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Anionic Polymerization of ${\varepsilon}$-Caprolactam via $CS_2$ / KOH Catalysis (Ⅲ) ($CS_2$ / KOH Catalysis에 의한 ${\varepsilon}$-Caprolactam의 음이온 중합 (제3보))

  • Koo Myeong-Seo;Choi Sam Kwon
    • Journal of the Korean Chemical Society
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    • v.21 no.6
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    • pp.440-444
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    • 1977
  • The anionic polymerization of ${\varepsilon}$-caprolactam via $CS_2$/KOH catalysis was carried out under various conditions. The inherent viscosity of the polymers and percent conversion of the polymers were determined. It was observed that the percent conversion was increased as an increasing concentration of catalyst and initiator. The percent conversion was relatively low at low temperature and the highest percent conversion was obtained at temperature between $130^{\circ}C,\;to\;155^{\circ}C$ with any $CS_2$/KOH mole ratio.

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Effects of the Curing Temperature on the Strength of Mortar added Admixtures (양생온도(養生溫度)가 혼화재(混和材)를 사용(使用)한 Mortar의 강도(强度)에 미치는 영향(影響))

  • Kang, Sin-Up;Kim, Seong-Wan
    • Korean Journal of Agricultural Science
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    • v.3 no.2
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    • pp.214-224
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    • 1976
  • This research was attempted as one of studies on the strength of mortar added admixtures at different curing temperatures. Variations of curing temperature to. test compressive strength, tensil strength and bending strength were $20^{\circ}C$, $30^{\circ}C$ and $35^{\circ}C$ and these results were summarized as follow : In strength of mortar added briquette ash, the compressive strength was increased: 1.58 percent, the tensile strength 0.96 percent, and the bending strength 1.26 percent compared with standard strength, by increasing one degree of celsius temperature. Also in strength of mortar added fly ash, the compressive strength increased on the average 1.3 percent, the tensile strength 0.99 percent, and the bending strength 1.18 percent at the above conditions. In case of using fly ash as admixture, maximum compressive strengths was attained at the level of 25 percent of fly ash, maximum tensile strength at the level of 20 percent of fly ash, and maximum bending strength at the level of 20 percent of fly ash. In case of using briquette ash, maximum compressive strength was attained maximum strength at 20 percent of the admixture, maximum tensile strength at the level of 15 to 20 percent of admixture and maximum bending strength at the level of 20 percent of admixture. Although addition of briquette ash was less effective in increasing the strength compared with the addition of fly ash, briquette ash might be used as one of admixtures because the control of curing temperature might affect in getting the required practical strength.

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PROCESSING OF STEAMED FISH JELLY PRODUCT FROM HAGFISH (먹장어 어묵 제조)

  • KIM Soo-Hyun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.11 no.4
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    • pp.197-203
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    • 1978
  • In this study, the effects of some additives to the quality of fish jelly product such as salt tripolyphosphate and starch were examined. Besides, that of washing and stepwise heating procedure were also discussed. From the result of quality test by measuring jelly strength and sensory evaluation the product was quite palatable 19 common, and the addition of 3 percent of salt and 5 percent of starch resulted in the best jelly strength. It was markedly enforced when 0.3 percent of tripolyphosphate was added. The suggestible processing method of hagfish jelly product is as follows : The meat is to be bleached by washing at least 6 times with tenfold tap water by volume of meat at $5-6^{\circ}C$ and then ground throughly with addition of 3 percent of salt, 5 percent of starch and 0.3 percent of tripolyphosphate. The ground meat is finally to be heated for 1 hour at 45 to $50^{\circ}C$ and then for 30 minutes at $90^{\circ}C$.

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Statistical flexural toughness modeling of ultra high performance concrete using response surface method

  • Mosabepranah, Mohammad A.;Eren, Ozgur
    • Computers and Concrete
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    • v.17 no.4
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    • pp.477-488
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    • 2016
  • This paper aims to model the effects of five different variables which includes: cement content (C), the steel fiber amount (F), the silica fume amount (SF), the superplasticizer (SP), the silica fume amount (SF), and the water to cementitious ratio (w/c) on 28 days flexural toughness of Ultra High Performance Concrete (UHPC) as well as, a study on the variable interactions and correlations by using analyze of variance (ANOVA) and response surface methodology (RSM). The variables were compared by fine aggregate mass. The model will be valid for the mixes with 0.18 to 0.32 w/c ratio, 4 to 8 percent steel fiber, 7 to 13 percent cement, 15 to 30 percent silica fume, and 4 to 8 percent superplasticizer by fine aggregate mass.

Effect of Antioxidant Fortification on Preservability of Buffalo Semen

  • Raina, V.S.;Gupta, A.K.;Singh, Kiran
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.1
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    • pp.16-18
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    • 2002
  • During the process of freezing, spermatozoa suffer cold shock which increases their susceptibility to lipid peroxidation which plays an important role in ageing of spermatozoa, shortening their life span and affecting the preservation of semen. An experiment was therefore conducted to study the effect of addition of natural antioxidants into semen diluents on the preservability of buffalo semen. Split semen samples were extended in milk egg yolk diluents fortified with vitamin E (MYE), vitamin C (MYC) and control group (MYO); Tris-egg yolk diluents fortified with vitamin E (TYE), vitamin C (TYC) and control group (TYO) and evaluated for their preservabilities at 4-7$^{\circ}C$ and $37^{\circ}C$. Overall least squares mean of percent motility observed after 0, 24, 48, 72 and 96 h of preservation at 4-7$^{\circ}C$ were 66.70, 54.00, 36.80, 21.90 and 12.50, respectively while the estimates for semen extended in MYE, MYC, MYO, TYE, TYC and TYO were 44.80, 42.70, 38.70, 36.00, 35.20 and 33.00 percent, respectively. The results showed that motility was significantly (p<0.01) affected by extender (extender-antioxidant combination) and preservation interval. Overall least squares mean percent motility observed after 0, 4, 8, 12 and 24 h of preservation at $37^{\circ}C$ were 68.50, 58.90, 45.00, 38.10 and 18.10 percent, respectively, while the estimates for semen extended in MYE, MYC, MYO, TYE, TYC and TYO were 48.20, 49.30, 46.80, 45.30, 42.30 and 42.50 percent, respectively. Extender and storage interval were found to be significantly (p<0.01) affecting spermatozoa motility on room temperature preservation. The results indicated that the incorporation of antioxidants, especially vitamin E, had beneficial effect on preservability of buffalo semen.

Pain reduction at venipuncture in newborn infants : oral glucose solution, EMLA cream and pacifiers (신생아의 정맥천자시 통증 감소 효과 : 경구 포도당액, EMLA 크림 및 노리개 젖꼭지)

  • Park, Sang Kee;Kim, Eun Young
    • Clinical and Experimental Pediatrics
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    • v.49 no.4
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    • pp.388-393
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    • 2006
  • Purpose : We compared the pain reducing effect of orally administered glucose solution with EMLA cream and pacifiers during venipuncture in newborn infants. Methods : Fifty newborn infants(30 prematures) were enrolled in this study. We performed these four pain-reducing methods to all infants in serial order. Group A(control) did not receive any treatment; to group B, EMLA cream was applied on the skin for 1 hour; group C(or D) received 10 percent(or 30 percent) glucose solution orally; group E used pacifiers. Symptoms and signs associated with pain at venipuncture were measured with the Premature Infants Pain Profile(PIPP) scale. Results : There was no significant difference in the PIPP scores between preterm and fullterm infants. The mean PIPP scores of groups were A : $12.5{\pm}2.5$, B : $10.1{\pm}2.6$, C : $9.4{\pm}2.0$, D : $6.5{\pm}2.1$ and E : $8.7{\pm}2.3$; the mean scores of groups B, C, D and E were significantly lower than that of group A(all, P<0.001 except B(P<0.05)), and the mean score of D was significantly lower than those of B, C and E(P<0.001, P<0.005, P<0.05, respectively). The percentages of patients with PIPP scores above 6, which means pain, were A : 100 percent, B : 82 percent, C : 56 percent, D : 40 percent and E : 70 percent. The percentages of patients with PIPP scores above 12, which means severe pain, were A : 72 percent, B : 30 percent, C : 22 percent, D : 0 percent and E : 14 percent; that of group D was clearly lowest. Conclusion : These results support the use of oral glucose solution, EMLA, and pacifiers for pain reduction as effective intervention at venipuncture in newborn infants. The most effective method was a 30 percent oral glucose solution.

Comparison of Carcass Composition of Iranian Fat-tailed Sheep

  • Kiyanzad, M.R.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.9
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    • pp.1348-1352
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    • 2005
  • Most breeds of sheep in Iran are adapted to their agro ecological niches where it is likely that they were also artificially selected by their owners. In general, most of sheep breeds are multipurpose producing lambs, wool and milk. To compare the physical and chemical composition of the carcasses of ten Iranian native fat-tailed sheep breeds, 243 male lambs (6-7 months of age) of ten fattailed, Iranian breeds of sheep, Sanjabi (S), Ghezel (G), Afshari (A), Mehrabani (M), Lori (L), Lori Bakhtiari (LB), Kordi Khorasan (K), Sangesari (Sa), Baluchi (B) and Chal (C) were studied. Lamb breed group had a significant (p<0.05) effect on all the carcass traits measured. The LB and C lambs showed the same live weight which was significantly (p<0.05) higher than the other breeds. Carcass dressing- out percentage in S lambs was lowest (p<0.05), but not different from G lambs. K and Sa breeds showed the highest (p<0.05) carcass dressing-out percentage. The S lambs had the highest (p<0.05) lean meat percent. Lean meat percentage was not significantly (p>0.05) different in the G, A, M and C breeds. The Sa and K breeds showed the lowest lean meat percent. The S lambs showed the lowest (p<0.05) fat percent in their carcass, while K and Sa showed the highest (p<0.05). Subcutaneous fat in K, Sa and B was higher (p<0.05) than the other breeds. Lambs of S, G, A and M breeds had the lowest subcutaneous fat in their carcasses (p>0.05). Intramascular fat was significantly (p<0.05) lower in M, S and C despite the fact that this values were highest in B and K lambs. The K and Sa breeds had highest fat-tail percentage (p<0.05) in their carcass, whereas S and G showed lowest. Lambs of G, S and A breeds had higher bone percent than other breeds (p<0.05). Lowest bone percent (p<0.05) was seen in K and Sa lambs. The carcass moisture percent was not significantly (p>0.05) different in S, G, A, M, L and C breeds. M lambs showed the lowest crude protein percentage and S breed the highest (p<0.05). There were no significant (p>0.05) differences among other lamb breeds for this trait. Chemical fat percentage was the same in S, G, A, C and M breeds, but significantly (p<0.05) lower from LB, K, Sa and B. Ash percent in S, G and A had no significant (p>0.05) difference. According to higher lean meat and lower fat percentages in the carcass, the ranking of breeds would be S, G, A, M and C.

On the Mechanical Properties at Low Temperatures for Steels of Ice-Class Vessels (빙해선박용 강재의 저온특성에 관한 연구)

  • Min, Dug-Ki;Shim, Chun-Sik;Shin, Dong-Wan;Cho, Sang-Rai
    • Journal of the Society of Naval Architects of Korea
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    • v.48 no.2
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    • pp.171-177
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    • 2011
  • Tensile tests were conducted at low temperatures for the steel materials which are used for outer shell of the vessels making transit through the polar regions. The selected steel materials were GL-DH32, GL-DH36 and GL-EH36. In comparison with the results at room temperature, the yield stress increases approximately by 10 to 13 percent at $-30^{\circ}C$ and by 13 to 19 percent at $-50^{\circ}C$ while the tensile strength increases about by 9 percent at $-30^{\circ}C$ and 11 to 14 percent at $-50^{\circ}C$. To obtain true stress-true strain, i.e. correct plastic hardening characteristics, Bridgman's(1952) necking correction formula was introduced taking triaxial state of stresses after onset of diffuse necking into consideration. Photographs of fractured surfaces were taken by using Scanning Electron Microscope immedately after tensile tests completed and one for GL-EH36 has been presented in this paper.

Studies on the Shrinkage of Silk Yarn by Neutral Salts (견의 중성염류에 의한 염축에 관한 연구)

  • 이용우;이광길
    • Journal of Sericultural and Entomological Science
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    • v.33 no.2
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    • pp.87-92
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    • 1991
  • The shrinkages and physical properties of silk yarn were studied on the effect of treatment concentration, time and temperature with various neutral salts. The degummed silk yarn was shrunk about 35 percent by highly concentrated solution of Ca(NO3)2 on conditions of S.G.(special gravity) 1.45 at 9$0^{\circ}C$ or S. G. 1.46 at 8$0^{\circ}C$. About 40 percent of silk yarn was contracted in length by the treatment of CaCl2 solution on conditions of S. G. 1.33 at 9$0^{\circ}C$ for 5 mins. or at 85$^{\circ}C$ for 10 mins. By treating the concentrated solution of LiBr the silk yarn showed about 40 percent of shrinkage on a conditions of S. G. 1.38, $25^{\circ}C$ 24hrs. The physical properties of salt-treated silk yarn could be significantly changed with shrinkage variations. There were some differences in shrinkages between different type of salts. However, it was observed that generally the tenacity was decreased and breaking elongation increased as the shrinkage increased. The bulkiness of salt-treated silk yarn was increased by 110 to 120 percent compared with untreated yarn.

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Survey on Menstruation of Middle & High School Girls in an Urban Area (일부 도시지역에 있어서 중, 고교생의 월경에 관한 조사연구)

  • 김명엽;강현숙
    • Journal of Korean Academy of Nursing
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    • v.2 no.1
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    • pp.63-72
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    • 1971
  • The conclusions were obtained from the detailed survey of 1,285 students experiencing menstruation, who were chosen among 1,717 students in middle & high school girls in Seoul. The survey was conducted during July 20-July 24, 1971. 1. Age of Menarche An average age of menarche was 13.3$\pm$1.07. The earliest age of menarche was 9 and the latest age 18. Ages of menarche were between 12 and 14 in 84.3 percent of the students surveyed. a. By present age distribution, the aged students were lower, than younger students in the average age of menarche. b. By father′s educational levels, among the students whose fathers were graduated from high schools, college & ever the earliest average age of menarche was found with 13.2, and among the students whose fathers were graduated from primary schools that wag latest with 13.6. c. By father′s occupations, among the students whose fathom engaged in "workers not classifiable"the earliest age of menarche was found with 12.5$\pm$0.27, among the students whose fathers were in "service business"the second was 12.9$\pm$1.07, and among the students whose fathers were in "miners, quarrymen and related workers"that was latest with 13.8$\pm$1.14. d. By economic status, among the students of "wealthy"families the age of menarche was 13.1$\pm$0.25, the among the students of "ordinary"families the lags of menarche 13.3$\pm$1.06. and the among the students of "poor" families that was 13.8$\pm$0.31. e. By home discipline, among the students being treated "rigid" the age of menarche was 13.5$\pm$1.13, among the students being treated "moderate"the age of menarche was 13.3$\pm$0.22, and those being treated "indifferent" that was 13.0$\pm$0.26. f. By students physical condition, among the students of "good" condition the average of menarche was 13.3$\pm$0.16, and among the students "poor" that was 13.5$\pm$0.31. 2. Menstruation a. For the six months after the average of menarche 39.0 percent of the students had normal menstruations, and 61.3 percent of them had abnormal ones. Of the students with abnormal menstruation 21.7 percent had abnormal menstruation from time to time, 25.4 percent had no menstruation for one month to three months, 7.2 percent had menstruation for four to six months and 6.7 per cent had no menstruation for more than sin months. Most students became to have normal menstruations a few months later the age of menarche. b. At the time interviewed, the percentile of cycle of menstruation as following: 23 days types: 46.8 percent 30 days types: 40.6 percent others : 12.6 percent The average cycle of menstruation was every 28.9 days. c. The average duration of menstruation is 4.69 days. d. The subjective symptoms during menstruation period: Out of the total 89.7 per cent had some pains, while 10.3 percent had no symptom. Among the symptoms, abdominal pain occupied 29.9 percent, neurotic symptoms 19.0 percent and lumbago 15.1 percent. e. By attitude or Action at first physical change, "Treated it by own experience" : 30.0 percent "Don′t know what to do because of ignorance" : 20.1 percent "Asked others about it" : 43.0 percent

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