increase rate of temperature in run 3 are an affinity to these in run 4. Particularly, decrease rate of temperature in run 3 is slower than others and this data shows the more activity of thermal microbial in run 3 than that in others. C/N ratio trends in run 3 shows slow reaction in initial stage but, after 9 days, is similar to that in run 1 and 4. Carbon trends in each run are a similarity to C/N ratio trends. Temperature, MC, carbon and C/N ratio trends in run 5, whose C/N ratio is 15, show less microbial activity than that in run 6, whose C/N ratio is 20. But temperature increase of the beginning stage and pH of the final stage in run 5 are greater than that in run 6. Final MC and carbon content in run 5 and 6 have a similar values. That is, final MC in run 5 and 6 is 49.39% and 48.97% and final carbon content in each run is 25.15% and 22.20%. Expecially, a temperature increase and C/N ratio decrease rate of the beginning stage in run 5 are greater than these in run 6. This shows the shorter lag time in run 5 than lag time in run 6.

• Journal of Environmental Science International
• /
• v.11 no.12
• /
• pp.1261-1265
• /
• 2002

This study was focused on the investigation of the characteristics of organics and nitrogen removal with the recycle ratio in anoxic/oxic(A/O) packed bed process that consisted of the anoxic reactor and the aerobic reactor. As increasing the recycle ratio by 0.5, 1.0, 2.0, the COD removal efficiency increased by 94.0%, 98.5%, 98.8% respectively. The aerobic reactor showed the perfect nitrification efficiency by 98.5%, 99.2%, 98.0% respectively. The T-N removal efficiency with the recycle ratio, increased by 56%, 67%, 70% respectively. As increasing the recycle ratio by 0.5, 1.0, 2.0, T-P removal efficiency decreased by 62.1%, 57.4%, 51.3% respectively. The process by releasing the stored phosphorus in the anoxic reactor and uptaking the excess phosphorus in the aerobic reactor, occurred well comparatively when recycle ratio is 0.5. But this process did not occur when the recycle ratio is 1.0 and 2.0. And optimum pH of nitrification was about 6~7 and alkalinity decreased as nitrification rate increased. As increasing the recycle ratio in the anoxic reactor, DO concentration and ORP increased.