• Journal of the Korean Society of Food Science and Nutrition
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• v.30 no.6
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• pp.1011-1020
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• 2001

Volatile organic components from onions stored in the different decay conditions were extracted by SDE apparatus and analyzed by GC-FID and GC/MS. Components of 115, 143, 123 and 137 were identified in fresh onions, decayed onions without heating, half-decayed and complete-decayed onions after heating, respectively. These components included esters, aldehydes, ketones, alcohols and sulfur-containing compounds. Dimethyl trisulfide, dimethyl disulfide, dipropyl trisulfide and 3,5-diethyl-1,2,4-trithiolane were the main sulfur-containing components in fresh onions and decayed onions without heating. As spoilage of onions, the concentrations of sulfur-containing components of volatile extracts significantly decreased. Apart from sulfur-containing components, volatile organic components in half-decayed and complete-decayed onions after heating were mainly composed of esters, aldehydes, ketones and alcohols. Ketones of volatiles in complete-decayed onions after heating were high relatively.

• The Korean Journal of Pesticide Science
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• v.18 no.4
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• pp.376-382
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• 2014

The soluble loess-sulfur mixture allowed standing to remove insoluble component materials for five weeks after manufacturing. We decreased the pH level of soluble loess-sulfur mixture at pH 1.0 modified with decreasing 25% sodium hydroxide than original content. The pH ranges of soluble loess-sulfur mixture solutions were adjusted to pH 5.0-pH 11.0 (pH 1 unit) with brown rice vinegar (pH 2.8). The pH of original loess-sulfur mixture was about pH 13 and damaged the foliar parts and young leaves of tomato after twice application. These stock solutions can be diluted 500:1 with tap water to make a 0.05% working solution and were sprayed two times with 7 days interval to the leaf and stem of tomato, which were spontaneously infected with E. cichoracearum. Control efficacy of powdery mildew ranged from 85% to 90% at 7 days after first application. After second application, each loess-sulfur mixture solutions adjusted pH level significantly suppressed the powdery mildew disease in tomato. Consequently, loess-sulfur complex adjusted pH level with brown rice vinegar was suggested to be low in acute toxicity at all different pH values and suggested to use an agent for control of tomato powdery mildew in organic farming.

• Journal of the Korea Organic Resources Recycling Association
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• v.9 no.1
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• pp.127-133
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• 2001

It can be known that from leachate generated in the initial stage of landfill there are a lot of undecomposed orgainc materials, its sulfur component reduces to sulfide ion by sulfur reducing microorgarnisms as an anaerobic digestion proceeds, the sulfide ion makes the leachate discolor to black by forming metal sulfide sol, on condition that much more equivalent of sulfide ion than that of metal ion is present, and the metal sulfide sol can be generated to the precipitates by forming black-colored particulates. Therefore, we can confirm the important possibility for the economic and efficient treatment of leachate that it can be passivated, provided that much more equivalent of sulfide ion is present in the reaction of sulfide ion and metal ion.

• Korean Journal of Food Science and Technology
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• v.51 no.2
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• pp.147-151
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• 2019

This study was performed to investigate the physiological activity of Hongsan garlic and Hansan garlic, which were registered in the plant breeders' right in 2016. The content of mineral components, except sodium and sulfur ingredients, was found to be high in Hansan garlic. In addition, organic sulfur components were high in Hansan garlic. Moreover, the total soluble solid content, reducing sugar content, and alpha glucosidase inhibitory activity were high in Hansan garlic. Acidity, pH, total phenol, and flavonoid content were high in Hongsan garlic. Both varieties showed higher inhibitory activity to gram-positive bacteria than to gram-negative bacteria. The antimicrobial activity of Hongsan garlic was slightly higher than that of Hansan garlic. These results are expected to provide useful information to farmers who grow the above garlic varieties.

• Bulletin of the Korean Chemical Society
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• v.31 no.11
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• pp.3151-3155
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• 2010

This study was performed to develop analytical methods to better understand the properties and reactivity of petroleum, which is a highly complex organic mixture, using high-resolution mass spectrometry and statistical analysis. Ten crude oil samples were analyzed using negative-mode electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS). Clustering methods, including principle component analysis (PCA), hierarchical clustering analysis (HCA), and k-means clustering, were used to comparatively interpret the spectra. All the methods were consistent and showed that oxygen and sulfur-containing heteroatom species played important roles in clustering samples or peaks. The oxygen-containing samples had higher acidity than the other samples, and the clustering results were linked to properties of the crude oils. This study demonstrated that clustering methods provide a simple and effective way to interpret complex petroleomic data.

• Journal of the Microelectronics and Packaging Society
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• v.23 no.4
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• pp.79-85
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• 2016

It is imperative to find environment-friendly coatings as an alternative to the currently used hexavalent chromate conversion coatings for the purpose of improving the anti-corrosion properties of aluminum alloys. Hence, in this study, the corrosion properties of a trivalent chromate conversion coating solution are analyzed and measured. Because of the presence of multiple components in trivalent chromate conversion coating solutions, it is difficult to control plating, attributed to their mutual organic relationship. It is of significance to determine the concentrations of the components present in these coatings; hence, qualitative and quantitative analysis is required. The coating solution contained not only an environment-friendly component chromium(III), but also zirconium, fluorine, sulfur, and potassium, in the coating film. These metals are confirmed to produce a film with improved corrosion resistance to form a thin layer. The excellent corrosion resistance for the trivalent chromate solution is attributed to various inorganic and organic additives.

• Journal of Korean Society for Atmospheric Environment
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• v.15 no.E
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• pp.39-43
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• 1999

To help idntify the potential sources of volatile organic sulfur compounds within the continental environment, we have conducted preliminary measurements of dimethylsulfide(DMS) during field campains held from three reference sites. These sampling sites were located within a waste reclamation facility in Won Ju City, Kang Won Province. The results of our measurements showed that DMS levels spanned over 1 to 55 pptv with a mean and 1 standard deviation(1SD) of 12 and 18 pptv(N=13). In a comparison of the data derived from the strongest sources, i.e., oceanic environment, the DMS levels in thre reclamation facility were jpronouncingly low with high day-to-night concentration ratios. It was noted that a significant difference in DMS levels between daytime and nighttime periods was mainly driven by a few exceptional data measured during daytime. Despite limitations of our measurement data in deriving meaningful interpretations of spatiotemporal distributions of DMS in inland facilities, the existence of extraordinary trends, i.e., especially "lower-than-expectedL" DMS values, can be explained in terms of mixed effects of several factors. Most importantly, we can infer that the rates of DMS production and of its destruction in the study site are at or near steady-state condition. Another possibility is that DMS is not adequate enough to explain the generally malordorous environment of reclamation sites, of particular in Won Ju area.n Ju area.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.39 no.spc1
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• pp.180-188
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• 2006

We examined the effect of salt marsh vegetation on the benthic environment in macro-tidal flats at Donggeomdo, Ganghwa, on the west coast of Korea. Nine stations were established along a transect across the tidal flats, including salt marsh, and field sampling was conducted monthly from July 1997 to June 1998. During the study period, environmental parameters fluctuated as follows: salinity, 15.0 to 28.2 psu, exposure time, 613 to 702 hr/m, inundation time, 28 to 117 hr/m, sediment organic carbon, 0.71 to 1.34%, nitrogen, 0.07 to 0.16%, sulfur from 0.07 to 0.22%, mean grain size from 6.3 to $6.9{\phi}$, water content from 19.4 to 44.4%, water temperature from 4.4 to $20.4^{\circ}C$ and temperature of the surface sediments, 2.7 to $31.1^{\circ}C$, in total, seven halophyte species were sampled and found to be vertically distributed across the tidal levels. Carer scabrifolia, Suaeda maritima, Limonium tetragonum and Phragmites communis dominated the upper zone of the salt marsh, Juncus haenkei, Triglochin maritimum and P. communis dominated the middle zone, and Suaeda japonica predominated in the lower area. Principal component analysis (PCA) and non-metric multi-dimensional scaling revealed that the zonation of halophytes was related to environmental variables such as salinity and exposure time. The halophyte communities were likely related to the organic content of the surface sediment.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.9
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• pp.793-802
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• 2009

Adsorption properties were estimated for the organic silicon compounds (siloxanes) in an actual landfill gas (LFG) using adsorbents such as coconut activated carbon, coal activated carbon, silica gel, sulfur adsorbent, carbonized sludge, and molecular sieve 13X. Coconut activated carbon showed the highest removal efficiency of more than 95%. The desorption of hexamethyldisiloxane (L2) from the adsorbent, however, resulted in the remarkable concentration variation of the compound in the treated gas. Silica gel, which had high adsorption capacity for L2 in single substance adsorption experiment in the other study, could not remove the component in the actual landfill gas while it adsorbed well octamethylcyclotetrasiloxane (D4) and decamethylcyclopentasiloxane (D5) in the LFG. Therefore the elimination of hexamethyldisiloxane is an important factor to determine the level of total organosilicon compound in pretreated landfill gas. Moreover, the L2 from the actual landfill gas was effectively adsorbed by the serial adsorption test using two columns packed with coconut activated carbon which has the great capacity of siloxanes removal among others. In order to utilize efficiently LFG as a renewable energy, the emission and adsorptive characteristics of the substance to be treated should be considered for the organization, operation, and management of pretreatment process.

• Korean Journal of Food Science and Technology
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• v.36 no.1
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• pp.1-8
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• 2004

Effects of temperature, discoloration, and conditioning on garlic compositions before and after storage were examined. Proximate composition, soluble solids, pH, organic acids, and total sugars of all samples were not significantly different. Sugar contents were sucrose > fructose > glucose, and included such fructooligosaccharide as 1-kestose, 1-nystose, and 1-F-fructosyl nystose. Allicin contents in control, green discolored, and conditioned garlics were 647,9, 613.8, and 648.0 mg%, respectively. Thirty-two flavor compounds were identified by GC/MSD, including 11 sulfide compounds, 5 acids, and 3 aldehydes. Contents of sulfur compounds, including disulfide(di-propenyl), 2-thiophene methanethiol, thiophene, 3,4 dihydro-3-vinyl-1,2-dithiin, and 2-vinyl-4H-1,3-dithin, and water-soluble pectins in low temperature-stored garlic were higher than those in control, and decreased by conditioning or inducing green discoloration. These results show sulfur compounds and water-soluble pectins accumulated in low temperature stored-garlic, and are then converted into green pigments by alliinase in disintegrated garlic tissues.