• 제목/요약/키워드: organic chemicals

검색결과 538건 처리시간 0.028초

Ink Jet Printing of Functional Materials

  • Canisius, Johannes;Brookes, Paul;Heckmeier, Michael;James, Mark;Mueller, David;Patterson, Katie
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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    • pp.1121-1124
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    • 2007
  • Ink jet printing has been targeted as a key technology for OLED, TFT backplane and other organic semiconductor device fabrication. This presentation will concentrate on aspects of the IJ process, formulation design, jetting performance, interaction with the substrate and resultant printed device performance.

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The Simplest Flowchart Stating the Mechanisms for Organic Xenobiotics-induced Toxicity: Can it Possibly be Accepted as a "Central Dogma" for Toxic Mechanisms?

  • Park, Yeong-Chul;Lee, Sundong;Cho, Myung-Haing
    • Toxicological Research
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    • 제30권3호
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    • pp.179-184
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    • 2014
  • Xenobiotics causing a variety of toxicity in biological systems could be classified as two types, inorganic and organic chemicals. It is estimated that the organic xenobiotics are responsible for approximately 80~90% of chemical-induced toxicity in human population. In the class for toxicology, we have encountered some difficulties in explaining the mechanisms of toxicity caused especially by organic chemicals. Here, a simple flowchart was introduced for explaining the mechanism of toxicity caused by organic xenobiotics, as the central dogma of molecular biology. This flowchart, referred to as a central dogma, was described based on a view of various aspects as follows: direct-acting chemicals vs. indirect-acting chemicals, cytochrome P450-dependent vs. cytochrome P450-independent biotransformation, reactive intermediates, reactivation, toxicokinetics vs. toxicodynamics, and reversibility vs. irreversibility. Thus, the primary objective of this flowchart is to help better understanding of the organic xenobiotics-induced toxic mechanisms, providing a major pathway for toxicity occurring in biological systems.

마이크로파에 의한 휘발성 유기토양오염물질 제거에 관한 연구 (Microwave Remediation of Soils Contaminated by Volatile Organic Chemicals)

  • 문경환;김우현;이병철;김덕찬
    • 한국환경보건학회지
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    • 제22권3호
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    • pp.116-122
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    • 1996
  • This study has been focused on the applicability of microwave treatment of soil contaminated by volitile organic chemicals. Substrates studied were sand and sandy soil. These substrates were impregnated with toluene, tetrachloroethylene, o-xylene and p-dichlorobenzene. The microwave treatment was conducted in a modified domestic microwave oven: 2450 MHz, 700 W. The sandy soil temperature added water went up rapidly to about 130$\circ$C for 4 minutes. And then, the temperature appeared to plateau out. A series of tests were performed to depict the effectiveness of microwave treatment technique to organic contaminants from soils. Removal efficiencies in sandy soil and sand were increased with increasing water content and exposure time. Microwave radiation penetrates the soil and heats water throughout the matrix. Therefore, addition of a certain amount of water to the contaminated soil can efficiently enhance the ability of the soil to absorb microwave energy and promote the evaporation of the volitile contaminants. And the vapour pressure of impregnated organic contaminants becomes lower. the removal efficiency becomes poor.

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야자껍질 탄화탄과 야자껍질 활성탄에 의한 수중 Trichloroethylene의 흡착에 관한 연구 (Adsorption of Trichloroethylene in Water by Coconut Carbon and Coconut Activated Carbon)

  • 김영규;정문호
    • 한국환경보건학회지
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    • 제19권4호
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    • pp.25-32
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    • 1993
  • Granular activated carbon is commonly used in fixed-bed adsorbers to remove organic chemicals. In this experiment organic chemical solutions were prepared by adding the reagent grade organic chemical to distilled water. Isotherm adsorption tests of volatile organic chemicals were conducted using bottle-point technique and column test. Organic chemicals after passing through the column were extracted with hexane and analyzed with gas chromatography (Hewlett-Packard 5890) to check the adsorption capacity and breakthrough curve. The result were as follows: 1. The BET surface area of coconut activated carbon was 658~1,010 m$^2$/g where as coconut shell carbon was 6.6 m$^2$/g. Coconut activated carbon increased the BET surface area and adsorption capacity in bottle-point isotherm. 2. The adsorption capacity of coconut activated carbon for trichloroethylene (TCE) was reduced in the presence of humic substance. 3. A decrease in particle size of activated carbon resulted in higher adsorption capacity and lower intraparticle diffusion coefficient. It is reflected not only as a decrease in Freudlich adsorption capacity value (K) but also as an increase in Freudlich exponenent value (1/n).

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서남해 연안해역의 유기오염물질 분포특성에 관한 연구 (A Study on Distribution Property of Organic Pollutants in Southwest Coastal Waters)

  • 한상국;박지영;이문희
    • 한국환경과학회지
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    • 제14권6호
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    • pp.597-603
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    • 2005
  • In this study, we try to determine the distributive property in southwest coastal waters, such as K wang-yang bay, Ka-mak bay, Yeo-ja bay, Wan-do, Hea-nam, Young-gwang, and Mok-po, using simultaneous analytical method of 310 chemicals. The results were detected tens of the organic pollutants in sampling sites, and the major chemicals detected were CH type chemicals such as aliphatic, polycyclic compounds and were CHN(O) type chemicals such as aromatic amines, nitro compounds, In particular, pesticides were mainly detected in summer, phenols and phthalate esters were not seasonal effect. Also, a number of aromatic chemicals were detected in Kwang-yang bay, From the results of this study, we confirmed that it is mainly contaminated in summer and the pesticide chemicals are the major pollutants in southwest coastal waters.

Multi-class Analysis of Exposure Chemicals in Deciduous Teeth by Liquid Chromatography-Mass Spectrometry: Preliminary Studies on Sample Preparation Methods

  • Lee, Yujin;Seo, Eunji;Park, Jun Young;Bae, Kwang-Hak;Lee, Jaeick;Cha, Sangwon
    • Mass Spectrometry Letters
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    • 제9권4호
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    • pp.110-114
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    • 2018
  • Since accumulation of chemicals in deciduous teeth can occur from the second trimester of fetal development to shedding, a deciduous tooth has been considered as an attractive biomatrix for estimating individual chemical exposures recently. Therefore, detection of organic chemicals from teeth has received an increasing attention in exposomics research. Most previous studies on organic chemical analysis of teeth not only focused on a few targeted chemicals but also ignored potential contaminants from an enamel surface or a dental pulp. Recently, our group started developing a multi-class organic analysis method for deciduous teeth and tried to find a proper incubation condition of tooth materials. Our results showed that incubation with methanolic HCl provided the best performance among tested.

친환경농산물 생산농가의 행태 및 특성 분석 (Analyzing the Producer's Behavior and Characteristics of Environmentally Friendly Agricultural Products)

  • 조완형
    • 한국유기농업학회지
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    • 제12권1호
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    • pp.45-66
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    • 2004
  • The objectives of this study are to analyze the producer's behaviors and characteristics of environmentally friendly agricultural products(organic agricultural products and non-chemicals agricultural products, low-chemicals agricultural products excluded). Firstly the present situation of environmentally-friendly agriculture is analyzed. Secondly the producer's behavior and attitude is analyzed tabularly and the social and economic characteristics of producers is analyzed by logit model with thc results of sample surveys on 341 farmers who have been producing quality-certificated environmentally friendly agricultural products. Thirdly based on the results of this study, problems and alternatives means in order to activate production of environmentally friendly agricultural products are finded and showed.

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사고 누출 화학물질의 지하수 및 토양 환경 내 거동 및 환경 독성 특성 III: 유기화학물질을 중심으로 (Fate and Toxicity of Spilled Chemicals in Groundwater and Soil Environment III: organics)

  • 정슬기;문희선;신도연
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제24권1호
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    • pp.1-9
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    • 2019
  • This study presents a technical perspective to the fate characteristics of phenol and m-cresol, which represent some of the most common organic chemicals found in chemical spill accidents, and likely to persist in soil and groundwater due to their highly stable physicochemical properties. Some cases of domestic and foreign chemical accidents linked to phenol and m-cresol contamination were compiled. Due to their low organic carbon-water partitioning coefficient (Koc), phenol and m-cresol tend to migrate into groundwater and remained as dissolved phase. On the other hands, phenol and m-cresol can be readily decomposed by microbes in soil and groundwater under appropriate conditions. Therefore, the fate characteristics of these chemicals are highly contingent on environmental conditions. Thus, if a great quantity of leakage is occurred by chemical accidents, the up-to-date and correct information about fate characteristics taking into account both the chemical and environmental conditions is greatly needed to minimized the potential hazards from these chemicals.

CO2로부터 5원환 탄산염의 화학적 고정화 반응을 위한 Metal-Organic Frameworks의 촉매적 응용 (Catalytic Application of Metal-Organic Frameworks for Chemical Fixation of CO2 into Cyclic Carbonate)

  • 지훈;카나가라지 나빈;김동우;조득희
    • 공업화학
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    • 제31권3호
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    • pp.258-266
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    • 2020
  • CO2로부터 5원환 탄산염의 합성은 지구 온난화를 문제를 해결하고 정밀한 화학 물질을 생산하는 유망한 방법 중 하나이다. 본 총설에서는 CO2와 에폭시 화합물로부터 5원환 탄산염 합성을 위한 다공성 결정 물질인 metal-organic framework (MOF)의 촉매로써 적용 가능성에 대해 검토하였다. CO2와 에폭시 화합물의 부가 반응에 대하여 MOF의 구조적 기능과 그에 따른 불균일계 촉매로써의 활성을 조사하였다. 그 결과, 5원환 탄산염 합성에서 MOF 촉매의 산점(acidic site)과 친핵체(nucleophile)의 상승효과(synergistic effect)에 의하여 반응성이 높아지는 것을 확인하였다. 또한 CO2의 부가반응에서 설계된 MOF의 구조에 대한 영향과 반응메커니즘을 조사하여 제시하였다.

유아용 유기면 의류의 소비 및 안전성능 인증실태 (Tendency of Consumption and Safety Certification for Infant's Organic Cotton Apparel)

  • 조성교;한은주
    • 한국의류학회지
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    • 제39권6호
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    • pp.924-937
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    • 2015
  • This study surveyed the recognition and credibility of infant's organic cotton apparel and examined the current quality of children's organic cotton clothes available in the market. This study contributes to improve fabric certification programs and safety standards by understanding customer opinions and actual quality. A customer survey revealed that customers believe that organic cotton products should not include chemicals such as pesticides, fluorescent whitening agents and chemical colors; in addition, customers have high expectations for safety as well as worries about the products' validity. Children's underwear was the most purchased item category among organic cotton products. Current organic cotton certification programs are voluntary with multiple organizations that provide various certification standards. A total of 34.2% of children's organic cotton clothes sold at online and offline stores were not certified, and 10.5% had invalid certification information. This may substantially lower the credibility of organic cotton products and requires immediate change. Examination of organic cotton products showed that products do not meet customer expectations for quality and safety: 3 out of 8 products used accessories (buttons and wappens) that include harmful chemicals such as lead, phthalate and formaldehyde, 6 products used fluorescent whitening agents, and 4 products used other fabrics such as rayon, polyurethane and polyester. GOTS mark is the most recognized organic certification, but it still allows the usage of fluorescent whitening agents, which indicates a gap between customer opinions and actual certification standards. Managing national-level mandatory certification programs like food and setting quality standards that meets customer expectations are required to enhance the credibility of organic cotton products.